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One-step synthesis of a β-cyclodextrin derivative and its performance for the removal of Pb(II) from aqueous solutions

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Abstract

A new multifunctional β-cyclodextrin-sodium xanthogenate (β-CDX) was successfully synthesized by a one-step process and applied to remove Pb(II) from aqueous solutions. The characteristics and chelation mechanisms of β-CDX were investigated by Fourier-transform infrared spectroscopy and X-ray photoelectron spectroscopy, and the influences of various operating parameters such as pH (lime dosage), the order of the additions, β-CDX dosage, and the initial concentration of Pb(II) on the removal capacity of β-CDX and the characteristics of the products were systematically evaluated. The results demonstrated that the optimal removal effect for Pb(II) was achieved when β-CDX was used rather than using lime alone. In addition, it was more effective to add β-CDX to the working solutions prior to adding the lime than adding β-CDX after the lime. The use of 0.05 g/L of β-CDX was effective for the removal of Pb(II) according to the residual concentration when the initial concentration was 100 mg/L at different pH values. The maximum removal rate of the Pb(II) ions was 98% for all initial concentrations and the products were larger (size = 137.9 μm) and looser (Df = 1.73) at an optimum pH range from 9 to 12. The characterization results confirmed that the RC(S)SNa in the β-CDX was the main contributor to the chelation of the Pb(II). These properties of β-CDX make it a promising compound for the treatment of wastewater contaminated by hazardous metal ions.

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References

  1. A.Z.M. Badruddoza, Z.B.Z. Shawon, W.J.D. Tay, K. Hidajat, M.S. Uddin, Carbohyd. Polym. 91, 322 (2013)

    Article  CAS  Google Scholar 

  2. O. Ozay, S. Ekici, Y. Baran, N. Aktas, N. Sahiner, Water Res. 43, 4403 (2009)

    Article  CAS  Google Scholar 

  3. R. Hua, Z. Li, Chem. Eng. J. 249, 189 (2014)

    Article  CAS  Google Scholar 

  4. M.R. Foroughi, M. Zarei, Res. Chem. Intermed. 41, 4009 (2015)

    Article  CAS  Google Scholar 

  5. J.-X. Yu, L.-Y. Wang, R.-A. Chi, Y.-F. Zhang, Z.-G. Xu, J. Guo, Res. Chem. Intermed. 41, 1525 (2015)

    Article  CAS  Google Scholar 

  6. F. Fu, Q. Wang, J. Environ. Manag. 92, 407 (2011)

    Article  CAS  Google Scholar 

  7. W. Wang, Y. Hua, S. Li, W. Yan, W.-X. Zhang, Chem. Eng. J. 304, 79 (2016)

    Article  CAS  Google Scholar 

  8. S. Pandey, J. Mol. Liq. 241, 1091 (2017)

    Article  CAS  Google Scholar 

  9. S. Pandey, J. Sci. Adv. Mater. Dev. 1, 431 (2016)

    Google Scholar 

  10. S. Pandey, J. Ramontja, Int. J. Biol. Macromol. 93, 712 (2016)

    Article  CAS  Google Scholar 

  11. S. Pandey, J. Ramontja, J. Anal. Sci. Technol. 93, 712 (2016)

    CAS  Google Scholar 

  12. V. Singh, S. Tiwari, S. Pandey, P. Singh, R. Sanghi, AML 6, 19 (2015)

    Article  CAS  Google Scholar 

  13. H. Qian, Z. Ai, Res. Chem. Intermed. 42, 4387 (2016)

    Article  CAS  Google Scholar 

  14. Á. Martínez, C. Ortiz Mellet, J.M. García Fernández, Chem. Soc. Rev. 42, 4746 (2013)

    Article  Google Scholar 

  15. F. Bellia, D. La Mendola, C. Pedone, E. Rizzarelli, M. Saviano, G. Vecchio, Chem. Soc. Rev. 38, 2756 (2009)

    Article  CAS  Google Scholar 

  16. E. Engeldinger, D. Armspach, D. Matt, Chem. Rev. 103, 4147 (2003)

    Article  CAS  Google Scholar 

  17. J. Wang, C. Chen, Biotechnol. Adv. 27, 195 (2009)

    Article  Google Scholar 

  18. S. Liang, X. Guo, N. Feng, Q. Tian, J. Hazard. Mater. 170, 425 (2009)

    Article  CAS  Google Scholar 

  19. Q. Chang, X. Hao, L. Duan, J. Hazard. Mater. 159, 548 (2008)

    Article  CAS  Google Scholar 

  20. Y. Sun, H.W. Liu, J. Funct. Polym. 22, 282 (2009)

    CAS  Google Scholar 

  21. D. Palomino, D. Hunkeler, S. Stoll, Polymer 52, 1019 (2011)

    Article  CAS  Google Scholar 

  22. S. Mohamad, H. Surikumaran, M. Raoov, T. Marimuthu, K. Chandrasekaram, P. Subramaniam, Int. J. Mol. Sci. 12, 6329 (2011)

