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Synthesis of sodium titanium phosphate at ultra-low temperature

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Abstract

Powders of the Nasicon material NaTi2(PO4)3 were directly synthesized at ultra-low temperature. NaTi2(PO4)3 was obtained by mixing the initial reagents titanium hydroxide, 85 % H3PO4, and NaH2PO4·2H2O at 85 °C for 3.5 h or at 125 °C for 1.5 h. The raw materials and synthesized products were characterized for purity, crystal structure, particle size, and powder morphology by thermogravimetric analysis, differential scanning calorimetry, X-ray diffraction (XRD), Fourier-transform infrared spectroscopy, scanning electron microscopy (SEM), and UV–visible diffuse reflectance spectroscopy. XRD results revealed that NaTi2(PO4)3 powders with rhombohedral crystal structure were synthesized at 85 and 125 °C. SEM patterns showed that the as-prepared products were agglomerated and that each of the agglomerations consisted of many small grains 50–80 nm in diameter.

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Authors and Affiliations

  1. School of Chemistry and Materials Science, Liaoning Shihua University, Fushun, 113001, China

    Fuhong Sun, Rui Wang, Heng Jiang & Weilei Zhou

  2. State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian, 116024, China

    Rui Wang

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  1. Fuhong Sun
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  2. Rui Wang
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  3. Heng Jiang
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  4. Weilei Zhou
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Correspondence to Heng Jiang.

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Sun, F., Wang, R., Jiang, H. et al. Synthesis of sodium titanium phosphate at ultra-low temperature. Res Chem Intermed 39, 1857–1864 (2013). https://doi.org/10.1007/s11164-012-0720-9

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  • DOI: https://doi.org/10.1007/s11164-012-0720-9

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