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Russian Journal of Applied Chemistry

, Volume 78, Issue 12, pp 1981–1986 | Cite as

Water-Soluble Polymeric Methanofullerene and Fulleropyrrolidine Derivatives

  • O. V. Nazarova
  • I. A. Nuretdinov
  • A. V. Slita
  • G. M. Pavlov
  • N. P. Evlampieva
  • L. S. Litvinova
  • V. P. Gubskaya
  • G. M. Fazleeva
  • L. Sh. Berezhnaya
  • A. P. Pronina
  • O. I. Kiselev
  • E. F. Panarin
Macromolecular Chemistry and Polymeric Materials
  • 43 Downloads

Abstract

Water-soluble methanofullerene and fulleropyrrolidine derivatives were synthesized by the reactions of methanofullerenes (MFs) and fulleropyrrolidines (FPs) with poly(N-vinylpyrrolidone) (PVP) bearing one terminal amino group. The products contain MF or FP covalently bound to the polymer, corresponding polymeric complexes, and unreacted PVP. Large aggregates of the polymeric MF and FP derivatives are found in aqueous solutions. The electrooptical properties of the products differ considerably from those of the initial polymer. The phosphorus-containing MF and FP derivatives are capable of cleaving the molecule of plasmid DNA.

Keywords

Polymer Aqueous Solution Large Aggregate Terminal Amino Polymeric Complex 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK "Nauka/Interperiodica" 2005

Authors and Affiliations

  • O. V. Nazarova
    • 1
    • 2
    • 3
    • 4
  • I. A. Nuretdinov
    • 1
    • 2
    • 3
    • 4
  • A. V. Slita
    • 1
    • 2
    • 3
    • 4
  • G. M. Pavlov
    • 1
    • 2
    • 3
    • 4
  • N. P. Evlampieva
    • 1
    • 2
    • 3
    • 4
  • L. S. Litvinova
    • 1
    • 2
    • 3
    • 4
  • V. P. Gubskaya
    • 1
    • 2
    • 3
    • 4
  • G. M. Fazleeva
    • 1
    • 2
    • 3
    • 4
  • L. Sh. Berezhnaya
    • 1
    • 2
    • 3
    • 4
  • A. P. Pronina
    • 1
    • 2
    • 3
    • 4
  • O. I. Kiselev
    • 1
    • 2
    • 3
    • 4
  • E. F. Panarin
    • 1
    • 2
    • 3
    • 4
  1. 1.Institute of Macromolecular CompoundsRussian Academy of SciencesSt. PetersburgRussia
  2. 2.Arbuzov Institute of Organic and Physical ChemistryRussian Academy of SciencesKazan, TatarstanRussia
  3. 3.Research Institute of InfluenzaRussian Academy of Medical SciencesSt. PetersburgRussia
  4. 4.Fock Research Institute of PhysicsSt. Petersburg State UniversitySt. PetersburgRussia

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