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Facile preparation and application of magnesium hydroxide assembly spheres

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Abstract

Magnesium hydroxide (Mg(OH)2) assembly spheres were successfully synthesized by use of a facile bio-template method, with Mg(NO3)2 and NaOH solution as reactants. The products were characterized by X-ray diffraction and transmission electron microscopy. The Mg(OH)2 nanomaterial obtained was assembled from nanoflakes and was approximately 2 μm in total size. Eggshell membrane was crucially important in the process of formation of the assembly spheres. The process and mechanism of assembly of the spheres are discussed. When the Mg(OH)2 assembly spheres were used to treat waste water containing heavy metals approximately 100 % of copper ions were removed.

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References

  1. Z. Zhou, Q. Sun, Z. Hu, Y. Deng, Nanobelt formation of magnesium hydroxide sulfate hydrate via a soft chemistry process. J. Phys. Chem. B 110, 13387–13392 (2006)

    Article  CAS  Google Scholar 

  2. Y.J. Zhao, Y. Tan, F.S. Wong, A.G. Fane, N.P. Xu, Formation of Mg(OH)2 dynamic membranes for oily water separation: effects of operating conditions. Desalination 191, 344–350 (2006)

    Article  CAS  Google Scholar 

  3. H. Cao, H. Zheng, J.F. Yin, Y.X. Lu, S.S. Wu, X.M. Wu, B.J. Li, Mg(OH)2 complex nanostructures with superhydrophobicity and flame retardant effects. J. Phys. Chem. C 114, 17362–17368 (2010)

    Article  CAS  Google Scholar 

  4. G.W. Beall, E.S.M. Duraia, F.E. Tantawy, F. Al-Hazmi, A.A. Al-Ghamdi, Rapid fabrication of nanostructured magnesium hydroxide and hydromagnesite via microwave-assisted technique. Powder Technol. 234, 26–31 (2013)

    Article  Google Scholar 

  5. J.C. Yu, A. Xu, L. Zhang, R. Song, L. Wu, Synthesis and characterization of porous magnesium hydroxide and oxide nanoplates. J. Phys. Chem. B 108, 64–70 (2004)

    Article  CAS  Google Scholar 

  6. J. Kang, P. Schwendeman, Comparison of the effects of Mg(OH)2 and sucrose on the stability of bovine serum albumin encapsulated in injectable poly(d, l-lactide-co-glycolide) implants. Biomater 23, 239–245 (2002)

    Article  CAS  Google Scholar 

  7. R.V. Siriwardane, R.W. Stevens, Novel regenerable magnesium hydroxide sorbents for CO2 capture at warm gas temperatures. Ind. Eng. Chem. Res. 48, 2135–2141 (2009)

    Article  CAS  Google Scholar 

  8. H. Minami, K. Kinoshita, T. Tsuji, H. Yanagimoto, Preparation of highly crystalline magnesium oxide and polystyrene/magnesium hydroxide composite particles by sol–gel processes in an ionic liquid. J. Phys. Chem. C 116, 14568–14574 (2012)

    Article  CAS  Google Scholar 

  9. H. Qian, M. Denga, S. Zhanga, L. Xua, Synthesis of superfine Mg(OH)2 particles by magnesite. Mater. Sci. Eng. A 445(446), 600–603 (2007)

    Article  Google Scholar 

  10. G. Song, S. Ma, G. Tang, X. Wang, Ultrasonic-assisted synthesis of hydrophobic magnesium hydroxide nanoparticles. Colloids Surf. A Physicochem. Eng. Aspects 364, 99–104 (2010)

    Article  CAS  Google Scholar 

  11. H. Pang, G. Ning, W. Gong, J. Ye, Y. Lin, Direct synthesis of hexagonal Mg(OH)2 nanoplates from natural brucite without dissolution procedure. Chem. Commun. 47, 6317–6319 (2011)

    Article  CAS  Google Scholar 

  12. W. Gong, D. Wu, Z. Cheng, H. Pang, Y. Lin, G. Ning, Direct synthesis of porous Mg(OH)2 nanoplates from natural brucite. Mater. Res. Bull. 48, 1333–1337 (2013)

    Article  CAS  Google Scholar 

  13. D. An, L. Wang, Y. Zheng, S. Guan, X. Gao, Y. Tian, In situ preparation and surface modification of magnesium hydroxide nanoparticles. Colloids Surf. A: Physicochem. Eng. Aspects 348, 9–13 (2009)

    Article  CAS  Google Scholar 

  14. J. Wu, H. Yana, X. Zhang, L. Wei, Xu Liu, B. Xu, Magnesium hydroxide nanoparticles synthesized in water-in-oil microemulsions. J. Colloid Interface Sci. 324, 167–171 (2008)

