Research on Chemical Intermediates

, Volume 42, Issue 2, pp 611–623 | Cite as

A novel oxido-vanadium(V) Schiff base complex: synthesis, spectral characterization, crystal structure, electrochemical evaluation, and biological activity

  • S. Yousef Ebrahimipour
  • Maryam Mohamadi
  • Iran Sheikhshoaie
  • Sebastián Suárez
  • Ricardo Baggio
  • Moj Khaleghi


A new oxido-vanadium(V) complex, [VO(L)(PrOH)(OPr)] (L = [(3-methoxy-2oxidobenzylidene)benzohydrazidato], PrOH = propanol, OPr = propanolato) has been synthesized and characterized by means of elemental analysis, Fourier transform infrared (FTIR), proton nuclear magnetic resonance (1HNMR), ultaviolet-visible (UV–Vis) spectroscopy, voltammetry and molar conductivity measurement. The structure of the complex has also determined using single crystal X-ray diffraction. The geometric structure around the V(V) ion has been found to be octahedral in which the positions around the central ion are occupied by ONO ligand donors, oxido groups, and oxygen atoms of coordinated propanol and propoxide group. Electrochemical behavior of this complex is also discussed in more details. In vitro antimicrobial effect of the title complex has investigated exhibiting significant activities against some Gram-positive (Staphylococcus aureus, Micrococcus luteus, Bacillus cereus, Eterococcus faecalis) and Gram-negative bacteria (Pseudomonas aeruginosa, Escherichia coli, Klebsiella sp, Pseudomonas sp) and fungus strain (Candida albicans).


Schiff base ligand V(V) complex Electrochemical behavior Anti-microbial activity Biofilm formation 



The authors gratefully acknowledge the financial support provided for this work by the Shahid Bahonar University of Kerman.


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Copyright information

© Springer Science+Business Media Dordrecht 2015

Authors and Affiliations

  • S. Yousef Ebrahimipour
    • 1
  • Maryam Mohamadi
    • 2
  • Iran Sheikhshoaie
    • 1
  • Sebastián Suárez
    • 3
  • Ricardo Baggio
    • 4
  • Moj Khaleghi
    • 5
  1. 1.Department of Chemistry, Faculty of ScienceShahid Bahonar University of KermanKermanIran
  2. 2.Department of ChemistryPayame Noor University (PNU), 19395-4697TehranIran
  3. 3.Departamento de Química Inorgínica, Analítica y Química, Física/INQUIMAE–CONICET, Facultad de Ciencias Exactas y NaturalesUniversidad de Buenos AiresBuenos AiresArgentina
  4. 4.Gerencia de Investigación y Aplicaciones, Centro Atómico Constituyentes, Comisión Nacional de Energía AtómicaBuenos AiresArgentina
  5. 5.Department of Biology, Faculty of ScienceShahid Bahonar University of KermanKermanIran

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