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Poly(vinylimidazolum acetic acid)-entrapped nanozeolite: efficient heterogeneous catalyst for synthesis of polyhydroquinolines and 1,4-dihydropyridines

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Abstract

An effective method for synthesis of substituted 1,4-dihydropyridines and polyhydroquinoline derivatives by Hantzsch reaction using poly(ionic liquid)-based nanozeolite (NZ@PIL-COOH) catalyst under simple conditions is described. The new solid acid catalyst was prepared by polymerization of 3-carboxymethyl-1-vinylimidazolium in presence of modified nanozeolite, and characterized by Fourier-transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), X-ray diffraction (XRD) analysis, and transmission electron microscopy (TEM). The resulting heterogeneous catalyst displayed high catalytic performance under mild reaction condition in short reaction time. The catalyst was recycled eight times without any loss in reactivity or yield.

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Acknowledgements

This research is supported by the Islamic Azad University, Ayatollah Amoli Branch, I. R. Iran.

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Authors and Affiliations

  1. Department of Chemistry, Ayatollah Amoli Branch, Islamic Azad University, Amol, Iran

    Tabassom Amoli & Seyed Meysam Baghbanian

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  1. Tabassom Amoli
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  2. Seyed Meysam Baghbanian
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Correspondence to Seyed Meysam Baghbanian.

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Amoli, T., Baghbanian, S.M. Poly(vinylimidazolum acetic acid)-entrapped nanozeolite: efficient heterogeneous catalyst for synthesis of polyhydroquinolines and 1,4-dihydropyridines. Res Chem Intermed 44, 3389–3405 (2018). https://doi.org/10.1007/s11164-018-3314-3

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