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Pd salen complex@CPGO as a convenient, effective heterogeneous catalyst for Suzuki–Miyaura and Heck–Mizoroki cross-coupling reactions

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Abstract

A Pd(II) Schiff base complex supported on graphene oxide nanosheets (Pd(II) salen@CPGO) has been synthesized and characterized by FT-IR, ICP-AES, XRD, SEM/EDX and TEM. The synthesized nanocatalyst has been found to be an efficient heterogeneous catalyst for Suzuki–Miyaura and Heck–Mizoroki coupling reactions. Pd(II) salen@CPGO could be separated and recovered easily from the reaction mixture and recycled several times without a discernible decrease in its catalytic activity. The construction of a solid sheet-supported Pd catalyst would be expected to be a promising system to perform heterogeneous catalytic reactions.

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Acknowledgements

The authors are grateful to the University of Birjand for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Birjand, P. O. Box 97175-615, Birjand, Iran

    Mahdieh Ghabdian, Mohammad Ali Nasseri & Ali Allahresani

  2. Department of Chemistry, School of Sciences, Islamic Azad University, Neyshabur Branch, P. O. Box 9318813-639, Neyshabur, Iran

    Alireza Motavallizadehkakhky

Authors
  1. Mahdieh Ghabdian
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  2. Mohammad Ali Nasseri
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  3. Ali Allahresani
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  4. Alireza Motavallizadehkakhky
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Correspondence to Mahdieh Ghabdian.

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Ghabdian, M., Nasseri, M.A., Allahresani, A. et al. Pd salen complex@CPGO as a convenient, effective heterogeneous catalyst for Suzuki–Miyaura and Heck–Mizoroki cross-coupling reactions. Res Chem Intermed 47, 1713–1728 (2021). https://doi.org/10.1007/s11164-018-3455-4

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