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Modified generalized kinetic model and degradation mechanistic pathways for catalytic oxidation of NBS dye in Fenton-like oxidation process

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Abstract

Rice husk was utilized as a silica source for the synthesis of mesoporous silica (MS), which was further used for the surface modification of iron oxide nanoparticles (IO-NPs) to form mesoporous silica-modified iron oxide nanoparticles (MSIO-NPs). IO-NPs and MSIO-NPs were characterized using FT-IR, XRD, X-ray photoelectron spectroscopy, vibrating sample magnetometry, nitrogen adsorption–desorption, TEM and dynamic light scattering analysis. The catalytic activity of MSIO-NPs was tested for degradation and mineralization of Nile blue sulphate dye (NBS) in Fenton-like oxidation process. The degradation efficiency and total organic carbon (TOC) removal of NBS dye onto MSIO-NPs was found to be 92.46 and 66.58%, respectively, after 20 min of reaction time using 5 mM of H2O2 concentration. Modified generalized kinetic model was developed for TOC removal of dye degradation onto MSIO-NPs, to account for oxidizable compounds, non-oxidizable compounds, and intermediate organic compounds. The intermediate products formed during degradation of NBS dye were detected by LC–MS experiment and ten fragments were identified based on mass to charge ratio (m/z). The mechanistic pathway for degradation of NBS dye onto MSIO-NPs has been proposed.

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References

  1. K. Hunger, Industrial Dyes: Chemistry, Properties, Applications, vol. 125 (Wiley-CH, Weinheim, 2003), p. 10144

    Google Scholar 

  2. S. Ekici, I. Yasemin, D. Sarayd, Polym. Bull. 241, 231 (2006)

    Article  Google Scholar 

  3. M. Iram, C. Guo, Y. Guan, A. Ishfaq, H. Liu, J. Hazard. Mater. 181, 1039 (2010)

    Article  CAS  PubMed  Google Scholar 

  4. M. Munoz, Z.M. De Pedro, J.A. Casas, J.J. Rodriguez, Appl. Catal. B Environ. 176–177, 249 (2015)

    Article  Google Scholar 

  5. P. Xu, G. Ming, D. Lian, C. Ling, S. Hu, M. Hua, Sci. Total Environ. 424, 1 (2012)

    Article  CAS  PubMed  Google Scholar 

  6. R.D. Ambashta, M. Sillanpaa, J. Hazard. Mater. 180, 38 (2010)

    Article  CAS  PubMed  Google Scholar 

  7. M. Hua, S. Zhang, B. Pan, W. Zhang, L. Lv, Q. Zhang, J. Hazard. Mater. 211–212, 317 (2012)

    Article  PubMed  Google Scholar 

  8. S. Karthikeyeni, T.S. Vijayakumar, S. Vasanth, J. Exp. Nanosci. 10, 199–208 (2013)

    Article  Google Scholar 

  9. N.N. Nassar, J. Hazard. Mater. 184, 538 (2010)

    Article  CAS  PubMed  Google Scholar 

  10. M. Minella, G. Marchetti, E. De Laurentiis, M. Malandrino, V. Maurino, C. Minero, D. Vione, K. Hanna, E. De Laurentiis, M. Malandrino, V. Maurino, C. Minero, D. Vione, K. Hanna, Appl. Catal. B Environ. 154–155, 102 (2014)

    Article  Google Scholar 

  11. W. Wang, Y. Liu, T. Li, M. Zhou, Chem. Eng. J. 242, 1 (2014)

    Article  CAS  Google Scholar 

  12. W. Wu, Q. He, C. Jiang, Nanoscale Res. Lett. 3, 397 (2008)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  13. N. Arsalani, Express Polym. Lett. 4, 329 (2010)

    Article  CAS  Google Scholar 

  14. S.I.C.J. Palma, A. Carvalho, J. Silva, P. Martins, M. Marciello, A.R. Fernandes, M. del Puerto Morales, A.C.A. Roque, Contrast Media Mol. Imaging 10, 320 (2015)