    Article  CAS  Google Scholar 

  15. C.Y. Tai, C.T. Tai, M.H. Chang, H.S. Liu, Synthesis of magnesium hydroxide and oxide nanoparticles using a spinning disk reactor. Ind. Eng. Chem. Res. 46, 5536–5541 (2007)

    Article  CAS  Google Scholar 

  16. G. Zou, R. Liu, W. Chen, Z. Xu, Preparation and characterization of lamellar-like Mg(OH)2 nanostructures via natural oxidation of Mg metal in formamide/water mixture. Mater. Res. Bull. 42, 1153–1158 (2007)

    Article  CAS  Google Scholar 

  17. H. Wu, M. Shao, J. Gu, X. Wei, Microwave-assisted synthesis of fibre-like Mg(OH)2 nanoparticles in aqueous solution at room temperature. Mater. Lett. 58, 2166–2169 (2004)

    Article  CAS  Google Scholar 

  18. P. Jeevanandam, R.S. Mulukutla, Z. Yang, H. Kwen, K.J. Klabunde, Nanocrystals to nanorods: a precursor approach for the synthesis of magnesium hydroxide nanorods from magnesium oxychloride nanorods starting from nanocrystalline magnesium oxide. Chem. Mater. 19, 5395–5403 (2007)

    Article  CAS  Google Scholar 

  19. J.L. He, C. Liu, J.K. Liu, X.H. Yang, Facile preparation and characterization of magnesium hydroxide assembly spheres. Mater. Technol. 27, 375–379 (2012)

    Article  CAS  Google Scholar 

  20. C. Yan, D. Xue, L. Zou, X. Yan, W. Wang, Preparation of magnesium hydroxide nanoflowers. J. Cryst. Growth 282, 448–454 (2005)

    Article  CAS  Google Scholar 

  21. M. Zhang, R. Miao, G.M. Li, Y.J. Du, Preparation and characterization of fluorescence probe from assembly hydroxyapatite nanocomposite. Nanoscale Res. Lett. 5, 675–679 (2010)

    Article  CAS  Google Scholar 

  22. J.K. Liu, C.X. Luo, N.J. Quan, Preparation and optical properties of silver chromate self-assembly necklace structures. J. Nanopart. Res. 10, 531–535 (2008)

    Article  CAS  Google Scholar 

  23. J.K. Liu, X.H. Yang, X.G. Tian, Preparation of silver/hydroxyapatite nanocomposite spheres. Powder Technol. 184, 21–24 (2008)

    Article  CAS  Google Scholar 

  24. J.K. Liu, C.X. Luo, J.D. Wang, X.H. Yang, X.H. Zhong, Controlled synthesis of silver phosphate crystals with high photocatalytic activity and bacteriostatic activity. CrystEngComm 14, 8714–8721 (2012)

    Article  CAS  Google Scholar 

  25. Z. Yang, C. Zhou, H. Yang, T. Cai, J. Cai, H. Li, D. Zhou, B. Chen, A. Li, R. Cheng, Improvement of the compatibilization of high-impact polystyrene/magnesium hydroxide composites with partia sulfonated polystyrene as macromolecular compatibilizers. Ind. Eng. Chem. Res. 51, 9204–9212 (2012)

    Article  CAS  Google Scholar 

  26. H.Z. Xie, J.D. Wang, C.X. Luo, J.K. Liu, Situ-preparation and sterilization activity of hydroxyapatite/silver nanocomposite. NANO 7, 1250050 (2012)

    Article  Google Scholar 

  27. X. Li, G.B. Ma, Y.Y. Liu, Synthesis and characterization of magnesium hydroxide using a bubbling setup. Ind. Eng. Chem. Res. 48, 763–768 (2009)

    Article  CAS  Google Scholar 

  28. X.S. Tai, W.H. Zhao, Synthesis, spectral characterization, and luminescence properties of a cup-like ligand and its magnesium(II) complex. Res. Chem. Intermed. 40, 2075–2082 (2014)

    Article  CAS  Google Scholar 

  29. S. Yuan, Y. Li, Q. Zhang, H. Wang, ZnO/Mg–Al layered double hydroxides as strongly adsorptive photocatalysts. Res. Chem. Intermed. 35, 685–692 (2009)

    Article  CAS  Google Scholar 

  30. X. Ma, J. Zheng, H. Pang, Intercalation of Mg–Al layered double hydroxides by l-proline: synthesis and characterization. Res. Chem. Intermed. 38, 629–638 (2012)

    Article  Google Scholar 

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Correspondence to Guang-Ming Li.

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Wang, SY., Li, GM., Xu, W. et al. Facile preparation and application of magnesium hydroxide assembly spheres. Res Chem Intermed 42, 2661–2668 (2016). https://doi.org/10.1007/s11164-015-2173-4

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