Skip to main content
Log in

Novel silica-supported molybdic acid (SSMA): an efficient catalyst for the synthesis of new azo dyes

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

Silica-supported molybdic acid (SSMA) as a novel and highly efficient catalyst was prepared and characterized by X-ray fluorescence, X-ray diffraction, and Fourier transform infrared spectroscopy. Catalytic activity of as-prepared SSMA was then investigated for synthesis of novel azo coumarin dyes. This convenient and efficient protocol provides better alternatives to existing methods because the reactions proceeded quickly under clean conditions with high yields.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Scheme 1
Fig. 1
Fig. 2
Scheme 2
Fig. 3

Similar content being viewed by others

References

  1. A. Corma, H. Garcia, Adv. Synth. Catal. 348, 1391–1412 (2006)

    Article  CAS  Google Scholar 

  2. M.A. Satam, R.K. Raut, N. Sekar, Dyes Pigm. 96, 92–103 (2013)

    Article  CAS  Google Scholar 

  3. A.D. Towns, Dyes Pigm. 42, 3–28 (1999)

    Article  CAS  Google Scholar 

  4. K.L. Georgiadou, E.G. Tsatsaroni, Dyes Pigm. 50, 93–97 (2001)

    Article  CAS  Google Scholar 

  5. A.S. Abd-El-Aziz, T.H. Afifi, Dyes Pigm. 70, 8–17 (2006)

    Article  CAS  Google Scholar 

  6. R. Cristiana, A.M. Hossu, I. Ionita, Dyes Pigm. 71, 123–129 (2006)

    Article  Google Scholar 

  7. H. Valizadeh, A. Shomali, S. Nourshargh, Dyes Pigm. 113, 522–528 (2015)

    Article  CAS  Google Scholar 

  8. H. Khanmohammadi, K. Rezaeian, M.M. Amini, N.S. Weng, Dyes Pigm. 98, 557–564 (2013)

    Article  CAS  Google Scholar 

  9. J. Koh, A.J. Greaves, Dyes Pigm. 50, 117–126 (2001)

    Article  CAS  Google Scholar 

  10. H.S. Bhatti, S. Seshadri, Color. Technol. 120, 151–155 (2004)

    Article  CAS  Google Scholar 

  11. E. Abdel-latif, M.A. Metwally, Mon. Chem. 138, 771–776 (2007)

    Article  CAS  Google Scholar 

  12. J. Merrington, M. James, M. Bradley, Chem. Commun. 2, 140–141 (2002)

    Article  Google Scholar 

  13. A.R. Hajipour, A. Zarei, A.E. Ruoho, Synth. Commun. 36, 1039–1050 (2006)

    Article  CAS  Google Scholar 

  14. S.A. Hameed, Jord. J. Chem. 2, 133–144 (2007)

    CAS  Google Scholar 

  15. H. Valizadeh, M. Amiri, A. Shomali, F. Hosseinzadeh, J. Iran. Chem. Soc. 8, 495–501 (2011)

    Article  CAS  Google Scholar 

  16. H. Valizadeh, M. Amiri, F. Hosseinzadeh, Dyes Pigm. 92, 1308–1313 (2012)

    Article  CAS  Google Scholar 

  17. S. Khodabakhshi, B. Karami, Catal. Sci. Technol. 2, 1940–1944 (2012)

    Article  CAS  Google Scholar 

  18. M.L. Kantam, M. Roy, S. Roya, B. Sreedhara, R.L. De, Catal. Commun. 9, 2226–2230 (2008)

    Article  CAS  Google Scholar 

  19. A.D. Murkute, J.E. Jackson, D.J. Miller, J. Catal. 278, 189–199 (2011)

    Article  CAS  Google Scholar 

  20. A. Cornelis, P. Laszlo, Synthesis 909–918 (1985)

  21. B. Karami, M. Kiani, Catal. Commun. 14, 62–67 (2011)

    Article  CAS  Google Scholar 

  22. B. Karami, Z. Haghighijou, M. Farahi, S. Khodabakhshi, Phosphorus Sulfur Silicon Relat. Elem. 187, 754–761 (2012)

    Article  CAS  Google Scholar 

  23. B. Karami, S. Khodabakhshi, M. Jamshidi, J. Chin. Chem. Soc. 60, 1103–1106 (2013)

    Article  CAS  Google Scholar 

  24. S. Khodabakhshi, B. Karami, K. Eskandari, S.J. Hoseini, A. Rashidi, RSC Adv. 4, 17891–17895 (2014)

    Article  CAS  Google Scholar 

  25. H. Karade, M. Sathe, M.P. Kaushik, Catal. Commun. 8, 741–746 (2007)

    Article  CAS  Google Scholar 

  26. T. Brezesinski, J. Wang, S.H. Tolbert, B. Dunn, Nat. Mater. 9, 146–151 (2010)

    Article  CAS  Google Scholar 

  27. S. Khodabakhshi, B. Karami, K. Eskandari, C. R. Chim. 17, 35–40 (2014)

    Article  CAS  Google Scholar 

  28. B. Karami, K. Eskandari, S. Khodabakhshi, J. Iran. Chem. Soc. 11, 631–637 (2014)

    Article  CAS  Google Scholar 

  29. B. Karami, S. Khodabakhshi, Z. Haghighijou, Chem. Pap. 66, 684–690 (2012)

    Article  CAS  Google Scholar 

  30. K. Eskandari, B. Karami, S. Khodabakhshi, Catal. Commun. 54, 124–130 (2014)

    Article  CAS  Google Scholar 

  31. B. Karami, S. Khodabakhshi, F. Hashemi, Tetrahedron Lett. 54, 3583–3585 (2013)

    Article  CAS  Google Scholar 

  32. B.B.F. Mirjalili, A. Bamoniri, A. Akbari, Curr. Chem. Lett. 1, 109–114 (2012)

    Article  CAS  Google Scholar 

  33. A. Zarei, A.R. Hajipour, L. Khazdooz, B.B.F. Mirjalili, A.N. Chermahini, Dyes Pigm. 81, 240–244 (2009)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors are grateful for the support from the Yasouj University (Iran).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Bahador Karami.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOC 4596 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Karami, B., Kiani, M. Novel silica-supported molybdic acid (SSMA): an efficient catalyst for the synthesis of new azo dyes. Res Chem Intermed 42, 3373–3383 (2016). https://doi.org/10.1007/s11164-015-2218-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11164-015-2218-8

Keywords

Navigation