Advertisement

Russian Journal of Applied Chemistry

, Volume 78, Issue 3, pp 409–413 | Cite as

Polythermal Study of the Systems M(ClO4)2-H2O (M2+ = Mg2+, Ca2+, Sr2+, Ba2+)

  • O. N. Pestova
  • L. A. Myund
  • M. K. Khripun
  • A. V. Prigaro
Physicochemical Studies of Systems and Processes

Abstract

The solubility polytherms in the systems for which the cryoscopic data are lacking were measured. The structural models of the electrolyte solutions were discussed on the basis of the solubility polytherms.

Keywords

Electrolyte Solution Solubility Polytherms Polythermal Study Cryoscopic Data 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

REFERENCES

  1. 1.
    Zalkin, V.M., Priroda evtekticheskikh splavov i effekt kontaktnogo plavleniya (Nature of Eutectic Alloys and Contact Melting Effect), Moscow: Metallurgiya, 1987.Google Scholar
  2. 2.
    Charykova, M.V., and Charykov, N.A., Termodinamicheskoe modelirovanie protsessov evaporitovoi sedimentatsii (Thermodynamic Modeling of Evaporite Sedimentation), St. Petersburg: Nauka, 2003.Google Scholar
  3. 3.
    Kurilenko, V.V., Sovremennye basseiny evaporitovoi sedimentatsii (Modern Basins of Evaporite Sedimentation), St. Petersburg: Sankt-Peterb. Gos. Univ., 1997.Google Scholar
  4. 4.
    Stewart, G.H., Ind. J. Phys., 1932, vol. 7, pp. 603–615.Google Scholar
  5. 5.
    Khripun, M.K., Lilich, L.S., and Efimov, A.Yu., in Problemy sovremennoi khimii koordinatsionnykh soedinenii (Problems of Modern Coordination Chemistry), Leningrad: Leningr. Gos. Univ., 1983, issue 7, pp. 58–102.Google Scholar
  6. 6.
    Lilich, L.S., and Khripun, M.K., Rastvory kak khimicheskie sistemy (Solutions as Chemical Systems), St. Petersburg: Sankt-Peterb. Gos. Univ., 1994, p. 61.Google Scholar
  7. 7.
    Penkina, N.V., and Smaev, V.N., Zh. Fiz. Khim., 1974, vol. 48, no.3, pp. 637–640.Google Scholar
  8. 8.
    Petrun’kin, S.P., Trostin, V.N., and Krestov, G.A., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1986, vol. 29, no.6, pp. 15–19.Google Scholar
  9. 9.
    Khripun, M.K., Karavan, S.V., and Bulgakov, S.A., in Problemy khimii koordinatsionnykh soedinenii (Problems of Coordination Chemistry), Leningrad: Leningr. Gos. Univ., 1987, issue 8, pp. 123–141.Google Scholar
  10. 10.
    Puchkov, L.V., and Sargaev, P.M., Zh. Prikl. Khim., 1973, vol. 46, no.12, pp. 2637–2639.Google Scholar
  11. 11.
    Khripun, M.K., Myund, L.A., Baranova, G.I., et al., Zh. Obshch. Khim., 1998, vol. 68, no.4, pp. 550–555.Google Scholar
  12. 12.
    Khripun, M.K., Chervonenko, K.Yu., Kiselev, A.A., and Khripun, A.V., Zh. Obshch. Khim., 2001, vol. 71, no.1, pp. 25–35.Google Scholar
  13. 13.
    Khripun, M.K., Chervonenko, K.Yu., Kiselev, A.A., and Petranovskii, V.P., Zh. Obshch. Khim., 2002, vol. 72, no.6, pp. 932–937.Google Scholar
  14. 14.
    Kiselev, A.A., Zubtsov, M.K., and Khripun, M.K., Vestn. Sankt-Peterb. Gos. Univ., Ser. 4, 2002, issue 3, pp. 51–54.Google Scholar
  15. 15.
    Kirgintsev, A.N., Trushnikova, L.N., and Lavrent’eva, V.G., Rastvorimost’ neorganicheskikh veshchestv v vode: Spravochnik (Solubility of Inorganic Substances in Water: Handbook), Leningrad: Khimiya, 1972.Google Scholar
  16. 16.
    Latysheva, V.A., Vodno-solevye rastvory, sistemnyi podkhod (Water-Salt Solutions. A Systematic Approach), St. Petersburg: Sankt-Peterb. Gos. Univ., 1998.Google Scholar
  17. 17.
    James, D. and Culter, P., New J. Chem., 1986, vol. 39, pp. 137–147.Google Scholar
  18. 18.
    Samoilov, O.Ya., Struktura vodnykh rastvorov elektrolitov i gidratatsiya ionov (Structure of Aqueous Solutions of Electrolytes and Ion Hydration), Moscow: Akad. Nauk SSSR, 1957.Google Scholar
  19. 19.
    Robinson, R.A., and Stokes, R.H., Electrolyte Solutions. The Measurement and Interpretation of Conductance, Chemical Potential, and Diffusion in Solutions of Simple Electrolytes, London: Butterworths, 1959.Google Scholar
  20. 20.
    Mikulin, A., Voprosy fizicheskoi khimii rastvorov elektrolitov (Problems of Physical Chemistry of Electrolyte Solutions), Leningrad: Khimiya, 1968, pp. 46–48.Google Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • O. N. Pestova
    • 1
  • L. A. Myund
    • 1
  • M. K. Khripun
    • 1
  • A. V. Prigaro
    • 1
  1. 1.St. Petersburg State UniversitySt. PetersburgRussia

Personalised recommendations