Abstract
Magnesium hydroxide (Mg(OH)2) assembly spheres were successfully synthesized by use of a facile bio-template method, with Mg(NO3)2 and NaOH solution as reactants. The products were characterized by X-ray diffraction and transmission electron microscopy. The Mg(OH)2 nanomaterial obtained was assembled from nanoflakes and was approximately 2 μm in total size. Eggshell membrane was crucially important in the process of formation of the assembly spheres. The process and mechanism of assembly of the spheres are discussed. When the Mg(OH)2 assembly spheres were used to treat waste water containing heavy metals approximately 100 % of copper ions were removed.
Similar content being viewed by others
References
Z. Zhou, Q. Sun, Z. Hu, Y. Deng, Nanobelt formation of magnesium hydroxide sulfate hydrate via a soft chemistry process. J. Phys. Chem. B 110, 13387–13392 (2006)
Y.J. Zhao, Y. Tan, F.S. Wong, A.G. Fane, N.P. Xu, Formation of Mg(OH)2 dynamic membranes for oily water separation: effects of operating conditions. Desalination 191, 344–350 (2006)
H. Cao, H. Zheng, J.F. Yin, Y.X. Lu, S.S. Wu, X.M. Wu, B.J. Li, Mg(OH)2 complex nanostructures with superhydrophobicity and flame retardant effects. J. Phys. Chem. C 114, 17362–17368 (2010)
G.W. Beall, E.S.M. Duraia, F.E. Tantawy, F. Al-Hazmi, A.A. Al-Ghamdi, Rapid fabrication of nanostructured magnesium hydroxide and hydromagnesite via microwave-assisted technique. Powder Technol. 234, 26–31 (2013)
J.C. Yu, A. Xu, L. Zhang, R. Song, L. Wu, Synthesis and characterization of porous magnesium hydroxide and oxide nanoplates. J. Phys. Chem. B 108, 64–70 (2004)
J. Kang, P. Schwendeman, Comparison of the effects of Mg(OH)2 and sucrose on the stability of bovine serum albumin encapsulated in injectable poly(d, l-lactide-co-glycolide) implants. Biomater 23, 239–245 (2002)
R.V. Siriwardane, R.W. Stevens, Novel regenerable magnesium hydroxide sorbents for CO2 capture at warm gas temperatures. Ind. Eng. Chem. Res. 48, 2135–2141 (2009)
H. Minami, K. Kinoshita, T. Tsuji, H. Yanagimoto, Preparation of highly crystalline magnesium oxide and polystyrene/magnesium hydroxide composite particles by sol–gel processes in an ionic liquid. J. Phys. Chem. C 116, 14568–14574 (2012)
H. Qian, M. Denga, S. Zhanga, L. Xua, Synthesis of superfine Mg(OH)2 particles by magnesite. Mater. Sci. Eng. A 445(446), 600–603 (2007)
G. Song, S. Ma, G. Tang, X. Wang, Ultrasonic-assisted synthesis of hydrophobic magnesium hydroxide nanoparticles. Colloids Surf. A Physicochem. Eng. Aspects 364, 99–104 (2010)
H. Pang, G. Ning, W. Gong, J. Ye, Y. Lin, Direct synthesis of hexagonal Mg(OH)2 nanoplates from natural brucite without dissolution procedure. Chem. Commun. 47, 6317–6319 (2011)
W. Gong, D. Wu, Z. Cheng, H. Pang, Y. Lin, G. Ning, Direct synthesis of porous Mg(OH)2 nanoplates from natural brucite. Mater. Res. Bull. 48, 1333–1337 (2013)
D. An, L. Wang, Y. Zheng, S. Guan, X. Gao, Y. Tian, In situ preparation and surface modification of magnesium hydroxide nanoparticles. Colloids Surf. A: Physicochem. Eng. Aspects 348, 9–13 (2009)
J. Wu, H. Yana, X. Zhang, L. Wei, Xu Liu, B. Xu, Magnesium hydroxide nanoparticles synthesized in water-in-oil microemulsions. J. Colloid Interface Sci. 324, 167–171 (2008)
