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Research on Chemical Intermediates

, Volume 41, Issue 7, pp 4919–4927 | Cite as

Boron trifluoride supported on hydroxyapatite-encapsulated-γ-Fe2O3 as a magnetically recoverable catalyst for ring opening of α,β-epoxy ketones

  • Ali Saffar-Teluri
  • Majid Ghashang
  • Hossein Saffar-Teluri
  • Shiva Bolouk
  • Fereshte Khademi
Article

Abstract

Catalytic ring opening reactions of α-epoxyketones by boron trifluoride supported on hydroxyapatite-encapsulated-γ-Fe2O3 [γ-Fe2O3@HAp-BF3 CH3OH2 +] as a heterogeneous, reusable and highly efficient catalyst in methanol solution at room temperature resulted in the formation of α-hydroxyl-β-methoxyketones through Cβ-O cleavage in excellent yields. The catalyst can be easily separated by a magnet and reused for several cycles.

Keywords

Ring opening Epoxy ketones Heterogeneous catalyst 

Notes

Acknowledgments

We gratefully acknowledge for financial support from the Research Council of Islamic Azad University of Najafabad Branch.

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Copyright information

© Springer Science+Business Media Dordrecht 2014

Authors and Affiliations

  • Ali Saffar-Teluri
    • 1
  • Majid Ghashang
    • 1
  • Hossein Saffar-Teluri
    • 1
  • Shiva Bolouk
    • 1
  • Fereshte Khademi
    • 1
  1. 1.Department of Chemistry, Najafabad BranchIslamic Azad UniversityNajafabadIran

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