Abstract
High (Z)-stereoselectivity of olefination of methyl α-phenylthioalkyl and methyl α-phenylthioalkenyl ketones with methyl trimethylsilylacetate decreases in the case of ketones containing a higher alkyl-substituent in place of the methyl group.
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Dedicated to Corresponding Member of the Russian Academy of Sciences E. P. Serebryakov on the occasion of his 70th birthday.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 1020–1021, April, 2005.
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Grigorieva, N.Y. Stereochemistry of ketone olefination with methyl trimethylsilylacetate. Russ Chem Bull 54, 1046–1047 (2005). https://doi.org/10.1007/s11172-005-0356-7
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DOI: https://doi.org/10.1007/s11172-005-0356-7