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Nanomagnetite-supported molybdenum oxide (nanocat-Fe-Mo): an efficient green catalyst for multicomponent synthesis of amidoalkyl naphthols

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Abstract

Magnetite (Fe3O4)-supported molybdenum oxide (MoO3) was synthesized from simple starting precursors in aqueous medium. The synthesized nanocat-Fe-Mo was analyzed using several techniques such as X-ray diffraction (XRD) analysis, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and vibrating-sample magnetometry (VSM). The catalytic activity of the synthesized nanocat-Fe-Mo was studied in a benign one-pot multicomponent transformation for synthesis of amidoalkyl naphthol derivatives under solvent-free condition using both conventional and microwave irradiation methods. Nanocat-Fe-Mo was found to be highly active and could be reused seven times without notable loss in catalytic activity. The proposed method offers advantages such as good reaction yield (80–95%), short process time, simple workup, and recycling of the catalyst, representing important green chemistry principles.

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Scheme 1
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Abbreviations

Ar:

Aryl

CCD:

Charge coupled device

DMF:

Dimethyl formamide

DMSO:

Dimethylsulfoxide

EDS:

Energy dispersive spectroscopy

Fe-Mo:

Ferrite-molybdenum

FT-IR:

Fourier-transform infrared

FWHM:

Full width at half maximum

HIV:

Human immunodeficiency virus

ICP-AES:

Inductively coupled plasma-atomic emission spectroscopy

LFD:

Large field detector

MNPs:

Magnetic nanoparticles

MP:

Melting point

MW:

Microwave

NMR:

Nuclear magnetic resonance

NP:

Nanoparticle

Ph:

Phenyl

ppm:

Parts per million

RBF:

Round-bottomed flask

RF:

Radiofrequency

RT:

Room temperature

SEM:

Scanning electron microscopy

TEM:

Transmission electron microscopy

TLC:

Thin-layer chromatography

TMS:

Tetramethylsilane

UV:

Ultraviolet

VSM:

Vibrating-sample magnetometry

XRD:

X-ray diffraction

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Acknowledgements

S.R.B. gratefully thanks the BCUD, Savitribai Phule Pune University, Pune for granting research stipend. The authors are grateful to the Director of SAIF, Panjab University (Chandigarh, India) for spectral analysis. S.R.B. thanks Dr. M. B. Gawande for constant inspiration. We also acknowledge the HOD and Principal, S.S.G.M. College, Kopargaon, Ahmednagar (MH) for providing research facilities.

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Authors and Affiliations

  1. P. G. and Research Centre, Department of Chemistry, S.S.G.M. College, Kopargaon, Ahmednagar, MS, 423601, India

    Swapnil R. Bankar & Sharad N. Shelke

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  1. Swapnil R. Bankar
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  2. Sharad N. Shelke
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Correspondence to Sharad N. Shelke.

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Supporting information file: spectral analysis data (DOC 2676 kb)

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Bankar, S.R., Shelke, S.N. Nanomagnetite-supported molybdenum oxide (nanocat-Fe-Mo): an efficient green catalyst for multicomponent synthesis of amidoalkyl naphthols. Res Chem Intermed 44, 3507–3521 (2018). https://doi.org/10.1007/s11164-018-3321-4

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