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Effect of solvated ionic liquids on the ion conducting property of composite membranes for lithium ion batteries

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Abstract

We prepared the polyethylene oxide (PEO)-based composite membrane electrolytes which contained the specialized ionic liquids and the inorganic filler of Li7La3Zr2O12 (LLZO). Mixtures of ionic liquids and tetragonal inorganic fillers were used as additives to prepare composite electrolytes for an application of all solid-state lithium ion batteries (ASLBs). In order to improve the ionic conductivity of composite membranes, we studied the structural change and the electrochemical behaviors as a function of the amounts of solvated ionic liquids (ILs). The addition effect of solvated ILs showed the higher ionic conductivity such as 10−4 S/cm at 55 °C by reducing the crystalline character of polymer based composite, resulting in the enhanced ion conducting property. The hybrid composite membranes were successfully made in flexible form, and have an excellent thermal and electrochemical stability. Finally, the electrochemical performance of the half-cell was evaluated, and it was confirmed that the ion-conducting characteristics were influenced and controlled by the effect of ILs.

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References

  1. Y. Inaguma, L.Q. Chen, M. Itoh, T. Nakamura, T. Uchida, H. Ikuta, M. Wakihara, Solid State Commun. 86, 689 (1993)

    Article  CAS  Google Scholar 

  2. J. Fu, J. Am. Ceram. Soc. 80, 1901 (1997)

    Article  CAS  Google Scholar 

  3. R. Kanno, M. Maruyama, J. Electrochem. Soc. 148, A742 (2001)

    Article  CAS  Google Scholar 

  4. A. Hayashi, S. Hama, T. Minami, M. Tatsumisago, Electrochem. Commun. 5, 111 (2003)

    Article  CAS  Google Scholar 

  5. B. Scrosati, F. Croce, L. Persi, J. Electrochem. Soc. 147, 1718 (2000)

    Article  CAS  Google Scholar 

  6. L. Persi, F. Croce, B. Scrosati, E. Plichta, M.A. Hendrickson, J. Electrochem. Soc. 149, A212 (2002)

    Article  CAS  Google Scholar 

  7. G.B. Appetecchi, F. Croce, G. Dautzenberg, M. Mastragostino, F. Ronci, B. Scrosati, F. Soavi, A. Zaneli, F. Alessandrini, P.P. Prosini, J. Electrochem. Soc. 145, 4126 (1998)

    Article  CAS  Google Scholar 

  8. G.B. Appetecchi, S. Passerini, Electrochim. Acta 45, 2139 (2000)

    Article  CAS  Google Scholar 

  9. S.J. Lee, S.J. Park, S. Kim, J. Nanosci. Nanotechnol. 17(8), 5768 (2017)

    Article  CAS  Google Scholar 

  10. J.H. Choi, C.H. Lee, J.H. Yu, C.H. Doh, S.M. Lee, J. Electrochem. Soc. 274, 458 (2015)

    CAS  Google Scholar 

  11. V. Thangadurai, W. Weppner, J. Solid State Chem. 179, 974 (2006)

    Article  CAS  Google Scholar 

  12. R. Murugan, V. Thangadurai, W. Weppner, Ionics 13, 195 (2007)

    Article  CAS  Google Scholar 

  13. A. Kaeriyama, H. Munakata, K. Kajihara, K. Kanamura, Y. Sato, T. Yoshida, ECS Trans. 16, 175 (2009)

    Article  CAS  Google Scholar 

  14. M. Kotobuki, H. Munakata, K. Kanamura, Y. Sato, T. Yoshida, J. Electrochem. Soc. 157, A1076 (2010)

    Article  CAS  Google Scholar 

  15. V. Thangadurai, H. Kaack, W. Weppner, J. Am. Ceram. Soc. 86, 437 (2003)

    Article  CAS  Google Scholar 

  16. V. Thangadurai, W. Weppner, Adv. Funct. Mater. 15, 107 (2005)

    Article  CAS  Google Scholar 

  17. V. Thangadurai, W. Weppner, J. Am. Ceram. Soc. 88, 411 (2005)

    Article  CAS  Google Scholar 

  18. S.S. Zhang, K. Xu, T.R. Jow, Electrochim. Acta 49, 1057 (2004)

    Article  CAS  Google Scholar 

  19. S. Ito, S. Fujiki, T. Yamada, Y. Aihara, Y. Park, T.Y. Kim, S.W. Baek, J.M. Lee, S. Doo, N. Machida, J. Electrochem. Soc. 248, 943 (2014)

