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Research on Chemical Intermediates

, Volume 35, Issue 4, pp 543–554 | Cite as

A novel CeIII-cyclam type complex and its redox chemistry in aqueous solutions

  • Guy Yardeni
  • Israel Zilbermann
  • Eric Maimon
  • Haim Cohen
  • Dan Meyerstein
Article
  • 39 Downloads

Abstract

A new CeIII complex was synthesized by mixing the ligand “dioxocyclam” with CeIII ions at pH 8.0 and its redox properties were investigated.

Keywords

CeIV/III Dioxocyclam Oxidation Radicals 

Notes

Acknowledgements

This study was supported in part by a grant from the Budgeting and Planning Committee of The Council of Higher Education and the Israel Atomic Energy Commission. G.Y. wishes to thank Ms. Lioubov Kats for help and technical support in Gas Chromatography analyses

References

  1. 1.
    D.R. Lide, Handbook of Chemistry and Physics, 87th edn. (CRC Press, USA, 2007)Google Scholar
  2. 2.
    F.A. Cotton, G. Wilkinson, Advanced Inorganic Chemistry, 5th edn. (Wiley, New york, 1988)Google Scholar
  3. 3.
    E.A. Malinina, L.I. Martynenko, N.I. Pechurova, V.I. Spiltsyn, Russian Chem. Bull. 18,1935 (1969)Google Scholar
  4. 4.
    A.E.V. Gorden, J. Xu, K.N. Raymond, Chem. Rev. 103, 4208 (2003)CrossRefGoogle Scholar
  5. 5.
    X.H. Bu, D.L. An, X.C. Cao, R.H. Zhang, T. Clifford, E. Kimura, J. Chem. Soc. Dalton Trans. 13, 2247 (1998)Google Scholar
  6. 6.
    M.S. Mashuta, K.V. Pimenov, C.A. Grapperhaus, Acta. Cryst. C58, o226 (2002)Google Scholar
  7. 7.
    Z.H. Zhang, X.H. Bu, X.C. Cao, S.Y. Ma, Z.A. Zhu, Y.T. Chen, Transition Met. Chem. 22, 479 (1997)CrossRefGoogle Scholar
  8. 8.
    J.M. Slocik, M.S. Ward, R.E. Shepherd, Inorg. Chim. Acta. 317, 290 (2001)CrossRefGoogle Scholar
  9. 9.
    M. Komod, E. Kimura, J. Chem. Soc. Dalton Trans. 2, 325 (1979)Google Scholar
  10. 10.
    L. Fabbrizzi, A. Poggi, J. Chem. Soc. Chem. Comm. 14, 646 (1980)Google Scholar
  11. 11.
    L. Fabbrizzi, A. Perotti, A. Poggi, Inorg. Chem. 22, 1411 (1983)CrossRefGoogle Scholar
  12. 12.
    L. Fabbrizzi, A. Perotti, A. Profumo, T. Soldi, Inorg. Chem. 25, 4256 (1986)CrossRefGoogle Scholar
  13. 13.
    R.W. Hay, R. Bemby, W. Sommerville, Inorg. Chim. Acta. 59, 147 (1982)CrossRefGoogle Scholar
  14. 14.
    I. Tabushi, Y. Taniguchi, H. Kato, Teterahedron Lett. 12, 1049 (1977)CrossRefGoogle Scholar
  15. 15.
    M.P. Suh, H.Y. Kim, M.J. Kim, K.Y. Oh, Inorg. Chem. 31, 3620 (1992)CrossRefGoogle Scholar
  16. 16.
    E.J. Hart, S. Gordon, J.K. Thomas, J. Phys. Chem. 68, 1271 (1964)CrossRefGoogle Scholar
  17. 17.
    E. J. Hart, Radiat. Res. 2, 33 (1955)CrossRefGoogle Scholar
  18. 18.
    H. Fricke, E.J. Hart, in Radiation Dosimetry, ed. by F.H. Attix, W.C. Roesch, E. Tochilin (Academic Press, New York, 1966), p. 167Google Scholar
  19. 19.
    S. Goldstein, G. Czapski, H. Cohen, D. Meyerstein, Inorg. Chem. 31, 2439 (1992)CrossRefGoogle Scholar
  20. 20.
    M.S. Matheson, L. Dorfman, Pulse Radiolysis (MIT Press, Cambridge, MA, 1969)Google Scholar
  21. 21.
    G.V. Buxton, C.L. Greenstook, W.P. Helman, A.B. Ross, J. Phys. Chem. Ref. Data 17, 513 (1988)Google Scholar
  22. 22.
    A.B. Ross, W.G. Mallard, W.P. Helman, J.V. Buxton, R.E. Huie, P. Neta, NIST Standard References Database, Version 2.0, (1994)Google Scholar
  23. 23.
    D. Behar, J. Phys. Chem. 76, 1815 (1972)CrossRefGoogle Scholar
  24. 24.
    D. Zehavi, J. Rabani, J. Phys. Chem. 76, 312 (1972)CrossRefGoogle Scholar
  25. 25.
    N. Motohashi, Y. Saito, Chem. Pharm. Bull. 41, 1842 (1993)Google Scholar
  26. 26.
    D. Veltwisch, E. Janata, K.D. Asmus, J. Chem. Soc. Perkin Trans. 2, 146 (1980)Google Scholar
  27. 27.
    L.C.T. Shoute, Z.B. Alfassi, P. Neta, R.E. Huie, J. Phys. Chem. 95, 3238 (1991)CrossRefGoogle Scholar
  28. 28.
    G. Ferraudi, J. Phys. Chem. 97, 2793 (1993)CrossRefGoogle Scholar
  29. 29.
    B. Hickel, J. Phys. Chem. 79, 1054 (1975)CrossRefGoogle Scholar
  30. 30.
    I. Rusonic, H. Polat, H. Cohen, D. Meyerstein, Eur. J. Inorg. Chem. 23, 4227 (2003)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media BV 2009

Authors and Affiliations

  1. 1.Chemistry DepartmentNuclear Research Centre NegevBeer-ShevaIsrael
  2. 2.Chemistry DepartmentBen-Gurion University of the NegevBeer-ShevaIsrael
  3. 3.Biological Chemistry DepartmentAriel University Center of SamariaArielIsrael

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