Synthesis of a novel DABCO-based nanomagnetic catalyst with sulfonic acid tags: application to the synthesis of diverse spiropyrans

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Abstract

In this paper, sulfonic acid functionalized 1,4-diazabicyclo[2.2.2]octane (DABCO)-based magnetic nanoparticle Fe3O4 [Fe3O4@SiO2@Pr-DABCO-SO3H]Cl2 was synthesized and fully characterized using various techniques. Then the catalyst was examined for the convenient synthesis of spiropyran derivatives, resulting in high reaction yields, short reaction times, and the recovery and reusability of the catalyst.

Graphical Abstract

Keywords

Sulfonic acid 1,4-Diazabicyclo[2.2.2]octane (DABCO) [Fe3O4@SiO2@(CH2)3-DABCO-SO3H]Cl2 Recyclable nanocatalyst Spiropyran derivatives 

Notes

Acknowledgements

We thank Bu-Ali Sina University, National Elites Foundation and the Iran National Science Foundation (INSF) (Grant Number: 940124) for financial support of our research groups.

Supplementary material

11164_2018_3421_MOESM1_ESM.docx (6.7 mb)
Supplementary material 1 (DOCX 6840 kb)

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© Springer Science+Business Media B.V., part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of Organic Chemistry, Faculty of ChemistryBu-Ali Sina UniversityHamedanIran

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