Advertisement

Research on Chemical Intermediates

, Volume 39, Issue 6, pp 2527–2536 | Cite as

Conductometric study of the complex system polyelectrolyte/surfactant in aqueous solution

  • L. Tennouga
  • K. Medjahed
  • A. Mansri
  • B. Grassl
Article

Abstract

In this work, the interaction between the anionic surfactant sodium dodecyl sulfate (SDS) and the polyelectrolyte complex hydrolyzed polyacrylamide/poly(4-vinylpyridine) (AD37–P4VP) in aqueous solution was investigated by conductometric measurements. Three main series with SDS concentrations of 0.01, 0.25 and 1 % and in a wide range of P4VP and AD37 concentrations, from 0.1 × 10−4 to 4 × 10−4 g/ml, and from 10−4 to 10−3 g/ml, respectively, were studied. The polyelectrolyte complex interacts strongly with the SDS surfactant. These interactions are of electrostatic and hydrophobic types. Thus, the effect of salt on the critical micelle concentration of SDS, and the neutralization degree on behavior conductivity of the mixture, were quantified.

Keywords

Conductivity Polyelectrolyte AD37 P4VP SDS Interactions 

Notes

Acknowledgment

Authors thank the Agence Nationale pour le Développement de la Recherche Universitaire (ANDRU) in Algeria for its financial support.

References

  1. 1.
    C. Monteux, Thèse de Doctorat, Université de Paris VI, France (2004)Google Scholar
  2. 2.
    P. Deo, N. Deo, Langmuir 21, 9998 (2005)CrossRefGoogle Scholar
  3. 3.
    G. Bai, M. Nichifor, A. Lopes, M. Bastos, J. Phys. Chem. B 109, 46, 21681 (2005)Google Scholar
  4. 4.
    R.S. Farinato, P.L. Dubin (eds.), Colloid–Polymer Interactions, from Fundamentals to Practice (Wiley, New York, 1999)Google Scholar
  5. 5.
    S. Zhou, B. Chu, Adv. Mater. 12, 545 (2000)CrossRefGoogle Scholar
  6. 6.
    G. Bai, J.A.M. Catita, M. Nichifor, M. Bastos, J. Phys. Chem. B 111, 11453–11462 (2007)CrossRefGoogle Scholar
  7. 7.
    D.N. Truong, Thèse de Doctorat, Strasbourg, France (1984)Google Scholar
  8. 8.
    G. Medjahdi, Thèse de Doctorat, Strasbourg, France (1989)Google Scholar
  9. 9.
    R. Rabhari, Thèse de Doctorat, Strasbourg, France (1988)Google Scholar
  10. 10.
    M. Yoshida, N. Sakamoto, K. Ikemi, S. Arichi, Bull. Chem. Soc. Jpn. 65, 3108 (1992)Google Scholar
  11. 11.
    L. Tennouga, K. Medjahed, A. Mansri, J. Desbrières, Polym. Bull. (2012). doi: 10.1007/s00289-012-0783-1
  12. 12.
    A. Mansri, L. Tennouga, J. Desbrières, Eur. Polym. J. 43, 540–549 (2007)CrossRefGoogle Scholar
  13. 13.
    A. Mansri, L. Tennouga, J. Desbrières, Polym. Bull. 61, 771–777 (2008)CrossRefGoogle Scholar
  14. 14.
    E. Choukchou-Braham, I. Benabadji, A. Mansri, J. François, Eur. Polym. J. 39, 297–303 (2007)CrossRefGoogle Scholar
  15. 15.
    F. Franks, Water: A Comprehensive Treatise (Plenum, New York, 1975)CrossRefGoogle Scholar
  16. 16.
    D.G. Hall, J. Chem. Soc. Faraday Trans. II 70, 1526 (1974)CrossRefGoogle Scholar
  17. 17.
    W. Binana-Limbeli, F. Clouet, J. Francois, J. Colloid Polym. Sci. 271, 748 (1995)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media B.V. 2012

Authors and Affiliations

  • L. Tennouga
    • 1
  • K. Medjahed
    • 1
  • A. Mansri
    • 1
  • B. Grassl
    • 2
  1. 1.Département de Chimie, Laboratoire d’Application des Electrolytes et des Polyélectrolytes Organiques (LAEPO) Université de TlemcenTlemcenAlgeria
  2. 2.Institut Pluridisciplinaire de Recherche en Environnement et Matériaux (IPREM) UMR UPPA CNRS 5254, Equipe de Physique et Chimie des Polymères (EPCP)Université de Pau et des Pays de l’Adour (UPPA)Pau Cedex 9France

Personalised recommendations