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Research on Chemical Intermediates

, Volume 40, Issue 3, pp 991–1002 | Cite as

Inhibition of corrosion of copper in nitric acid solution by four amino acids

  • K. Barouni
  • A. Kassale
  • L. Bazzi
  • R. Salghi
  • B. Hammouti
  • A. Albourine
  • S. El Issami
  • O. Jbara
  • M. Bouachrine
Article

Abstract

Inhibition of corrosion of copper in 1M HNO3 solution by four amino acids, proline (Pro), phenylalanine (Phe), tyrosine (Tyr), and tryptophan (Try), has been studied by use of gravimetric and electrochemical polarization measurements. The results obtained the from two different techniques are comparable, and show that Tyr and Try act as good inhibitors of corrosion of copper in 1 mol L−1 HNO3. Correlation between inhibition efficiency and quantum chemical calculations, performed using semi empirical (AM1 and MNDO) and ab-initio methods, is discussed.

Keywords

Corrosion Inhibition Copper Amino acids Nitric acid 

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Copyright information

© Springer Science+Business Media Dordrecht 2013

Authors and Affiliations

  • K. Barouni
    • 1
  • A. Kassale
    • 1
  • L. Bazzi
    • 1
  • R. Salghi
    • 2
  • B. Hammouti
    • 3
  • A. Albourine
    • 1
  • S. El Issami
    • 1
  • O. Jbara
    • 4
  • M. Bouachrine
    • 5
  1. 1.Laboratoire Matériaux et Environnement, Faculté des SciencesUniversité Ibn RochdAgadirMorocco
  2. 2.Equipe de Génie de l’Environnement et de Biotechnologie, ENSAUniversité Ibn RochdAgadirMorocco
  3. 3.LCAE-URAC18, Faculté des SciencesUniversité Mohammed PremierOujdaMorocco
  4. 4.GRSPI, Equipe Matériaux FonctionnelsUniversité de ReimsReimsFrance
  5. 5.ESTMUniversité Moulay IsmailMeknesMorocco

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