C.Y. Tai, C.T. Tai, M.H. Chang, H.S. Liu, Synthesis of magnesium hydroxide and oxide nanoparticles using a spinning disk reactor. Ind. Eng. Chem. Res. 46, 5536–5541 (2007)
G. Zou, R. Liu, W. Chen, Z. Xu, Preparation and characterization of lamellar-like Mg(OH)2 nanostructures via natural oxidation of Mg metal in formamide/water mixture. Mater. Res. Bull. 42, 1153–1158 (2007)
H. Wu, M. Shao, J. Gu, X. Wei, Microwave-assisted synthesis of fibre-like Mg(OH)2 nanoparticles in aqueous solution at room temperature. Mater. Lett. 58, 2166–2169 (2004)
P. Jeevanandam, R.S. Mulukutla, Z. Yang, H. Kwen, K.J. Klabunde, Nanocrystals to nanorods: a precursor approach for the synthesis of magnesium hydroxide nanorods from magnesium oxychloride nanorods starting from nanocrystalline magnesium oxide. Chem. Mater. 19, 5395–5403 (2007)
J.L. He, C. Liu, J.K. Liu, X.H. Yang, Facile preparation and characterization of magnesium hydroxide assembly spheres. Mater. Technol. 27, 375–379 (2012)
C. Yan, D. Xue, L. Zou, X. Yan, W. Wang, Preparation of magnesium hydroxide nanoflowers. J. Cryst. Growth 282, 448–454 (2005)
M. Zhang, R. Miao, G.M. Li, Y.J. Du, Preparation and characterization of fluorescence probe from assembly hydroxyapatite nanocomposite. Nanoscale Res. Lett. 5, 675–679 (2010)
J.K. Liu, C.X. Luo, N.J. Quan, Preparation and optical properties of silver chromate self-assembly necklace structures. J. Nanopart. Res. 10, 531–535 (2008)
J.K. Liu, X.H. Yang, X.G. Tian, Preparation of silver/hydroxyapatite nanocomposite spheres. Powder Technol. 184, 21–24 (2008)
J.K. Liu, C.X. Luo, J.D. Wang, X.H. Yang, X.H. Zhong, Controlled synthesis of silver phosphate crystals with high photocatalytic activity and bacteriostatic activity. CrystEngComm 14, 8714–8721 (2012)
Z. Yang, C. Zhou, H. Yang, T. Cai, J. Cai, H. Li, D. Zhou, B. Chen, A. Li, R. Cheng, Improvement of the compatibilization of high-impact polystyrene/magnesium hydroxide composites with partia sulfonated polystyrene as macromolecular compatibilizers. Ind. Eng. Chem. Res. 51, 9204–9212 (2012)
H.Z. Xie, J.D. Wang, C.X. Luo, J.K. Liu, Situ-preparation and sterilization activity of hydroxyapatite/silver nanocomposite. NANO 7, 1250050 (2012)
X. Li, G.B. Ma, Y.Y. Liu, Synthesis and characterization of magnesium hydroxide using a bubbling setup. Ind. Eng. Chem. Res. 48, 763–768 (2009)
X.S. Tai, W.H. Zhao, Synthesis, spectral characterization, and luminescence properties of a cup-like ligand and its magnesium(II) complex. Res. Chem. Intermed. 40, 2075–2082 (2014)
S. Yuan, Y. Li, Q. Zhang, H. Wang, ZnO/Mg–Al layered double hydroxides as strongly adsorptive photocatalysts. Res. Chem. Intermed. 35, 685–692 (2009)
X. Ma, J. Zheng, H. Pang, Intercalation of Mg–Al layered double hydroxides by l-proline: synthesis and characterization. Res. Chem. Intermed. 38, 629–638 (2012)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Wang, SY., Li, GM., Xu, W. et al. Facile preparation and application of magnesium hydroxide assembly spheres. Res Chem Intermed 42, 2661–2668 (2016). https://doi.org/10.1007/s11164-015-2173-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11164-015-2173-4