Abstract
A rhodamine-conjugated coumarin (L) was used in designing a selective fluorescence chemosensor for the determination of trace amounts of Cr3+ ions in acetonitrile–water (MeCN/H2O (90:10, %v/v) solutions. The intensity of the fluoresce emission of the chemosensor is intensified upon addition of Cr3+ ions in MeCN/H2O (90:10, %v/v) solutions, due to the formation of a selective 1:1 complex between L and Cr3+ ions. The fluorescence enhancement versus Cr3+ concentration has been found to be linear from 1.0 × 10−7 to 1.8 × 10−5 M and a detection limit of 7.5 × 10−8 M. The proposed fluorescent probe proved to be highly selective towards Cr3+ ions as compared to other common metal ions and could be successfully applied to the determination of Cr3+ concentrations in some water and wastewater samples.
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The authors thank the research Council of University of Tehran (Grant 28645/01/02) for financial support of this work.
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Hosseini, M., Khoobi, M., Tarasi, R. et al. A selective colorimetric and fluorescence chemosensing sensor for Cr3+ based on a rhodamine base derivative. Res Chem Intermed 44, 5031–5042 (2018). https://doi.org/10.1007/s11164-018-3407-z
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DOI: https://doi.org/10.1007/s11164-018-3407-z