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Complex formation of carbonyls, carboxylates, and acetylacetonates of main-group and transition metals with hydroperoxides and alcohols

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Abstract

The thermodynamic and structural parameters of complexes formed by secondary and tertiary alcohols and hydroperoxides with carbonyls, carboxylates, and acetylacetonates of variable-valence metals were determined. The complexes of s and 3d elements with hydroperoxides have different structures.

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Authors and Affiliations

  1. St. Petersburg State Technological Institute, St. Petersburg, Russia

    A. M. Syroezhko & V. A. Proskuryakov

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  1. A. M. Syroezhko
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  2. V. A. Proskuryakov
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Translated from Zhurnal Prikladnoi Khimii, Vol. 77, No. 12, 2004, pp. 2011–2017.

Original Russian Text Copyright © 2004 by Syroezhko, Proskuryakov.

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Syroezhko, A.M., Proskuryakov, V.A. Complex formation of carbonyls, carboxylates, and acetylacetonates of main-group and transition metals with hydroperoxides and alcohols. Russ J Appl Chem 77, 1987–1993 (2004). https://doi.org/10.1007/s11167-005-0205-3

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  • DOI: https://doi.org/10.1007/s11167-005-0205-3

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