Computer simulation of geminate recombination in non-crystalline polymer solids
- 55 Downloads
A computer simulation method is applied to model geminate charge recombination in non-crystalline polymer solids that exhibit charge transport anisotropy due to different intra- and interchain hopping rates. We investigate how the electron escape probability is affected by both the degree of charge transport anisotropy and morphology of polymer systems.
KeywordsAnisotropy Charge transport anisotropy Interchain hopping rates Intrachain hopping rates
This work was supported by the Ministry of Science and Higher Education of Poland (Grant No. N204 080 32/2232).
- 3.M. Tachiya, Theory of diffusion-controlled reactions: Formulation of the bulk reaction rate in terms of the pair probability. Radiat. Phys. Chem. 21, 167 (1983)Google Scholar
- 4.M. Wojcik, M. Tachiya, Geminate charge recombination with distance-dependent intrinsic reaction rate: Escape probability and its electric field effect. Radiat. Phys. Chem. 74, 132 (2005)Google Scholar
- 5.S.A. Rice, Diffusion-Limited Reactions (Elsevier, Amsterdam, 1985), Chap. 7 and references thereinGoogle Scholar