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Synthesis and characterization of pyridine-4-carboxylic acid functionalized Fe3O4 nanoparticles as a magnetic catalyst for synthesis of pyrano[3,2-b]pyranone derivatives under solvent-free conditions

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Abstract

Pyridine-4-carboxylic acid (PYCA) functionalized Fe3O4 nanoparticles as an organic–inorganic hybrid heterogeneous catalyst was fabricated and characterized by FT-IR, XRD, TGA, TEM, SEM, and VSM techniques. The catalytic activity of the magnetic catalyst was probed through one-pot synthesis of pyrano[3,2-b]pyranone derivatives from three component reactions of aromatic aldehydes, kojic acid, and ethyl cyanoacetate under solvent-free conditions. Some advantages of this protocol are its environmentally benign method, simple procedure, high yields, and short reaction time. The catalyst was readily separated using an external magnet and reusable without significant loss of its catalytic efficiency.

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Acknowledgments

This research was supported by the Research Council of the University of Mazandaran in Iran.

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Authors and Affiliations

  1. Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, 47416-95447, Babolsar, Iran

    Sakineh Asghari & Majid Mohammadnia

  2. Nano and Biotechnology Research Group, University of Mazandaran, Babolsar, Iran

    Sakineh Asghari

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  1. Sakineh Asghari
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  2. Majid Mohammadnia
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Correspondence to Sakineh Asghari.

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Asghari, S., Mohammadnia, M. Synthesis and characterization of pyridine-4-carboxylic acid functionalized Fe3O4 nanoparticles as a magnetic catalyst for synthesis of pyrano[3,2-b]pyranone derivatives under solvent-free conditions. Res Chem Intermed 42, 1899–1911 (2016). https://doi.org/10.1007/s11164-015-2124-0

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