Skip to main content
Log in

MCM-41@Cu–Fe–LDH magnetic nanoparticles modified with cationic surfactant for removal of Alizarin Yellow from water samples and its determination with HPLC

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

An adsorbent formed from MCM-41 and layered double hydroxides (LDH) coated on magnetic nanoparticles was synthesized and modified with a cationic surfactant (Fe3O4@MCM@Cu–Fe–LDH) for use in dispersive micro solid-phase extraction for removal of Alizarin Yellow (AY) (an anionic dye) prior to high-performance liquid chromatography–ultraviolet (HPLC–UV) detection. This adsorbent was obtained from mesopore MCM-41 coated with Fe3O4 as main core and Cu–Fe–layered double hydroxide (Cu–Fe–LDH) as nanoplatelet shell. The adsorbent was characterized by Fourier-transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX) analyses. Also, the surface morphology, Brunauer–Emmett–Teller (BET) specific surface area, and Barrett–Joyner–Halenda (BJH) pore size of the adsorbent were obtained. The adsorption isotherms were studied based on the Langmuir and Freundlich models. Adsorption data were successfully fit using the Langmuir model, showing maximum adsorption capacity of 121.95 mg g−1. The proposed method showed good linearity for AY with correlation coefficient R2 > 0.9998. The limit of detection was 0.5 µg L−1. Precision of 6.5% was obtained, as relative standard deviation (RSD) (n = 6). The method was successfully applied to determine AY in well and wastewater samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. M.B. Gholivand, Y. Yamini, M. Dayeni, Sh Seidi, E. Tahmasebi, J. Environ. Chem. Eng. 3, 529 (2015)

    Article  CAS  Google Scholar 

  2. K.T. Chung, S.E. Stevens Jr, Environ. Toxicol. Chem. 12, 2121 (1993)

    CAS  Google Scholar 

  3. L. Calvosa, A. Monteverdi, B. Rindone, G. Riva, Water Res. 25, 985 (1991)

    Article  CAS  Google Scholar 

  4. Y. Wang, Y. Zhao, Y. Ma, H. Liu, T. Wei, J. Mol. Catal. A Chem. 325, 79 (2010)

    Article  CAS  Google Scholar 

  5. M. Abbasi, J. Clean. Prod. 145, 105 (2017)

    Article  CAS  Google Scholar 

  6. Y. Zhu, P. Kolar, J. Environ. Chem. Eng. 2, 2050 (2014)

    Article  CAS  Google Scholar 

  7. S. Wang, H. Wu, J. Hazard. Mater. 136, 482 (2006)

    Article  CAS  Google Scholar 

  8. Y.X. Yang, J. Ma, Q.D. Qin, X.D. Zhai, J. Mol. Catal. A Chem. 267, 41 (2007)

    Article  CAS  Google Scholar 

  9. Y. Huang, J. Li, X. Chen, X. Wang, RSC Adv. 4, 62160 (2014)

    Article  CAS  Google Scholar 

  10. S. Zhang, M. Zeng, W. Xu, J. Li, J. Xu, X. Wang, Dalton Trans. 42, 7854 (2013)

    Article  CAS  Google Scholar 

  11. D. Shao, G. Hou, J. Li, T. Wen, X. Ren, X. Wang, Chem. Eng. J. 255, 604 (2014)

    Article  CAS  Google Scholar 

  12. E. Kazemi, A.M. Haji Shabani, Sh Dadfarnia, A. Abbasi, M.R. RashidianVaziri, A. Behjat, Anal. Chim. Acta 905, 85 (2016)

