Use of drinking water sludge in the production process of zeolites
- 293 Downloads
This study reports the synthesis of zeolites A, X, and P, cancrinite, and sodalite using sludge generated in a drinking water plant. Two experimental steps were carried out: (1) fusion and (2) hydrothermal treatment. Crystallization was achieved by means of a 23 experimental design with central point with the following factors: temperature, time, and solid/liquid ratio. The sludge presented Si and Al contents (SiO2/Al2O3 = 1.7) which allow the synthesis of zeolites with high cation exchange capacity. The content of organic matter was considerable (loss on ignition 26.1 %), but is eliminated in the fusion step at 550 °C. This process also permits the conversion of the initial aluminosilicates into zeolite precursors (sludge–NaOH mix of 1:0.785 g/g). Hydrothermal treatment then permits the crystallization of the aforementioned zeolites. These materials showed high cation exchange capacities as compared to other commercial and experimentally synthesized zeolites, and can be used in the removal of heavy metals such Cd2+, Pb2+, Cu2+, Fe2+, and ammonium present in water, providing an interesting new option in wastewater treatment and remediation of soils.
KeywordsSludge Drinking water plants Zeolite Ion exchange
The authors thank Omar Novelo for his assistance in the SEM analyses and Leticia García for her assistance in N2 adsorption–desorption analyses. F. Espejel Ayala acknowledges support from DGAPA in the form of his post-doctoral grant.
- 2.K-S. You, G-Ch. Han, H-Ch. Cho, J-W. Ahn, TMS Annual Meeting. 37–41 (2007)Google Scholar
- 3.D.W. Breck, Zeolite Molecular Sieves: Structure, Chemistry, and Use, 3rd edn. (EUA, New York, 1974)Google Scholar
- 7.F. Espejel-Ayala, R. M. Ramírez Zamora, MRS Proceedings 1380 (2012) imrc2011-1380-s21-full030. doi: 10.1557/opl.2012.403
- 11.R. M. Barrer, Hydrothermal Chemistry of Zeolites. (New York: EUA, 1982)Google Scholar