Research on Chemical Intermediates

, Volume 39, Issue 9, pp 4099–4107 | Cite as

Poly(acrylamide-co-4-vinylpyridine) containing quaternary alkyl bromide; synthesis and characterization

  • K. Medjahed
  • L. Tennouga
  • A. Mansri
  • O. Baba


The copolymer poly(acrylamide-co-4-vinylpyridine) (P(AM-co-4-VP); PAV) of acrylamide (AM) and 4-vinylpyridine (4-VP) was synthesized by conventional radical copolymerization then quaternized by reaction with an alkyl bromide with a C8 carbon chain to produce the copolymer series of cationic bromide octanes poly(acrylamide-co-4-vinypyridine) CPAVC8Br2 (I), (II), and (III). The structure and composition of the cationic copolymers CPAVC8Br2 were characterized by conductimetry, FTIR, UV–visible, and 1H NMR spectroscopy, Scanning electron microscopy (SEM) and Energy dispersion x-ray spectroscopy (EDX).


Polymer supported bromated Conversion rate Synthesis Characterization 



The authors thank the National Agency for the Development of University Research (ANDRU) in Algeria for financial support.


  1. 1.
    B. Dizman, M.O. Asri, L. Mathias, J. Polym. Macromol. 39, 5738–5746 (2006)CrossRefGoogle Scholar
  2. 2.
    C. Damas, A. Brembilla, P. Lochon, F. Baros, M. Viriot, J. Polym. Sci. 36, 2095–2101 (1995)Google Scholar
  3. 3.
    C. Damas, A. Brembilla, P. Lochon, Macromol. Sci. 102, 233–240 (1996)Google Scholar
  4. 4.
    G. Baojiao, L. Yuexian, J. Hongfang, Polym. In. 52, 1468–1473 (2003)Google Scholar
  5. 5.
    C. Yi, Z. Xu, S. Cheng, Acta Polymerica China 3, 29 (1999)Google Scholar
  6. 6.
    S.A. Umoren, Y. Lia, F.H. Wang, Corros. Sci. 52, 1777 (2010)CrossRefGoogle Scholar
  7. 7.
    A. Mansri, B. Bouras, B. Hammouti, I. Warad, A. Chetouani, Res. Chem. Intermed. (2012). doi: 10.1007/s11164-012-0710-y
  8. 8.
    I. ElOuali, B. Hammouti, A. Aouniti, M. Benabdellah, S. Kertit, Der Pharma Chemica 5, 294–300 (2011)Google Scholar
  9. 9.
    A. Chetouani, K. Medjahed, K.E. Benabadji, B. Hammouti, S. Kertit, A. Mansri, Prog. Org. Coat. 46, 312 (2003)CrossRefGoogle Scholar
  10. 10.
    A. El-Khair, B.M. Khalifa, O. Abdel-Hamid, I. Azzam, Corros. Prev. Control 7(34), 152 (1987)Google Scholar
  11. 11.
    S. El Ayyoubi, A. Chetouani, B. Hammouti, A. Warthan, A. Mansri, S.S. Al-Deyab, Int. J. Electrochem. Sci. 7, 1639–1655 (2012)Google Scholar
  12. 12.
    A. Chetouani, B. Hammouti, S. Kertit, K. Medjahed, A. Mansri, K.I. Benabadji, Prog. Org. Coat. 46, 312–316 (2003)CrossRefGoogle Scholar
  13. 13.
    A. Chetouani, B. Hammouti, K. Medjahed, A. Mansri, Der Pharma Chemica 3, 307–316 (2011)Google Scholar
  14. 14.
    F. Kaoru, A. Yasuhiro, U. Seiji, S. Yasushi, S. Minoru, Anal. Sci. Jap. 15 (1999)Google Scholar
  15. 15.
    C. Ashish, K. Balbir, J. Textile Sci. Eng. India 1, 1 (2011)Google Scholar
  16. 16.
    H. El-Hamshary, M. El-Garawany, F. Assubaie, M. Al-Eed, J. Appl. Polym. Sci. 89, 2522–2526 (2003)CrossRefGoogle Scholar
  17. 17.
    E.Y. Kirch, O.P. Komarova, G.M. Lukovkin, Eur. Polym. 19, 1405 (1973)Google Scholar
  18. 18.
    A. Bernas, N. Kumara, P. Mäki-Arvel, N. Kulkova, B. Holmbomc, T. Salmi, D. Murzin, Appl. Catal. A 245, 257–275 (2003)CrossRefGoogle Scholar
  19. 19.
    S. Thibaud-Dartigues, Thesis doctoral (Bordeaux, France, 2004)Google Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2012

Authors and Affiliations

  1. 1.Département de Chimie, Laboratoire d’Application des Electrolytes et des Polyélectrolytes Organiques (LAEPO)Université de TlemcenTlemcenAlgeria

Personalised recommendations