    Article  CAS  Google Scholar 

  13. W.H. Chung, S.H. Tzing, W.H. Ding, J. Chromatogr. A 1307, 34 (2013)

    Article  CAS  Google Scholar 

  14. S.P. Gao, T.H. Lu, S.P. Li, H. Zhong, Colloid Surf. A 351, 26 (2009)

    Article  CAS  Google Scholar 

  15. F. Kovanda, E. Jindová, K. Lang, P. Kubát, Z. Sedláková, Appl. Clay Sci. 48, 260 (2010)

    Article  CAS  Google Scholar 

  16. A.A. Matin, P. Biparva, H. Amanzadeh, K. Farhadi, Talanta 103, 207 (2013)

    Article  CAS  Google Scholar 

  17. Y.L. Liu, J.B. Zhou, R.S. Zhao, X.F. Chen, Anal. Bioanal. Chem. 404, 1603 (2012)

    Article  CAS  Google Scholar 

  18. H. Abdolmohammad-Zadeh, K. Tavarid, Z. Talleb, Sci. World J. 2012, 1 (2012)

    Article  Google Scholar 

  19. H. Abdolmohammad-Zadeh, S. Kohansal, G.H. Sadeghi, Talanta 84, 368 (2011)

    Article  CAS  Google Scholar 

  20. H. Abdolmohammad-Zadeh, Z. Rezvani, G.H. Sadeghi, E. Zorufi, Anal. Chim. Acta 685, 212 (2011)

    Article  CAS  Google Scholar 

  21. M. Saraji, M. Ghani, J. Chromatogr. A 1366, 24 (2014)

    Article  CAS  Google Scholar 

  22. G. Giakisikli, A.N. Anthemidis, Anal. Chim. Acta 789, 1 (2013)

    Article  CAS  Google Scholar 

  23. M. Shao, F. Ning, J. Zhao, M. Wei, D.G. Evans, X. Duan, J. Am. Chem. Soc. 134, 1071 (2012)

    Article  CAS  Google Scholar 

  24. H. Zhang, G. Zhang, X. Bi, X. Chen, J. Mater. Chem. A 1, 5934 (2013)

    Article  CAS  Google Scholar 

  25. F. Mi, X. Chen, Y. Ma, S. Yin, F. Yuan, H. Zhang, Chem. Commun. 47, 12804 (2011)

    Article  CAS  Google Scholar 

  26. D. Pan, H. Zhang, T. Fan, J. Chen, X. Duan, Chem. Commun. 47, 908 (2011)

    Article  CAS  Google Scholar 

  27. Y. Zhao, S. He, M. Wei, D.G. Evans, X. Duan, Chem. Commun. 46, 3031 (2010)

    Article  CAS  Google Scholar 

  28. A. Wongariyakawee, F. Schäeffel, J.H. Warner, D. O’Hare, J. Mater. Chem. 22, 7751 (2012)

    Article  CAS  Google Scholar 

  29. H. Zhang, D. Pan, K. Zou, J. He, X. Duan, J. Mater. Chem. 19, 3069 (2009)

    Article  CAS  Google Scholar 

  30. X. Zhao, Sh Liu, P. Wang, Zh Tang, H. Niu, Y. Cai, F. Wu, H. Wang, W. Meng, J.P. Giesy, J. Chromatogr. A 1414, 22 (2015)

    Article  CAS  Google Scholar 

  31. H. Niu, S. Zhang, X. Zhang, Y. Cai, ACS Appl. Mater. Interfaces 2, 1157 (2010)

    Article  CAS  Google Scholar 

  32. X. Zhao, Y. Shi, Y. Cai, S. Mou, Environ. Sci. Technol. 42, 1201 (2008)

    Article  CAS  Google Scholar 

  33. Y. Zou, Y. Chen, Z. Yan, C. Chen, J. Wang, S. Yao, Analyst 138, 5904 (2013)

    Article  CAS  Google Scholar 

  34. L. Sun, C. Zhang, L. Chen, J. Liu, H. Jin, H. Xu, L. Ding, Anal. Chim. Acta 638, 162 (2009)

    Article  CAS  Google Scholar 

  35. J. Li, X. Zhao, Y. Shi, Y. Cai, S. Mou, G. Jiang, J. Chromatogr. A 1180, 24 (2008)

    Article  CAS  Google Scholar 

  36. X. Yang, K. Qiao, F. Liu, X. Wu, M. Yang, J. Li, H. Gao, S. Zhang, W. Zhou, R. Lu, Talanta 166, 93 (2017)

    Article  CAS  Google Scholar 

  37. P. Tartaj, Chem. Commun. 47, 256 (2011)

    Article  CAS  Google Scholar 

  38. L. Adlnasab, H. Ebrahimzadeh, A.A. Asgharinezhad, M. Nasiri Aghdam, A. Dehghani, S. Esmaeilpour, Anal. Methods 3, 616 (2013)

    Google Scholar 

  39. J. Li, Q. Fan, Y. Wu, X. Wang, C. Chen, Z. Tang, X. Wang, J. Mater. Chem. A 4, 1737 (2016)

    Article  CAS  Google Scholar 

  40. M. Ghaedi, D. Daneshfar, A. Ahmadi, M.S. Momeni, J. Ind. Eng. Chem. 21, 587 (2015)

    Article  CAS  Google Scholar 

  41. V. Belessi, G. Romanos, N. Boukos, D. Lambropoulou, C. Trapalis, J. Hazard. Mater. 170, 836 (2009)

    Article  CAS  Google Scholar 

  42. J. Zolgharnein, N. Asanjrani, M. Bagtash, G. Azimi, Spectrochim. Acta. A Mol. Biomol. Spectrosc. 126, 291 (2014)

    Article  CAS  Google Scholar 

  43. S. Hashemian, M. Rahimi, A.A. Kerdegari, Desalin. Water Treat. 57, 14696 (2015)

    Article  Google Scholar 

  44. M. Salman, M. Athar, U. Shafique, M.I. Din, R. Rehman, A. Akram, S.Z. Ali, Turk. J. Eng. Environ. Sci. 35, 209 (2011)

    CAS  Google Scholar 

Download references

Acknowledgements

Support of this investigation by the research council of Payame Noor University is gratefully acknowledged.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Maryam Ezoddin.

Ethics declarations

Conflict of interest

The authors declare that there are no conflicts of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Adlnasab, L., Ezoddin, M., Karimi, M.A. et al. MCM-41@Cu–Fe–LDH magnetic nanoparticles modified with cationic surfactant for removal of Alizarin Yellow from water samples and its determination with HPLC. Res Chem Intermed 44, 3249–3265 (2018). https://doi.org/10.1007/s11164-018-3304-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11164-018-3304-5

Keywords

Navigation