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Russian Chemical Bulletin

, Volume 53, Issue 9, pp 2008–2012 | Cite as

New trigonal tris(phosphine oxides)

  • S. A. Pisareva
  • P. V. Petrovskii
  • K. A. Lyssenko
  • M. Yu. Antipin
  • E. E. Nifant’ev
Article

Abstract

The reaction of 1,1,1-tris(chloromethyl)propane with diphenylphosphine under phase-transfer conditions afforded 1,1,1-tris(diphenylphosphinomethyl)propane, whose oxidation gave a previously unknown representative of trigonal tris(phosphine oxides), viz., stable 1,1,1-tris(diphenylphosphorylmethyl)propane. Its analogs, viz., bis(diphenylphosphoryl)diphenylphosphinomethane and tris(diphenylphosphoryl)methane, are unstable in air and decompose with the cleavage of the P-C bond.

Key words

bis(diphenylphosphoryl)diphenylphosphinomethane tris(diphenylphosphoryl)methane 1,1,1-tris(diphenylphosphinomethyl)propane 1,1,1-tris(diphenylphosphorylmethyl)propane 

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Copyright information

© Springer Science+Business Media, Inc. 2004

Authors and Affiliations

  • S. A. Pisareva
    • 1
  • P. V. Petrovskii
    • 1
  • K. A. Lyssenko
    • 1
  • M. Yu. Antipin
    • 1
  • E. E. Nifant’ev
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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