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Russian Journal of Applied Chemistry

, Volume 78, Issue 2, pp 315–318 | Cite as

Mechanism of Depolymerization of Polymeric p-Dinitrosobenzene in Vulcanization of Unsaturated Rubbers: A Quantum-Chemical Study

  • O. R. Klyuchnikov
  • D. V. Chachkov
  • R. Ya. Deberdeev
  • G. E. Zaikov
Macromolecular Chemistry and Polymeric Materials

Abstract

The mechanism of depolymerization of polymeric p-dinitrosobenzene in vulcanization of unsaturated rubbers is analyzed. The results obtained explain why the vulcanizing activity of p-dinitrosobenzene decreases in the course of its prolonged storage.

Keywords

Rubber Vulcanization Prolonged Storage Unsaturated Rubber 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • O. R. Klyuchnikov
    • 1
    • 2
    • 3
  • D. V. Chachkov
    • 1
    • 2
    • 3
  • R. Ya. Deberdeev
    • 1
    • 2
    • 3
  • G. E. Zaikov
    • 1
    • 2
    • 3
  1. 1.Kazan State University of Power EngineeringKazan, TatarstanRussia
  2. 2.Kazan State Technological UniversityKazan, TatarstanRussia
  3. 3.Emanuel’ Institute of Biochemical PhysicsRussian Academy of SciencesMoscowRussia

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