Russian Journal of Applied Chemistry

, Volume 78, Issue 4, pp 617–622 | Cite as

Synthesis and Pore Structure of Monolithic Polymeric Sorbents

  • G. N. Khimich
  • E. N. Rakhmatullina
  • M. Yu. Slabospitskaya
  • T. B. Tennikova
Macromolecular Chemistry and Polymeric Materials


The pore structure of monolithic sorbents prepared by photoinduced copolymerization of 2,3-epoxypropyl methacrylate with ethylene glycol dimethacrylate was studied. The parameters of the pore structure of these copolymers were examined as influenced by the quantitative ratio of pore-forming agents and the type and concentration of the initiators.


Ethylene Ethylene Glycol Pore Structure Methacrylate Copolymerization 
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  1. 1.
    Svec, F., Tennikova, T.B., and Deyl, Z., Monolithic Materials: Preparation, Properties and Applications, Amsterdam: Elsevier, 2003, vol. 67, p. 457.Google Scholar
  2. 2.
    Tennikova, T.B., Belenkii, B.G., and Svec, F., J. Liq. Chromatogr., 1990, vol. 13, no.1, pp. 63–71.Google Scholar
  3. 3.
    Tennikova, T.B., Bleha, M., Svec, F. et al., J. Chromatogr., 1991, vol. 555, nos.1–2, pp. 90–107.Google Scholar
  4. 4.
    Svec, F. and Tennikova, T.B., J. Biocompat. Polym., 1991. vol. 6, no.2, pp. 393–398.Google Scholar
  5. 5.
    US Patent, no. 4 889 632.Google Scholar
  6. 6.
    Svec, F. and Frechet, J.M.J., Anal. Chem., 1992, vol. 64, no.7, pp. 820–822.Google Scholar
  7. 7.
    Tennikova, T. and Svec, F., J. Chromatogr., 1993, vol. 646, no.2, pp. 279–286.Google Scholar
  8. 8.
    Svec, F. and Freechet, J.M.J., J. Chromatogr. A, 1995, vol. 702, nos.1–2, pp. 89–95.Google Scholar
  9. 9.
    Strancar, A., Koselj, P., and Schwinn, H., Josic Dj., Anal. Chem., 1996, vol. 68, no.19, pp. 3483–3490.Google Scholar
  10. 10.
    Xie, S., Svec, F., and Freechet, J.M.J., J. Chromatogr., 1997, vol. 775, nos.1–2, pp. 65–72.Google Scholar
  11. 11.
    Strancar, A., Barut, M., Podgornik, A., et al., LC-GC Int., 1998, vol. 10, no.11, pp. 660–668.Google Scholar
  12. 12.
    Kasper, C., Meringova, L., Freitag, R., and Tennikova, T., J. Chromatogr., 1998, vol. 798, nos.1–2, pp. 65–74.Google Scholar
  13. 13.
    Tennikova, T. and Freitag, R., J. High Resol. Chro-matogr., 2000, vol. 23, no.1, pp. 27–38.Google Scholar
  14. 14.
    Strancar, A., Podgornik, A., Barut, M., et al., Advances in Biochemical Engineering/Biotechnology: Modern Advances Chromatography, Heidelberg: Springer Verlag, 2002, vol. 76, pp. 49–85.Google Scholar
  15. 15.
    Svec, F. and Frechet, J.M.J., Monolithic Materials: Preparation, Properties and Applications, Amsterdam: Elsevier, 2003, vol. 67, pp. 19–50.Google Scholar
  16. 16.
    Yu, C., Davey, M.H., Svec, F., and Frechet, J.M.J, Anal. Chem., 2001, vol. 73, no.21, pp. 5088–5096.PubMedGoogle Scholar
  17. 17.
    Swart, R., Kraak, J.C., and Poppe, H., J. Chromatogr. A, 1994, vol. 670, no.1, pp. 25–38.Google Scholar
  18. 18.
    Viklund, C., Ponten, E., Glad, B., et al., Chem. Mater., 1997, vol. 9, no.2, pp. 463–471.Google Scholar
  19. 19.
    Yu, C., Svec, F., and Frechet, J.M.J., Electrophoresis, 2000, vol. 21, no.1, pp. 120–127.CrossRefPubMedGoogle Scholar
  20. 20.
    Svec, F. and Frechet, J.M.J., Ind. Eng. Chem. Res., 1999, vol. 38, no.1, pp. 34–48.Google Scholar
  21. 21.
    Xie, S., Svec, F., and Frechet, J.M.J., Chem. Mater., 1998, vol. 10, no.12, pp. 4072–4078.Google Scholar
  22. 22.
    Cooper, A.I. and Holmes, A.B., Adv. Mater., 1999, vol. 11, no.5, pp. 1270–1274.Google Scholar
  23. 23.
    Cooper, A.I., Wood, C.D., and Holmes, A.B., Ind. Eng. Chem. Res., 2000, vol. 39, no.12, pp. 4741–4744.Google Scholar
  24. 24.
    Kun, K.A. and Kunin, R., J. Polym. Sci., 1967, vol. 16, pp. 1457–1469.Google Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • G. N. Khimich
    • 1
  • E. N. Rakhmatullina
    • 1
  • M. Yu. Slabospitskaya
    • 1
  • T. B. Tennikova
    • 1
  1. 1.Institute of Macromolecular CompoundsRussian Academy of SciencesSt. PetersburgRussia

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