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Fullerides: heterometallic superconductors with composition M2M′C60 (M = K, Rb; M′ = Yb, Lu, Sc)

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Abstract

One- or two-step reactions of potassium and rubidium fullerides with composition M k C60 (M = K, Rb; k = 3—6) and K6C60 + m K mixtures (m = 1, 3) with anhydrous salts M′Cl3 (M′ = La, Pr, Nd, Sm, Gd, Tb, Yb, Lu, Y, Sc) and YbI2 in a toluene—THF medium afforded heterometallic fullerides M3–nM′ n C60 (n = 1—3). Among these compounds, substituted fullerides with composition M2M′C60 (M′ = Yb, Lu, Sc) display superconducting properties with critical temperatures of 14—20 K.

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Leninskie Gory, 119992, Moscow, Russian Federation

    B. M. Bulychev & R. V. Shpanchenko

  2. Department of Physics, Moscow State University, Leninskie Gocy, 119992, Moscow, Russian Federation

    R. A. Lunin & V. A. Kul’bachinskii

  3. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    V. I. Privalov

Authors
  1. B. M. Bulychev
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  2. R. A. Lunin
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  3. V. A. Kul’bachinskii
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  4. R. V. Shpanchenko
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  5. V. I. Privalov
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1623–1628, August, 2004.

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Bulychev, B.M., Lunin, R.A., Kul’bachinskii, V.A. et al. Fullerides: heterometallic superconductors with composition M2M′C60 (M = K, Rb; M′ = Yb, Lu, Sc). Russ Chem Bull 53, 1686–1692 (2004). https://doi.org/10.1007/s11172-005-0018-9

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  • DOI: https://doi.org/10.1007/s11172-005-0018-9

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