Advertisement

Russian Chemical Bulletin

, Volume 53, Issue 10, pp 2215–2220 | Cite as

New efficient boron-containing initiators of methyl methacrylate radical polymerization

  • S. Yu. Erdyakov
  • O. A. Mel’nik
  • M. E. Gurskii
  • A. V. Ignatenko
  • Ya. S. Vygodskii
Article

Abstract

An efficient method for methyl methacrylate radical polymerization by tri-n-propyl-, triisopropyl-, and triisobutylborane ammonia complexes, including the addition of a boron-containing initiating agent into the monomer in air, was developed. An advantage of this method is that the reaction occurs at room temperature, requires no peroxide components, and leads to polymers with enhanced thermal stability.

Key words

radical polymerization methyl methacrylate trialkylborane ammonia adducts nuclear magnetic resonance 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    V. A. Dodonov, L. S. Kochneva, I. N. Aksenova, and L. M. Terman, Vysokomol. Soedin., Ser. B, 1986, 28, 582 [Polym. Sci. USSR; Ser. B, 1986, 28 (Engl. Transl.)].Google Scholar
  2. 2.
    V. A. Dodonov, Zh. V. Garusova, Z. V. Orlova, and T. I. Starostina, Vysokomol. Soedin., Ser. B, 1999, 41, 1831 [Polym. Sci., Ser. B, 1999, 41, 327 (Engl. Transl.)].Google Scholar
  3. 3.
    O. Grummit, J. Am. Chem. Soc., 1942, 64, 1811.CrossRefGoogle Scholar
  4. 4.
    G. A. Razuvaev, V. A. Dodonov, and Yu. A. Ivanova, Dokl. Akad. Nauk SSSR, 1980, 250, 119 [Dokl. Chem., 1980 (Engl. Transl.)].Google Scholar
  5. 5.
    V. A. Dodonov, Yu. L. Kuznetsova, and A. A. Skatova, Vysokomol. Soedin., Ser. B, 1999, 41, 1516 [Polym. Sci., Ser. B, 1999, 41, 261 (Engl. Transl.)].Google Scholar
  6. 6.
    V. A. Dodonov, A. A. Skatova, Yu. L. Kuznetsova, and I. I. Brezhneva, Vysokomol. Soedin., Ser. A, 2000, 42, 1478 [Polym. Sci., Ser. A, 2000, 42, 967 (Engl. Transl.)].Google Scholar
  7. 7.
    A. N. Nesmeyanov and R. A. Sokolik, Metody elemento-organicheskoi khimii. Bor, alyuminii, gallii, indii, tallii [Methods of Organoelement Chemistry. Boron, Aluminum, Gallium, Indium, Thallium], Nauka, Moscow, 499 pp. (in Russian).Google Scholar
  8. 8.
    C. H. E. Bawn, D. Margerison, and N. M. Richardson, Proc. Chem. Soc., 1959, 397.Google Scholar
  9. 9.
    D. V. Demchuk, Ph. D. (Chem.) Thesis, Institite of Organic Chemistry, Russian Academy of Sciences, Moscow, 1991, 130 pp. (in Russian).Google Scholar
  10. 10.
    F. G. Welch, J. Polymer Sci., 1962, 61, 243.CrossRefGoogle Scholar
  11. 11.
    V. A. Dodonov, O. S. Morozov, D. F. Grishin, E. G. Lyutin, and N. N. Vyshinskii, Dokl. Akad. Nauk USSR, 1980, 255, 1123 [Dokl. Chem., 1980 (Engl. Transl.)].Google Scholar
  12. 12.
    V. A. Dodonov and I. N. Aksenova, Vysokomol. Soedin., Ser. B, 1986, 28, 422 [Polym. Sci. USSR, Ser. B, 1986, 28 (Engl. Transl.)].Google Scholar
  13. 13.
    W. Debski, Polymetakrylan metylu, Widawnictwa Naukowo-techniczne, Warsawa, 1972 (in Polish).Google Scholar
  14. 14.
    V. S. Bogdanov, Doct. Sci. (Chem.) Thesis, Institute of Organic Chemistry, USSR Academy of Sciences, Moscow, 1975, 253 pp. (in Russian).Google Scholar
  15. 15.
    P. Renaud and O. Cyril, Chem. Rev., 2001, 101, 3415.CrossRefPubMedGoogle Scholar
  16. 16.
    N. N. Vyshinskii and V. I. Kokorev, Dokl. Akad. Nauk, SSSR, 1977, 236, 8836 [Dokl. Chem., 1977 (Engl. Transl.)].Google Scholar
  17. 17.
    F. A. Bovey, High Resolution NMR of Macromolecules, Academic Press, New York—London, 1972.Google Scholar
  18. 18.
    F. A. Bovey, J. Polym. Sci. Polym. (A) (Chem. Ed.), 1996, 34, 711.Google Scholar
  19. 19.
    V. A. Kabanov, Int. Symp. on Makromol. Chem. IUPAC, Budapest, 1969, 435.Google Scholar
  20. 20.
    V. A. Dodonov and D. F. Grishin, Vysokomol. Soedin., Ser. B, 1993, 35, 47 [Polym. Sci., Ser. B, 1993, 35, 137 (Engl. Transl.)].Google Scholar
  21. 21.
    A. J. Gordon and R. A. Ford, The Chemist’s Companion, Wiley-Interscience, New York, 1972.Google Scholar
  22. 22.
    B. M. Mikhailov, Yu. N. Bubnov, and V. G. Kiselev, Zh. Org. Khim. [Sov. J. Org. Chem.], 1966, 36, 62 (in Russian).Google Scholar
  23. 23.
    B. M. Mikhailov and Yu. N. Bubnov, Organoboron Compounds in Organic Synthesis, Bell and Bain Ltd., Glasgow, 1984, 781 pp.Google Scholar
  24. 24.
    J. Billiani, I. Amtman, T. Mayr, and K. Lederer, J. Liq. Cromatogr., 1990, 13, 2973.Google Scholar
  25. 25.
    R. Koster, G. Bruno, and P. Binger, Ann., 1961, 1, 644.Google Scholar
  26. 26.
    H. C. Brown, J. Am. Chem. Soc., 1945, 67, 374.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, Inc. 2004

Authors and Affiliations

  • S. Yu. Erdyakov
    • 1
  • O. A. Mel’nik
    • 2
  • M. E. Gurskii
    • 1
  • A. V. Ignatenko
    • 1
  • Ya. S. Vygodskii
    • 2
  1. 1.N. D. Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussian Federation
  2. 2.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

Personalised recommendations