    Article  CAS  PubMed  Google Scholar 

  15. F. Ge, M.-M. Li, H. Ye, B.-X. Zhao, J. Hazard. Mater. 211–212, 366 (2012)

    Article  PubMed  Google Scholar 

  16. H.Y. Shen, Y. Zhang, Q.F. Mao, Y.G. Zhao, S.D. Pan, Int. Rev. Chem. Eng. 4, 359 (2012)

    Google Scholar 

  17. S. Lee, C. Laldawngliana, D. Tiwari, Chem. Eng. J. 195–196, 103 (2012)

    Article  Google Scholar 

  18. M.E. Mahmoud, M.S. Abdelwahab, E.M. Fathallah, Chem. Eng. J. 223, 318 (2013)

    Article  CAS  Google Scholar 

  19. M.A. Morales, A.J.S. Mascarenhas, A.M.S. Gomes, C.A.P. Leite, H.M.C. Andrade, C.M.C. de Castilho, F. Galembeck, J. Colloid Interface Sci. 342, 269 (2010)

    Article  CAS  PubMed  Google Scholar 

  20. N. Panda, H. Sahoo, S. Mohapatra, J. Hazard. Mater. 185, 359 (2011)

    Article  CAS  PubMed  Google Scholar 

  21. D. Lewandowski, M. Smoluch, E. Reszke, Microporous Mesoporous Mater. 240, 80 (2017)

    Article  CAS  Google Scholar 

  22. K. Li, Z. Zeng, J. Xiong, L. Yan, H. Guo, S. Liu, Y. Dai, T. Chen, Colloids Surf. A Physicochem. Eng. Asp. 465, 113 (2015)

    Article  CAS  Google Scholar 

  23. D. Mittal, Resonance 2(7), 64 (1997)

    Article  CAS  Google Scholar 

  24. A.N. Soon, B.H. Hameed, Appl. Catal. A Gen. 450, 96 (2013)

    Article  CAS  Google Scholar 

  25. Y. Wang, J. Ren, X. Liu, Y. Wang, Y. Guo, Y. Guo, G. Lu, J. Colloid Interface Sci. 326, 158 (2008)

    Article  CAS  PubMed  Google Scholar 

  26. H.I. Melendez-Ortiz, A. Mercado-Silva, L.A. García-Cerda, G. Castruita, Y.A. Perera-Mercado, J. Mex. Chem. Soc. 57, 73 (2013)

    CAS  Google Scholar 

  27. R. Ahmadi, M. Malek, H. Reza, M. Hosseini, M.A. Shokrgozar, M.A. Oghabian, A. Masoudi, N. Gu, Y. Zhang, Mater. Chem. Phys. 131, 170 (2011)

    Article  CAS  Google Scholar 

  28. H.H. Jiang, X.Y. Han, Z.L. Li, X.C. Chen, Y.H. Hou, L.G. Gai, D.C. Li, X.R. Lu, T.L. Fu, Colloid. Surf. A 401, 74 (2012)

    Article  CAS  Google Scholar 

  29. M. Mahdavi, M. Bin Ahmad, M.J. Haron, F. Namvar, B. Nadi, M.Z.A. Rahman, J. Amin, Molecules 18, 7533 (2013)

    Article  CAS  PubMed  Google Scholar 

  30. M. Mahdavi, F. Namvar, M. Bin Ahmad, R. Mohamad, Molecules 18, 5954 (2013)

    Article  PubMed  Google Scholar 

  31. J. Pires, S. Borges, A. Carvalho, C. Pereira, A.M. Pereira, C. Fernandes, J.P. Araújo, C. Freire, Polyhedron 106, 125 (2016)

