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Research on Chemical Intermediates

, Volume 41, Issue 2, pp 845–852 | Cite as

Synthesis, characterization, and crystal structure of a binuclear UO2(VI) complex with a bipyridine derivative ligand

  • Niloufar Akbarzadeh-T
  • Tahereh Kondori
Article

Abstract

The binuclear complex {[UO2(5,5′-dmbpy)(NO3)]2(μ-O2)}, where 5,5′-dmbpy is 5,5′-dimethyl-2,2′-bipyridine, was prepared by reaction of UO2(NO3)2.6H2O with 5,5′-dimethylbipyridine in 1:1 methanol–acetonitrile. The complex was characterized by FT-IR and UV–visible spectroscopy, cyclic voltammetry (CV), and single-crystal X-ray diffraction analysis. The crystal data for {[UO2(5,5′-dmbpy)(NO3)]2(μ-O2)} at 25 °C are: monoclinic, space group P2 1 /n with a = 9.8(7) Å, b = 16.0 (12) Å, c = 10.3 (8) Å, β = 111.023(9)° and Z = 2.

Keywords

5,5′-Dimethyl-2,2′-bipyridine Space group Monoclinic 

Notes

Acknowledgments

The authors sincerely thank the university of Sistan and Baluchestan for financial support of this work.

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Copyright information

© Springer Science+Business Media Dordrecht 2013

Authors and Affiliations

  1. 1.Department of ChemistryUniversity of Sistan and BaluchestanZahedanIran

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