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Russian Journal of Applied Chemistry

, Volume 78, Issue 2, pp 291–294 | Cite as

Radical Copolymerization of Methyl Methacrylate and Styrene in the Presence of Metallocenes

  • R. Kh. Yumagulova
  • S. V. Kolesov
  • Yu. B. Monakov
Macromolecular Chemistry and Polymeric Materials
  • 36 Downloads

Abstract

The effect of ferrocene and zirconocene dichloride on the rate and constants of copolymerization of methyl methacrylate with styrene was studied. The results obtained suggest that the metallocenes in the elementary steps of the reaction.

Keywords

Methyl Styrene Methacrylate Copolymerization Ferrocene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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REFERENCES

  1. 1.
    Kabanov, V.A., Zubov, V.P., and Semchikov, Yu.D., Kompleksno-radikal’naya polimerizatsiya (Coordination-Radical Polymerization), Moscow: Nauka, 1987.Google Scholar
  2. 2.
    Novoe v chereduyushcheisya sopolimerizatsii (New Data on Alternating Copolymerization), Krentsel’, B.A., Ed., Leningrad: Inst. Neftekhim. Sinteza, Akad. Nauk SSSR, 1976.Google Scholar
  3. 3.
    Furukawa, J., Vysokomol. Soedin., Ser. A, 1979, vol. 21, no.11, pp. 2591–2605.Google Scholar
  4. 4.
    Grishin, D.F. and Moikin, A.A., Dokl. Ross. Akad. Nauk, 1997, vol. 356, no.6, p. 766.Google Scholar
  5. 5.
    Grishin, D.F. and Semenycheva, L.L., Usp. Khim., 2001, vol. 70, no.5, pp. 486–510.Google Scholar
  6. 6.
    Grishin, D.F. and Moikin, A.A., Vysokomol. Soedin., Ser. B, 1996, vol. 38, no.11, pp. 1909–1912.Google Scholar
  7. 7.
    Puzin, Yu.I., Prokudina, E.M., Yumagulova, R.Kh., et al., Dokl. Ross. Akad. Nauk, 2002, vol. 386, no.1, p. 69.Google Scholar
  8. 8.
    Sigaeva, N.N., Kolesov, S.V., Prokudina, E.M., et al., Abstracts of Papers, XVII Mendeleevskii s”ezd po obshchei i prikladnoi khimii (XVII Mendeleev Congr. on General and Applied Chemistry), Kazan, September 21–26, 2003, vol. 3, p. 481.Google Scholar
  9. 9.
    Analytical Chemistry of Polymers, part 1, Analysis of Monomers and Polymeric Materials, Kline, G.M., Ed., New York: Interscience, 1959.Google Scholar
  10. 10.
    Toroptseva, A.M., Belogorodskaya, K.V., and Bondarenko, V.M., Laboratornyi praktikum po khimii i tekhnologii vysokomolekulyarnykh soedinenii (Laboratory Manual on Chemistry and Technology of Macromolecular Compounds), Leningrad: Khimiya, 1972.Google Scholar
  11. 11.
    Gladyshev, G.P., Polimerizatsiya vinil’nykh monomerov (Polymerization of Vinyl Monomers), Alma-Ata, 1964.Google Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • R. Kh. Yumagulova
    • 1
  • S. V. Kolesov
    • 1
  • Yu. B. Monakov
    • 1
  1. 1.Institute of Organic Chemistry, Ufa Scientific CenterRussian Academy of SciencesUfa, BashkortostanRussia

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