Skip to main content

Advertisement

Log in

Study on the visible-light photocatalytic performance of Ag3PO4/Cu2O composite

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

Ag3PO4/Cu2O composites were prepared by a facile wet chemical method. The specimens were examined by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and UV–Vis diffuse reflectance spectroscopy. The specimens exhibited an excellent photocatalytic activity on the degradation of RhB than pure Ag3PO4 and Cu2O. Furthermore, the photocatalyst specimen was found to exhibit higher efficiency in hydrogen conversion. It was found that a 30 wt% Ag3PO4-loaded specimen showed an excellent hydrogen generation performance. The excellent photocatalytic activity was ascribed to the separation of e–h pairs via the Z-scheme method composed of Ag, Ag3PO4 and Cu2O. This study demonstrated the potential approach to the photocatalytic splitting water to release hydrogen as well as the environmental purification of organic pollutants under visible-light irradiation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. P.D. Tran, S.K. Batabyal, S.S. Pramana, J. Barber, L.H. Wong, S.C.J. Loo, Nanoscale 4, 3875 (2012)

    Article  CAS  PubMed  Google Scholar 

  2. Y.F. Zhao, Z.Y. Yang, Y.X. Zhang, L. Jing, X. Guo, Z.T. Ke, P.W. Hu, G.X. Wang, Y.M. Yan, K.N. Sun, J. Phys. Chem. C 118, 14238 (2014)

    Article  CAS  Google Scholar 

  3. Y.H. Su, S.H. Huang, P.Y. Kung, T.W. Shen, W.L. Wang, ACS Sustain. Chem. Eng. 3, 1965 (2015)

    Article  CAS  Google Scholar 

  4. O. Mehraj, N.A. Mir, B.M. Pirzada, S. Sabir, Appl. Surf. Sci. 332, 419 (2015)

    Article  CAS  Google Scholar 

  5. K. Zhong, J. Su, Spectrosc. Lett. 48, 553 (2015)

    Article  CAS  Google Scholar 

  6. K. Zhou, T. Zhang, Z. Wang, Phys. Scr. 90, 105701 (2015)

    Article  CAS  Google Scholar 

  7. S. Kumar, T. Surendar, A. Baruah, V. Shanker, J. Mater. Chem. A 1, 5333 (2013)

    Article  CAS  Google Scholar 

  8. D.L. Jiang, J.J. Zhu, M. Chen, J.M. Xie, J. Colloid Interface Sci. 417, 115 (2014)

    Article  CAS  PubMed  Google Scholar 

  9. J.C. Wang, L. Zhang, W.X. Fang, J. Ren, Y.Y. Li, H.C. Yao, J.S. Wang, Z.J. Li, A.C.S. Appl, Mater. Interfaces 7, 8631 (2015)

    Article  CAS  Google Scholar 

  10. L.Q. Ye, J.Y. Liu, C.Q. Gong, L.H. Tian, T.Y. Peng, L. Zan, ACS Catal. 2, 1677 (2012)

    Article  CAS  Google Scholar 

  11. T.T. Yang, W.T. Chen, Y.J. Hsu, K.H. Wei, T.Y. Lin, T.W. Lin, Appl. Catal. B 163, 343 (2015)

    Article  CAS  Google Scholar 

  12. Y.H. Chiu, Y.J. Hsu, Nano Energy 31, 286 (2017)

    Article  CAS  Google Scholar 

  13. Y.W. Su, W.H. Lin, Y.J. Hsu, K.H. Wei, Small 10, 4427 (2014)

    Article  CAS  PubMed  Google Scholar 

  14. J.M. Li, H.Y. Cheng, Y.H. Chiua, Y.J. Hsu, Nanoscale 8, 15720 (2016)

    Article  CAS  PubMed  Google Scholar 

  15. A. Abulizi, G.H. Yang, J.J. Zhu, Ultrason. Sonochem. 21, 129 (2014)

    Article  CAS  PubMed  Google Scholar 

  16. Y.L. Tian, B.B. Chang, J. Fu, B.C. Zhou, J.Y. Liu, F.N. Xi, X.P. Dong, J. Solid State Chem. 212, 1 (2014)

    Article  CAS  Google Scholar 

  17. P.Z. He, L.M. Song, S.J. Zhang, X.Q. Wu, Q.W. Wei, Mater. Res. Bull. 51, 432 (2014)

    Article  CAS  Google Scholar 

  18. Y.D. Luo, Q.Q. Huang, B. Li, L.H. Dong, M.G. Fan, F.Y. Zhang, Appl. Surf. Sci. 357, 1072 (2015)

    Article  CAS  Google Scholar 

  19. M.Y. Zhang, L. Lia, X.T. Zhang, RSC Adv. 5, 29693 (2015)

    Article  CAS  Google Scholar 

  20. L.L. Sun, G.H. Wang, R.R. Hao, D.Y. Han, S. Cao, Appl. Surf. Sci. 358, 91 (2015)

    Article  CAS  Google Scholar 

  21. H. Zhang, G. Wang, D. Chen, X. Lv, J. Li, Chem. Mater. 20, 6543 (2008)

    Article  CAS  Google Scholar 

  22. Y.C. Pu, H.Y. Chou, W.S. Kuo, K.H. Wei, Y.J. Hsub, Appl. Catal. B 204, 21 (2017)

    Article  CAS  Google Scholar 

  23. T.T. Yang, W.T. Chen, Y.J. Hsu, K.H. Wei, T.Y. Lin, T.W. Lin, J. Phys. Chem. C 114, 11414 (2010)

    Article  CAS  Google Scholar 

  24. Y.M. He, L.H. Zhang, B.T. Teng, M.H. Fan, Environ. Sci. Technol. 49, 649 (2015)

    Article  CAS  PubMed  Google Scholar 

  25. Y.P. Zang, L.P. Li, X.G. Li, R. Lin, G.S. Li, Chem. Eng. J. 246, 277 (2014)

    Article  CAS  Google Scholar 

  26. G.T. Li, K.H. Wong, X.W. Zhang, C. Hu, J.C. Yu, R.C.Y. Chan, P.K. Wong, Chemosphere 76, 1185 (2009)

    Article  CAS  PubMed  Google Scholar 

  27. Y.M. He, L.H. Zhang, B.T. Teng, M.H. Fan, Sci. Technol. 49, 649 (2015)

    Article  CAS  Google Scholar 

  28. O. Mehraja, N.A. Mirb, B.M. Pirzadaa, S. Sabir, Appl. Surf. Sci. 332, 419 (2015)

    Article  CAS  Google Scholar 

  29. Y.L. Tian, B.B. Chang, J. Fu, B.C. Zhou, J.Y. Liu, F.N. Xi, X.P. Dong, J. Solid State Chem. 212, 1 (2014)

    Article  CAS  Google Scholar 

  30. A.L. Wang, X.S. Li, Y.B. Zhao, W. Wu, J.F. Chen, H. Meng, Powder Technol. 261, 42 (2014)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The present work is supported by the National Natural Science Foundation of China (No. 51472123).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Kun Zhong.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhong, K., Su, J. Study on the visible-light photocatalytic performance of Ag3PO4/Cu2O composite. Res Chem Intermed 45, 1207–1216 (2019). https://doi.org/10.1007/s11164-018-3662-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11164-018-3662-z

Keywords

Navigation