    CAS  Google Scholar 

  20. S.S. Zhang, K. Xu, T.R. Jow, Electrochim. Acta 51, 1636 (2006)

    Article  CAS  Google Scholar 

  21. K. Yoshida, M. Nakamura, Y. Kazue, N. Tachikawa, S. Tsuzuki, S. Seki, K. Dokko, M. Watanabe, J. Am. Ceram. Soc. 133, 13121 (2011)

    CAS  Google Scholar 

  22. T. Tamura, K. Yoshida, T. Hachida, M. Tsuchiya, M. Nakamura, Y. Kazue, N. Tachikawa, K. Dokko, M. Watanabe, Chem. Lett. Soc. 39, 753 (2010)

    Article  CAS  Google Scholar 

  23. K. Yoshida, M. Tsuchiya, N. Tachikawa, K. Dokko, M. Watanabe, J. Phys. Chem. C 115, 18384 (2011)

    Article  CAS  Google Scholar 

  24. K. Yoshida, M. Tsuchiya, N. Tachikawa, K. Dokko, M. Watanabe, J. Electrochem. Soc. 159, A1005 (2012)

    Article  CAS  Google Scholar 

  25. T. Welton, Chem. Rev. 99, 2071 (1999)

    Article  CAS  PubMed  Google Scholar 

  26. P. Wasserscheid, W. Keim, Angew. Chem. Int. Ed. 39, 3772 (2000)

    Article  CAS  Google Scholar 

  27. B.R. Choi, S.J. Park, S. Kim, J. Nanosci. Nanotechnol. 16(9), 9149 (2016)

    Article  CAS  Google Scholar 

  28. B.R. Choi, S.J. Park, S. Kim, J. Nanosci. Nanotechnol. 16(3), 2765 (2016)

    Article  CAS  PubMed  Google Scholar 

  29. K.M. Kim, S.J. Park, J.S. Im, C.W. Lee, Y. Jung, S. Kim, Carbon Lett. 17(1), 70 (2016)

    Article  Google Scholar 

  30. B.R. Choi, S.J. Park, S. Kim, J. Ind. Eng. Chem. 31, 352 (2015)

    Article  CAS  Google Scholar 

  31. M.G. Kim, I.J. Kim, Y. Jung, S. Kim, Res. Chem. Int. 41, 4749 (2015)

    Article  CAS  Google Scholar 

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Acknowledgements

This research was supported by Korea Electrotechnology Research Institute (KERI) Primary research program through the National Research Council of Science and Technology (NST) funded by the Ministry of Science, ICT and Future Planning (MSIP) (No. 17-12-N0101-35).

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Authors and Affiliations

  1. Battery Research Center, Korea Electrotechnology Research Institute, 12 Bulmosan-ro10beon-gil, Seongsan-gu, Changwon, 51543, Republic of Korea

    Jae-Yeong Park, Jun-Woo Park, Chil-Hoon Doh, Yoon-Cheol Ha & Sang-Min Lee

  2. Department of Chemical and Biomolecular Engineering, Pusan National University, 2, Busandaehak-ro 63 beon-gil, Geumjung, Busan, 46241, Republic of Korea

    Jae-Yeong Park & Seok Kim

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  1. Jae-Yeong Park
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  2. Jun-Woo Park
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  3. Chil-Hoon Doh
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  4. Yoon-Cheol Ha
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  5. Sang-Min Lee
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  6. Seok Kim
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Correspondence to Jun-Woo Park or Seok Kim.

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Park, JY., Park, JW., Doh, CH. et al. Effect of solvated ionic liquids on the ion conducting property of composite membranes for lithium ion batteries. Res Chem Intermed 44, 6039–6051 (2018). https://doi.org/10.1007/s11164-018-3474-1

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  • DOI: https://doi.org/10.1007/s11164-018-3474-1

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