    Article  CAS  Google Scholar 

  32. G.E.A. Mahmoud, L.F.M. Ismail, J. Basic Appl. Chem. 1, 70 (2011)

    Google Scholar 

  33. A. Babuponnusami, K. Muthukumar, Sep. Purif. Technol. 98, 130 (2012)

    Article  CAS  Google Scholar 

  34. L. Xu, J. Wang, J. Hazard. Mater. 186, 256 (2011)

    Article  CAS  PubMed  Google Scholar 

  35. T.R. Sundararaman, Mod. Appl. Sci. 3, 15 (2009)

    Article  CAS  Google Scholar 

  36. F. Martı, J.A. Melero, G. Calleja, R. Molina, Appl. Catal. B 60, 181 (2005)

    Article  Google Scholar 

  37. M. Arshadi, M.K. Abdolmaleki, F. Mousavinia, H. Firouzabadi, A. Gil, Chem. Eng. Res. Des. 112, 113 (2016)

    Article  CAS  Google Scholar 

  38. J.H. Ramirez, F.J. Maldonado-Hódar, A.F. Pe, C. Moreno-castilla, C.A. Costa, L.M. Madeira, Appl. Catal. B 75, 312 (2007)

    Article  CAS  Google Scholar 

  39. M.E. Argun, M. Karatas, Environ. Prog. Sustain. Energy 30, 540 (2011)

    Article  CAS  Google Scholar 

  40. L. Wang, J. Yang, Y. Li, J. Lv, J. Zou, Chem. Eng. J. 284, 1058 (2016)

    Article  CAS  Google Scholar 

  41. D. Singh, K. Mishra, G. Ramanthan, Wastewater Treatment Engineering (InTech, Rijeka, 2015)

    Google Scholar 

  42. S. Xavier, R. Gandhimathi, P.V. Nidheesh, R.T. Sreekrishnaperumal, Desalin Water Treatm 53(1), 109 (2015)

    Article  CAS  Google Scholar 

  43. J. Jiang, J. Zou, L. Zhu, L. Huang, H. Jiang, Y. Zhang, J. Nanosci. Nanotechnol. 11, 4793 (2011)

    Article  CAS  PubMed  Google Scholar 

  44. C. Nadejde, M. Neamtu, R.J. Schneider, V.-D. Hodoroaba, G. Ababei, U. Panne, Appl. Surf. Sci. 352, 42 (2015)

    Article  CAS  Google Scholar 

  45. X. Zhong, S. Royer, H. Zhang, Q. Huang, L. Xiang, S. Valange, J. Barrault, Sep. Purif. Technol. 80, 163 (2011)

    Article  CAS  Google Scholar 

  46. A.E. Nogueira, I.A. Castro, A.S. Giroto, Z.M. Magriotis, Catalysts 2014, 1 (2014)

    Article  Google Scholar 

  47. H. Aliyan, R. Fazaeli, R. Jalilian, Appl. Surf. Sci. 276, 147 (2013)

    Article  CAS  Google Scholar 

  48. H. Xie, W. He, G. Chen, J. Chin. Chem. Soc. 62, 1144 (2015)

    Article  Google Scholar 

  49. X. Tang, Q. Feng, K. Liu, Z. Li, H. Wang, J. Mater. Sci. 53, 369–384 (2018)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemical Engineering, Dr B R Ambedkar National Institute of Technology, Jalandhar, 144011, India

    Rajkamal Kushwaha, Sangeeta Garg & Shailendra Bajpai

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  1. Rajkamal Kushwaha
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  2. Sangeeta Garg
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  3. Shailendra Bajpai
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Correspondence to Sangeeta Garg.

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Kushwaha, R., Garg, S. & Bajpai, S. Modified generalized kinetic model and degradation mechanistic pathways for catalytic oxidation of NBS dye in Fenton-like oxidation process. Res Chem Intermed 44, 5759–5786 (2018). https://doi.org/10.1007/s11164-018-3453-6

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  • DOI: https://doi.org/10.1007/s11164-018-3453-6

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