Russian Chemical Bulletin

, Volume 54, Issue 3, pp 560–565 | Cite as

Nature of weak inter- and intramolecular interactions in crystals 3. Intermolecular P=O...C=O contact in crystals of phenyl methylisopropoxyphosphorylformate

  • K. A. Lyssenko
  • I. L. Odinets
  • P. V. Kazakov
  • M. P. Pasechnik
  • M. Yu. Antipin


Phenyl methylisopropoxyphosphorylformate was studied by high resolution X-ray diffraction. The chemical bonding in the vicinity of the phosphoryl group was studied by analyzing the deformation electron density, the Laplacian of the electron density, and the electron localization function. A P=O...C=O intermolecular contact was revealed and its nature was analyzed.

Key words

phosphorylformic acid derivatives P=O...C=O contacts nature of P—O chemical bonding electron density distribution topological theory of Atoms in Molecules X-ray diffraction data 


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Copyright information

© Springer Science+Business Media, Inc. 2005

Authors and Affiliations

  • K. A. Lyssenko
    • 1
  • I. L. Odinets
    • 1
  • P. V. Kazakov
    • 1
  • M. P. Pasechnik
    • 1
  • M. Yu. Antipin
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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