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A novel oxido-vanadium(V) Schiff base complex: synthesis, spectral characterization, crystal structure, electrochemical evaluation, and biological activity

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Abstract

A new oxido-vanadium(V) complex, [VO(L)(PrOH)(OPr)] (L = [(3-methoxy-2oxidobenzylidene)benzohydrazidato], PrOH = propanol, OPr = propanolato) has been synthesized and characterized by means of elemental analysis, Fourier transform infrared (FTIR), proton nuclear magnetic resonance (1HNMR), ultaviolet-visible (UV–Vis) spectroscopy, voltammetry and molar conductivity measurement. The structure of the complex has also determined using single crystal X-ray diffraction. The geometric structure around the V(V) ion has been found to be octahedral in which the positions around the central ion are occupied by ONO ligand donors, oxido groups, and oxygen atoms of coordinated propanol and propoxide group. Electrochemical behavior of this complex is also discussed in more details. In vitro antimicrobial effect of the title complex has investigated exhibiting significant activities against some Gram-positive (Staphylococcus aureus, Micrococcus luteus, Bacillus cereus, Eterococcus faecalis) and Gram-negative bacteria (Pseudomonas aeruginosa, Escherichia coli, Klebsiella sp, Pseudomonas sp) and fungus strain (Candida albicans).

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Acknowledgments

The authors gratefully acknowledge the financial support provided for this work by the Shahid Bahonar University of Kerman.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Shahid Bahonar University of Kerman, 76169-14111, Kerman, Iran

    S. Yousef Ebrahimipour & Iran Sheikhshoaie

  2. Department of Chemistry, Payame Noor University (PNU), 19395-4697, Tehran, Iran

    Maryam Mohamadi

  3. Departamento de Química Inorgínica, Analítica y Química, Física/INQUIMAE–CONICET, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina

    Sebastián Suárez

  4. Gerencia de Investigación y Aplicaciones, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Buenos Aires, Argentina

    Ricardo Baggio

  5. Department of Biology, Faculty of Science, Shahid Bahonar University of Kerman, Kerman, Iran

    Moj Khaleghi

Authors
  1. S. Yousef Ebrahimipour
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  2. Maryam Mohamadi
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  3. Iran Sheikhshoaie
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  4. Sebastián Suárez
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  5. Ricardo Baggio
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  6. Moj Khaleghi
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Correspondence to S. Yousef Ebrahimipour.

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Yousef Ebrahimipour, S., Mohamadi, M., Sheikhshoaie, I. et al. A novel oxido-vanadium(V) Schiff base complex: synthesis, spectral characterization, crystal structure, electrochemical evaluation, and biological activity. Res Chem Intermed 42, 611–623 (2016). https://doi.org/10.1007/s11164-015-2045-y

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  • DOI: https://doi.org/10.1007/s11164-015-2045-y

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