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Microwave-assisted, methanesulfonic acid-catalyzed synthesis of 3,3′-(arylmethylene)bis(4-hydroxy-2H-chromen-2-ones)

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Abstract

Efficient synthesis of 3,3′-(arylmethylene)bis(4-hydroxy-2H-chromen-2-ones) has been achieved by methanesulfonic acid-catalyzed, microwave-assisted reaction of 4-hydroxycoumarin and aromatic aldehydes in ethanol. The procedure has the advantages of high yield, short reaction time, low energy consumption, and convenient work-up. Compound structures were confirmed by IR, 1H NMR, and 13C NMR spectroscopy and by elemental analysis.

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Authors and Affiliations

  1. Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huaian, 223300, China

    Xan Qi, Xiao-Jun Sun, Yin Zhi & Jian-Feng Zhou

  2. Department of Chemistry, Nanjing Xiaozhuang University, Nanjing, 211171, China

    Meng-Wei Xue

Authors
  1. Xan Qi
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  2. Meng-Wei Xue
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  3. Xiao-Jun Sun
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  4. Yin Zhi
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  5. Jian-Feng Zhou
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Correspondence to Jian-Feng Zhou.

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Qi, X., Xue, MW., Sun, XJ. et al. Microwave-assisted, methanesulfonic acid-catalyzed synthesis of 3,3′-(arylmethylene)bis(4-hydroxy-2H-chromen-2-ones). Res Chem Intermed 40, 1187–1192 (2014). https://doi.org/10.1007/s11164-013-1031-5

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  • DOI: https://doi.org/10.1007/s11164-013-1031-5

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