    Article  CAS  Google Scholar 

  23. Y.P. Chin, S.F. Abdul Raof, S. Sinniah, V.S. Lee, S. Mohamad, N.S. Abdul Manan, J. Mol. Struct. 1083, 236 (2015)

    Article  CAS  Google Scholar 

  24. X. Hao, Q. Chang, L. Duan, Y. Zhang, Starch – Stärke 59, 251 (2007)

    Article  CAS  Google Scholar 

  25. R. Fan, Q. Yi, Y. Xie, F. Xie, Q. Zhang, Z. Luo, J. Appl. Polym. Sci. 133, 28 (2016)

    Google Scholar 

  26. Y. Chen, J. Wang, Nucl. Eng. Des. 242, 452 (2012)

    Article  CAS  Google Scholar 

  27. B. Kannamba, K.L. Reddy, B.V. AppaRao, J. Hazard. Mater. 175, 939 (2010)

    Article  CAS  Google Scholar 

  28. N. Wang, X. Xu, H. Li, L. Yuan, H. Yu, Ind. Eng. Chem. Res. 55, 12222 (2016)

    Article  CAS  Google Scholar 

  29. A.Z.M. Badruddoza, Z.B.Z. Shawon, W.J.D. Tay, K. Hidajat, M.S. Uddin, Carbohydr. Polym. 91, 322 (2013)

    Article  CAS  Google Scholar 

  30. D.H.K. Reddy, S.-M. Lee, Ind. Eng. Chem. Res. 52, 15789 (2013)

    Article  CAS  Google Scholar 

  31. C. Gao, X.-Y. Yu, T. Luo, Y. Jia, B. Sun, J.-H. Liu, X.-J. Huang, J. Mater. Chem. A 2, 2119 (2014)

    Article  CAS  Google Scholar 

  32. F. Zhao, E. Repo, D. Yin, Y. Meng, S. Jafari, M. Sillanpää, Environ. Sci. Technol. 49, 10570 (2015)

    Article  CAS  Google Scholar 

  33. R.G. Kumar, K.B. Strom, A. Keyvani, Cont. Shelf Res. 30, 2067 (2010)

    Article  Google Scholar 

  34. Y. Qi, K.B. Thapa, A.F.A. Hoadley, Chem. Eng. J. 171, 373 (2011)

    Article  CAS  Google Scholar 

  35. Y. Wang, W. Zhang, J. Zhang, W. Sun, R. Zhang, H. Gu, ACS Appl. Mater. Interfaces. 5, 10337 (2013)

    Article  CAS  Google Scholar 

  36. S. Tunali, A. Çabuk, T. Akar, Chem. Eng. J. 115, 203 (2006)

    Article  CAS  Google Scholar 

  37. V.J. Inglezakis, M.A. Stylianou, D. Gkantzou, M.D. Loizidou, Desalination 210, 248 (2007)

    Article  CAS  Google Scholar 

  38. M.T. Alvarez, C. Crespo, B. Mattiasson, Chemosphere 66, 1677 (2007)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was financially supported by Chongqing education committee science and technology research project (Grant Nos. KJ1601901; KJ1719373).

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Authors and Affiliations

  1. Rongzhi College of Chongqing Technology and Business University, Chongqing, 401320, China

    Changhua He, Qigang Zhou, Fuhai Wang & Hui Li

  2. Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming, 650500, Yunnan, China

    Changhua He, Zhengyang Duan & Xiaojun Xu

Authors
  1. Changhua He
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  2. Qigang Zhou
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  3. Zhengyang Duan
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  4. Xiaojun Xu
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Correspondence to Qigang Zhou.

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He, C., Zhou, Q., Duan, Z. et al. One-step synthesis of a β-cyclodextrin derivative and its performance for the removal of Pb(II) from aqueous solutions. Res Chem Intermed 44, 2983–2998 (2018). https://doi.org/10.1007/s11164-018-3289-0

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  • DOI: https://doi.org/10.1007/s11164-018-3289-0

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