Russian Journal of Applied Chemistry

, Volume 77, Issue 12, pp 1987–1993 | Cite as

Complex formation of carbonyls, carboxylates, and acetylacetonates of main-group and transition metals with hydroperoxides and alcohols

  • A. M. Syroezhko
  • V. A. Proskuryakov


The thermodynamic and structural parameters of complexes formed by secondary and tertiary alcohols and hydroperoxides with carbonyls, carboxylates, and acetylacetonates of variable-valence metals were determined. The complexes of s and 3d elements with hydroperoxides have different structures.


Alcohol Carboxylate Carbonyl Complex Formation Hydroperoxide 
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  1. 1.
    Syroezhko, A.M., Liquid-Phase Oxidation of Alkanes, Cycloalkanes, and Their Oxygen-Containing Derivatives with Oxygen and Ozone in the Presence of Compounds of s and 3d Elements, Doctoral Dissertation, Leningrad, 1985.Google Scholar
  2. 2.
    Swift, T.J. and Connick, R.B., J. Chem. Phys., 1962, vol. 37, pp. 307–320.Google Scholar
  3. 3.
    Svitych, R.B., NMR Study of Paramagnetic Complexes in Solutions, Cand. Sci. Dissertation, Donetsk, 1978.Google Scholar
  4. 4.
    Yablonskii, O.P., Complex Formation and Its Role in Oxidation and Separation of Hydrocarbons, Doctoral Dissertation, Ivanovo, 1979.Google Scholar
  5. 5.
    Svitych, R.B., Buchachenko, A.L., Yablonskii, O.P., et al., Kinet. Katal., 1974, vol. 15, no.5, pp. 1300–1306.Google Scholar
  6. 6.
    Gribov, A.A., Zolotov, Yu.A., and Noskova, MN., Zh. Strukt. Khim., 1968, vol. 9, no.3, pp. 448–457.Google Scholar
  7. 7.
    Bulgakova, G.M., Shchupik, A.N., Zamaraev, K.I., and Skibida, I.P., Dokl. Akad. Nauk SSSR, 1972, vol. 203, no.4, pp. 363–367.Google Scholar
  8. 8.
    Smirnov, P.A., Timofeeva, T.N., Syroezhko, A.M., et al., Zh. Org. Khim., 1974, vol. 10, no.9, pp. 1892–1896.Google Scholar
  9. 9.
    Lunenok-Burmakina, V.A., in Neorganicheskie perekisnye soedineniya (Inorganic Peroxy Compounds), Moscow: Nauka, 1975, pp. 27–38.Google Scholar
  10. 10.
    Sapunov, V.N., A Study of Hydroperoxide Epoxidation of Olefins, Doctoral Dissertation, Moscow, 1980.Google Scholar
  11. 11.
    Syrkin, V.G., Karbonily metallov (Metal Carbonyls), Moscow: Khimiya, 1983.Google Scholar
  12. 12.
    Mel’nichenko, N.A., Bazhanov, A.V., and Kupriyanov, A.S., Zh. Strukt. Khim., 2003, vol. 44, no.3, pp. 446–454.Google Scholar
  13. 13.
    Allakhverdov, G.R., Zh. Fiz. Khim., 1996, vol. 70, no.10, pp. 1828–1833.Google Scholar
  14. 14.
    Cao, Y., Gankin, M., and Betterton, E., Health Perspect., 1995, vol. 103, no.1, pp. 29–32.Google Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2004

Authors and Affiliations

  • A. M. Syroezhko
    • 1
  • V. A. Proskuryakov
    • 1
  1. 1.St. Petersburg State Technological InstituteSt. PetersburgRussia

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