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Russian Chemical Bulletin

, Volume 53, Issue 12, pp 2798–2804 | Cite as

Cyclization of 1-hydroxy-2-(oxoalkynyl)anthraquinones

  • M. A. Mzhelskaya
  • I. D. Ivanchikova
  • N. E. Polyakov
  • A. A. Moroz
  • M. S. Shvartsberg
Article

Abstract

Procedures were developed for the heterocyclization of 2-benzoylethynyl-1-hydroxy-and 1-hydroxy-2-(1-oxo-3-phenylpropynyl)anthraquinone. The regioselective preparation of 2-substituted anthra[1,2-b]pyran-4,7,12-triones was demonstrated to be possible under mild conditions.

Key words

anthraquinones anthra[1,2-b]pyrantriones anthra[1,2-b]furandiones heterocyclization alkynones enamines iodination 

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Copyright information

© Springer Science+Business Media, Inc. 2004

Authors and Affiliations

  • M. A. Mzhelskaya
    • 1
  • I. D. Ivanchikova
    • 1
  • N. E. Polyakov
    • 1
  • A. A. Moroz
    • 2
  • M. S. Shvartsberg
    • 1
  1. 1.Institute of Chemical Kinetics and Combustion, Siberian BranchRussian Academy of SciencesNovosibirskRussian Federation
  2. 2.Kemerovo State UniversityKemerovoRussian Federation

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