Abstract
Numerous experimental data indicate that nanosystems develop by stages. The evolution route of closed nanosystems includes stages of nanoparticle nucleation, growth, ripening, and agglomeration, and texture and composition ordering. In closed systems, nanodispersed substances occur in the nano-state for a limited period of time, which can be changed by varying the supersaturation of the medium with respect to nanoparticles. Nanoparticles in open systems tend to degrade due to chemical transformations, dissolution, or evaporation and the lifetime of open systems can be estimated. At every stage of development of nanosystems, the rates of variation of the state parameters of nanoparticles fluctuate over a scale much exceeding the molecular scale. The behavior of the set of nanoparticles is described by a Fokker—Planck type equation, which may underlie the formulation of the principal equation of physicochemical evolution of nanosystem.
Similar content being viewed by others
References
M. C. Roco, R. S. Williams, and P. Alivisatos, Nanotechnology Research Directions, I. W. G. N. Workshop Report., Kluwer Acad. Publ., Dordrecht, 2000.
A. S. Edelstein and R. C. Camarata, Nanomaterials: Synthesis, Properties and Application, Inst. Physics. Publ., Bristol-Philadelphia, 1996.
I. V. Melikhov and V. E. Bozhevolnov, J. Nanoparticle Res., 2003, 5, 465.
Yu. I. Petrov, Klastery i malye chastitsy [Clusters and Small Particles], Nauka, Moscow, 1986 (in Russian).
I. V. Kazakova, G. V. Godiyak, Khim. Fizika [Chem. Phys.] 1997, 16, 118 (in Russian).
M. Volmer, Kinetik der Phasenbildung, Nh. Steinkopfverb., Dresden-Leipzig, 1939.
I. V. Melikhov, E. D. Kozlovskaya, A. M. Kutepov, M. V. Fedotova, V. N. Trosnin, and V. V. Kuznetsov, Kontsentrirovannye i nasyshchennye rastvory [Concentrated and Saturated Solutions], Nauka, Moscow, 2002 (in Russian).
V. F. Komarov, A. V. Severin, and I. V. Melikhov, Crystalografiya, 2000, 45, 364 [Crystallogr. Repts, 2000, 45 (Engl. Transl.)].
I. V. Melikhov, V. F. Komarov, and Yu. A. Kozel, Kolloid. zh., 1988, 49, 690 [Colloid. J. USSR, 1988, 49 (Engl. Transl.)].
D. Balarev, Stroezh na realnokristalnite sistemy, Nauka i izkustvo, Sofia, 1964.
N. P. Yushkin, Teoriya microblochnogo rosta crystalov v prirodnykh geterogennykh rastvorakh [Theory of Microblock Crystal Growth in Natural Heterogeneous Solutions], Komi FAN SSSR, Syktyvkar, 1971 (in Russian).
I. V. Melikhov and V. G. Pechnikov, Zh. Fiz. Khimii, 1970, 44, 2239 [Russ. J. Phys. Chem., 1970, 44 (Engl. Transl.)].
I. V. Melikhov, E. N. Kitova, A. N. Kamenskaya, N. B. Mikheev, and S. A. Kulyukhin, Kolloid. Zh., 1997, 59, 78 [Colloid. J., 1997, 59 (Engl. Transl.)].
N. B. Mikheev, I. V. Melikhov, and A. N. Kamenskaya, Radiokhimiya, 1997, 39, 523 [Russ. Radiochem., 1997, 39 (Engl. Transl.)].
I. V. Melikhov, S. B. Baronov, and S. S. Berdonosov, Zhurn. Fiz. Khimii, 2004, 78, 1794 [Russ. J. Phys. Chem., 2004, 78 (Engl. Transl.)].
I. V. Melikhov, E. D. Kozlovskaya, L. B. Berliner, and M. A. Prokofiev, J. Colloid. Interface Sci., 1987, 117, 1.
I. V. Melikhov, Zh. Fiz. Khimii, 1989, 63, 476 [Russ. J. Phys. Chem., 1989, 63 (Engl. Transl.)].
L. B. Berliner and I. V. Melikhov, Teoret. Osnovy Khim. Tekhnologii, 1985, 19, 24 [Theor. Foundations Chem. Technol., 1985, 19 (Engl. Transl.)].
I. V. Melikhov and B. D. Nebylitsin, Rost crystallov [Crystal Growth], Izd. Erevanskogo Univ., 1977, 12, 103 (in Russian).
