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Boron trifluoride supported on hydroxyapatite-encapsulated-γ-Fe2O3 as a magnetically recoverable catalyst for ring opening of α,β-epoxy ketones

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Abstract

Catalytic ring opening reactions of α-epoxyketones by boron trifluoride supported on hydroxyapatite-encapsulated-γ-Fe2O3 [γ-Fe2O3@HAp-BF3 −CH3OH2 +] as a heterogeneous, reusable and highly efficient catalyst in methanol solution at room temperature resulted in the formation of α-hydroxyl-β-methoxyketones through Cβ-O cleavage in excellent yields. The catalyst can be easily separated by a magnet and reused for several cycles.

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Acknowledgments

We gratefully acknowledge for financial support from the Research Council of Islamic Azad University of Najafabad Branch.

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Authors and Affiliations

  1. Department of Chemistry, Najafabad Branch, Islamic Azad University, P.O. Box 85141-43131, Najafabad, Iran

    Ali Saffar-Teluri, Majid Ghashang, Hossein Saffar-Teluri, Shiva Bolouk & Fereshte Khademi

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  1. Ali Saffar-Teluri
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  2. Majid Ghashang
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  3. Hossein Saffar-Teluri
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  4. Shiva Bolouk
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  5. Fereshte Khademi
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Correspondence to Ali Saffar-Teluri.

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Saffar-Teluri, A., Ghashang, M., Saffar-Teluri, H. et al. Boron trifluoride supported on hydroxyapatite-encapsulated-γ-Fe2O3 as a magnetically recoverable catalyst for ring opening of α,β-epoxy ketones. Res Chem Intermed 41, 4919–4927 (2015). https://doi.org/10.1007/s11164-014-1577-x

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