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Research on Chemical Intermediates

, Volume 41, Issue 11, pp 8355–8362 | Cite as

Samarium(III) triflate: a new catalyst for facile synthesis of benzothiazoles and benzoxazoles from carboxylic acids in aqueous media

  • Pratapsinha B. Gorepatil
  • Yogesh D. Mane
  • Amarsinha B. Gorepatil
  • Mahadev V. Gaikwad
  • Vilas S. Ingle
Article

Abstract

A facile synthetic method for benzothiazoles and benzoxazoles comprising the reaction of corresponding 2-aminothiophenol and 2-aminophenol with various substituted aromatic carboxylic acids using Samarium(III) triflate as a catalyst has been described. The advantages of the method are short reaction times and aqueous reaction media and easy work-up. The catalysts can be recovered for the subsequent reactions and reused without any appreciable loss of efficiency.

Keywords

Carboxylic acids Benzothiazoles Benzoxazoles Lewis acid Samarium triflate 

Notes

Acknowledgment

One of the authors, Mr. P.B. Gorepatil, is grateful to the Council of Scientific and Industrial Research (CSIR), New Delhi for a Junior Research Fellowship (JRF).

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Copyright information

© Springer Science+Business Media Dordrecht 2014

Authors and Affiliations

  • Pratapsinha B. Gorepatil
    • 1
  • Yogesh D. Mane
    • 1
  • Amarsinha B. Gorepatil
    • 2
  • Mahadev V. Gaikwad
    • 3
  • Vilas S. Ingle
    • 1
  1. 1.Department of ChemistryS. C. S. CollegeDist-OsmanabadIndia
  2. 2.Department of ChemistryS. G. R. G. S. CollegeDist-OsmanabadIndia
  3. 3.Department of ChemistryB. P. C. A. S. AngarDist-SolapurIndia

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