O. M. Todes, V. A. Seballo, and A. D. Gol’tsiker, Massovaya Crystalizatsiya iz Rastvorov, Khimiya, Leningrad, 1984 (in Russian).
P. H. Singer, Semiconductor International, 1998, 21, 111.
I. V. Melikhov and G. Vucovic, Radiochim. Acta, 1998, 77, 83.
I. V. Melikhov, V. A. Prisyazhnyuk, Crystalografiya, 1978, 23, 595 [Sov. Phys.-Crystallogr., 1978, 23 (Engl. Transl.)].
V. E. Bozhevolnov, L. N. Ivanov, V. K. Kozlov, V. V. Voronov, Yu. P. Timofeev, and V. V. Karelin, Phys. Stat. Sol., 1976, 78, 483.
V. V. Karelin, Yu. N. Orlov, V. E. Bozhevol’nov, L. N. Ivanov, Vestn. MGU, Seriya 2. Khimiya, 1981, 22, 63 [Vestn. Mosk. Univ., Ser. Khim., 1981 (Engl. Transl.)].
V. I. Aleshin, V. E. Bozhevol’nov, L. N. Ivanov, V. V. Karelin, Izv. Akad. Nauk SSSR, Ser. fiz., 1986, 50, 571 [Bull. Acad. Sci. USSR, Div. Phys. Sci., 1986 (Engl. Transl.)].
I. V. Melikhov, V. M. Podkopov, B. A. Ilyin, and E. D. Kozlovskaya, Chem. Eng. Sci., 1996, 51, 671.
R. Kaischev and E. Budevski, Contemp. Phys., 1967, 8, 489.
J. D. Wright and N. A. J. M. Sommerdijk, Sol Gel Materials: Chemystry and Applications, Taylor and Francis, New York, 2001.
E. I. Suvorova, L. E. Popak, V. F. Komarov, and I. V. Melikhov, Crystalografiya, 2000, 45, 1520 [Crystallogr. Repts, 2000, 45 (Engl. Transl.)].
I. V. Melikhov, E. N. Kitova, A. Ya. Gorbachevskii, Yu. D. Perfil’ev, V. P. Shantarovich, I. O. Bogatyrev, I. B. Kevdina, and A. L. Nikolaev, Zh. Fiz. Khim., 1993, 67, 75 [Russ. J. Phys. Chem., 1993, 67 (Engl. Transl.)].
I. V. Melikhov, Zh. Vukovich, B. D. Nebylitsin, Zh. Fiz. Khim., 1972, 46, 1952 [Russ. J. Phys. Chem., 1972, 46 (Engl. Transl.)].
I. V. Melikhov and M. S. Merkulova, Socrystalizatsiya [Co-Crystallization], Nauka, Moscow, 1975 (in Russian).
P. M. Ajayan, L. S. Schlager, and P. V. Braun, Nanocomposite Science and Technology, Willey VCH Verlag, Weinheim, 2003.
S. Mann, Biomineralization: Principle and Concepts in Bioinorganic Materials Chemistry, Oxford Univ. Press., Oxford, 2002.
G. M. Whitesides, J. P. Mathias, and C. T. Seto, Science, 1991, 254, 1312.
I. V. Melikhov and A. S. Kelebeev, Crystalografiya, 1979, 24, 410 [Sov. Phys.-Crystallogr., 1979, 24 (Engl. Transl.)].
I. V. Melikhov, A. S. Kelebeev, and S. Bacic, J. Colloid Interface Sci., 1986, 53, 784.
I. V. Melikhov, M. Ya. Belousova, N. A. Rudnev, N. T. Buludov, Crystalografiya, 1974, 19, 784 [Sov. Phys.-Crystallogr., 1974, 19 (Engl. Transl.)].
V. F. Komarov, A. G. Chaliyan, I. V. Melikhov, Zh. Neorg. Khim., 1966, 41, 533 [J. Inorg. Chem. USSR, 1966, 41 (Engl. Transl.)].
Author information
Authors and Affiliations
Additional information
__________
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 17–31, January, 2005.
Rights and permissions
About this article
Cite this article
Melikhov, I.V., Bozhevol’nov, V.E. Condensation route of evolution of nanodispersed substances. Russ Chem Bull 54, 16–30 (2005). https://doi.org/10.1007/s11172-005-0213-8
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/s11172-005-0213-8