Research on Chemical Intermediates

, Volume 44, Issue 5, pp 3081–3095 | Cite as

Enhanced photocatalytic degradation of methyl orange using ZnO/graphene oxide nanocomposites

  • Van Noi Nguyen
  • Dinh Trinh Tran
  • Manh Tuong Nguyen
  • Thi Thanh Thuy Le
  • Minh Ngoc Ha
  • Minh Viet Nguyen
  • Thanh Dong Pham
Article
  • 59 Downloads

Abstract

ZnO/graphene oxide (ZnO/GO) nanocomposites were synthesized by hydrothermal method using zinc acetate and graphite as precursors. Properties of synthesized materials were investigated by different physico-chemical techniques and their photocatalytic performance was evaluated with the aid of the photodegradation of methyl orange under UV irradiation. Impacts of reaction conditions such as pH of solutions, catalyst loading and initial concentration on photodegradation rate of synthesized photocatalysts were also investigated. TEM images showed that the average size of the synthesized ZnO was approximately 35 nm, being in good agreement with the obtained XRD results which revealed good dispersion of ZnO particles over the wrinkled GO layers. UV–Vis absorption spectra of these synthesized materials revealed that 5% ZnO/GO exhibited the highest visible light absorption. Photocatalytic experimental results showed that the highest photodegradation rates occurred in a neutral solution with an initial methyl orange (MO) concentration of 10 mg/L. After 2 h of reaction under UV irradiation, more than 95% of MO was degraded at optimal conditions. The photodegradation of MO followed the pseudo-first-order kinetics with apparent reaction rate constants in the range of 0.009–0.030 (min−1). ZnO/GO photocatalyst was relatively stable in neutral aqueous solutions during the photodegradation of MO, with a decrease of 6% in photocatalytic performance observed after four cycles compared with the first cycle.

Keywords

ZnO/GO nanocomposites Enhanced photocatalytic performance Methyl orange First-order kinetics 

Notes

Acknowledgements

This research was funded by the Vietnam National University, Hanoi (VNU), under project number QG.16.21.

Supplementary material

11164_2018_3294_MOESM1_ESM.docx (393 kb)
Supplementary material 1 (DOCX 393 kb)

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Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2018

Authors and Affiliations

  • Van Noi Nguyen
    • 1
  • Dinh Trinh Tran
    • 1
  • Manh Tuong Nguyen
    • 2
  • Thi Thanh Thuy Le
    • 3
  • Minh Ngoc Ha
    • 1
  • Minh Viet Nguyen
    • 1
  • Thanh Dong Pham
    • 1
  1. 1.VNU Key Laboratory of Advanced Materials for Green Growth, Faculty of ChemistryVietnam National UniversityHanoiVietnam
  2. 2.Institute of Chemistry - MaterialVietnam Academy of Military Science and TechnologyHanoiVietnam
  3. 3.Department of ChemistryQuy Nhon UniversityQui Nhon CityVietnam

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