Abstract
Supported cobalt oxides on mesoporous nitrogen-doped carbon (CoxOy/NC) were prepared by a simple pyrolysis method using cobalt acetate as the cobalt source and chitosan as the nitrogen and carbon source. The as-synthesized catalysts were characterized by XRD, N2 adsorption/desorption, SEM, TEM and XPS. It was found that chitosan was transformed to mesoporous carbon after pyrolysis at 900 °C under N2 atmosphere, while Co2+ was reduced to metallic Co covering with cobalt oxide, which was uniformly distributed in the surface of carbon. The catalytic performances were examined by Acid Orange 7 (AO7) degradation with H2O2 as an oxidant in bicarbonate aqueous solution. The dye was decolorized completely after 20 min at room temperature with the CoxOy/NC catalyst. The catalyst can be recycled up to four times without significant loss of activity. The addition of methanol as a hydroxyl radical scavenger confirmed that the radicals take part in the reaction as the major active species. In addition, intermediate products were identified by electrospray ionization-mass spectrometry during the degradation of AO7.
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Acknowledgements
The authors gratefully acknowledge the financial support provided by China Postdoctoral Science Special Foundation (No. 201104457) and the Open Fund from Hubei Biomass-Resource Chemistry and Environmental Biotechnology Key Laboratory (Wuhan University).
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Zhong, H., Duan, L., Ye, P. et al. Synthesis of cobalt–nitrogen-doped mesoporous carbon from chitosan and its performance for pollutant degradation as Fenton-like catalysts. Res Chem Intermed 45, 907–918 (2019). https://doi.org/10.1007/s11164-018-3655-y
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DOI: https://doi.org/10.1007/s11164-018-3655-y