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Synthesis, characterization, and crystal structure of a binuclear UO2(VI) complex with a bipyridine derivative ligand

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Abstract

The binuclear complex {[UO2(5,5′-dmbpy)(NO3)]2(μ-O2)}, where 5,5′-dmbpy is 5,5′-dimethyl-2,2′-bipyridine, was prepared by reaction of UO2(NO3)2.6H2O with 5,5′-dimethylbipyridine in 1:1 methanol–acetonitrile. The complex was characterized by FT-IR and UV–visible spectroscopy, cyclic voltammetry (CV), and single-crystal X-ray diffraction analysis. The crystal data for {[UO2(5,5′-dmbpy)(NO3)]2(μ-O2)} at 25 °C are: monoclinic, space group P2 1 /n with a = 9.8(7) Å, b = 16.0 (12) Å, c = 10.3 (8) Å, β = 111.023(9)° and Z = 2.

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Acknowledgments

The authors sincerely thank the university of Sistan and Baluchestan for financial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, University of Sistan and Baluchestan, P.O. Box 98135-674, Zahedan, Iran

    Niloufar Akbarzadeh-T & Tahereh Kondori

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  1. Niloufar Akbarzadeh-T
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  2. Tahereh Kondori
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Correspondence to Niloufar Akbarzadeh-T.

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Akbarzadeh-T, N., Kondori, T. Synthesis, characterization, and crystal structure of a binuclear UO2(VI) complex with a bipyridine derivative ligand. Res Chem Intermed 41, 845–852 (2015). https://doi.org/10.1007/s11164-013-1236-7

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