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Russian Chemical Bulletin

, Volume 53, Issue 10, pp 2241–2247 | Cite as

A novel method for the oxidation of thiophenes. Synthesis of thiophene 1,1-dioxides containing electron-withdrawing substituents

  • V. G. Nenajdenko
  • A. M. Moiseev
  • E. S. Balenkova
Article

Abstract

A novel method for the synthesis of thiophene 1,1-dioxides by oxidation of substituted thiophenes with trifluoroperoxyacetic acid was developed. The effect of the solvent nature on the course of the reaction was studied and optimum conditions for the oxidation of thiophenes containing various functional groups were found. Previously unknown thiophene dioxides were obtained.

Key words

thiophene 1,1-dioxides trifluoroperoxyacetic acid thiophenes with electron-withdrawing substituents 

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Copyright information

© Springer Science+Business Media, Inc. 2004

Authors and Affiliations

  • V. G. Nenajdenko
    • 1
  • A. M. Moiseev
    • 1
  • E. S. Balenkova
    • 1
  1. 1.Department of ChemistryM. V. Lomonosov Moscow State University, Leninskie GoryMoscowRussian Federation

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