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Spectrochemical and theoretical approaches for acylhydrazone-based fluoride sensors

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Abstract

Acylhydrazone derivatives N′-[1-(2-fluorophenyl)ethylidene]pyridine-3-carbohydrazide (R1) and N′-[2-fluorobenzylidene]benzohydrazide (R2) were synthesized from their corresponding hydrazides and characterized by spectroscopic methods. The response of these acylhydrazones towards different anions was studied by colorimetric and spectrofluorometric methods in acetonitrile. The receptors exhibited a specific response towards fluoride ion. The binding affinity of the receptors with fluoride anion was studied by fluorescence spectroscopic techniques and ab initio density functional theory calculations with Becker’s three-parameter Lee–Yang–Par (B3LYP) exchange functional with 6-311G basis set.

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Acknowledgements

P.B.S. is grateful for financial support from CHRIST (Deemed to be University), Bengaluru.

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Authors and Affiliations

  1. Department of Chemistry, CHRIST (Deemed to be University), Hosur Road, Bangalore, 560029, India

    Jemini Jose, Athira M. John & P. B. Sreeja

  2. Department of Chemistry, National Institute of Technology, Tiruchirappalli, 620015, India

    A. Sreekanth & Sabeel M. Basheer

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  1. Jemini Jose
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  2. A. Sreekanth
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  3. Athira M. John
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  4. Sabeel M. Basheer
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  5. P. B. Sreeja
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Correspondence to P. B. Sreeja.

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Jose, J., Sreekanth, A., John, A.M. et al. Spectrochemical and theoretical approaches for acylhydrazone-based fluoride sensors. Res Chem Intermed 45, 425–435 (2019). https://doi.org/10.1007/s11164-018-3609-4

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