The influences of various processing parameters on phase and structure formation during reactive sintering of B4C materials in a Si melt are studied. The reaction of B4C particles and C with molten Si during reactive sintering is examined. Dissolution of B4C particles in the Si melt during reactive sintering has a negative effect. Methods for increasing the content of B4C particles in the reactively sintered B4C ceramic are discussed.
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R. Telle and G. Petzow, “Mechanisms in the liquid phase sintering of boron carbide with silicon based melts,” High Tech Ceram. (Part A), 38, 961 – 973 (1986).
Z. F. Chen, Y. C. Su, and Y. B. Cheng, “Formation and sintering mechanisms of reaction bonded silicon carbide – boron carbide composites,” Key Eng. Mater., 352, 207 – 212 (2007).
E. F. Kharchenko, V. A. Aniskovich, V. V. Lenskii, I. S. Gavrikov, and V. A. Bykov, RU Pat. 2,440,956 (C1), Jan. 27, 2012, “Method of producing ceramic armor material based on silicon carbide and boron carbide.”
A. I. Ovsienko, V. I. Rumyantsev, S. S. Ordan’yan, and V. N. Fishchev, RU Pat. 2,621,241, Jun. 1, 2017, “Nanostructured composite material based on boron carbide and the method of its obtaining.”
M. K. Aghajanian, A. L. McCormick, B. N. Morgan, and A. F. Liszkiewicz, Jr., US Pat. 7,332,221 (B2), Feb. 19, 2008, “Boron carbide composite bodies, and method for making same.”
K. M. Taylor and R. J. Palicka, US Pat. 3,796,564, Mar. 12, 1974, “Dense carbide composite bodies and method of making same.”
C. Zhang, H. Ru, W. Wang, et al., “The role of infiltration temperature in the reaction bonding of boron carbide by silicon infiltration,” J. Am. Ceram. Soc., 97(10), 3286 – 3293 (2014).
S. Hayun, A. Weizmann, M. P. Dariel, and N. Farge, “Microstructural evolution during the infiltration of boron carbide with molten silicon,” J. Eur. Ceram. Soc., 30(4), 1007 – 1014 (2010).
M. Patel, V. V. B. Prasad, and J. Subrahmanyan, “Compressive property of liquid silicon (infiltrated) boron carbide,” Trans. Indian Inst. Met., 63(6), 863 – 866 (2010).
D. Mallick, T. K. Kayal, J. Ghosh, et al., “Development of multi-phase B–Si–C ceramic composite by reaction sintering,” Ceram. Int., 35(4), 1667 – 1669 (2009).
S. Hayun, N. Frage, and M. P. Dariel, “The morphology of ceramic phases in BxC–SiC–Si infiltrated composites,” J. Solid State Chem., 179(9), 2875 – 2879 (2006).
S. Hayun, A. Weizmann, M. P. Dariel, and N. Frage, “The effect of particle size distribution on the microstructure and the mechanical properties of boron carbide-based reaction-bonded composites,” Int. J. Appl. Ceram. Technol., 6(4), 492 – 500 (2009).
M. P. Dariel and N. Frage, “Reaction bonded boron carbide: Recent developments,” Adv. Appl. Ceram., 111(5/6), 301 – 310 (2012).
P. Barick, D. C. Jana, and N. Thiyagarajan, “Effect of particle size on the mechanical properties of reaction bonded boron carbide ceramics,” Ceram. Int., 39(1), 763 – 770 (2013).
K. Korniyenko, et al., “Boron–carbon–silicon,” in: Refractory Metal Systems, Springer, Berlin, Heidelberg, 2009, pp. 499 – 534.
W. A. Gooch, “An overview of ceramic armor applications,” in: Ceramic Armor Material by Design, J. W. McCauley, et al. (eds.), American Ceramic Society, Westerville, 2002, pp. 3 – 21.
SiC Armour Materials for Ballistic Protection; https://www.schunkgroup.com/fileadmin/Redakteur/Mediathek/Broschueren/SchunkCar-bonTechnology/TechnicalCeramics/Schunk-Carbon-Technology-SiC-Armour-Materials-Ballistic-Protection-EN.pdf (accessed Apr. 3, 2018).
J. Briggs, Engineering Ceramics in Europe and the USA, Enceram, Menith Wood, Worcester, UK, 2011, 331 pp.
M. K. Aghajanian, B. N. Morgan, J. R. Singh, et al., “A new family of reaction bonded ceramics for armor applications,” Ceram. Trans., 134, 527 – 539 (2002).
A. I. Ovsienko, V. I. Rumyantsev, S. S. Ordan’yan, et al., “Reaction sintered boron carbide: Structure, properties and potential applications as ceramic armor,” in: Current Problems in Production Technology of Modern Ceramics: Proceedings of a Scientific Seminar [in Russian], Izd. Politekhn. Univ., St. Petersburg, 2015, pp. 84 – 93.
A. I. Ovsienko, V. I. Rumyantsev, I. A. Bespalov, and N. M. Sil’nikov, “Potential use of reaction sintered boron carbide as a reinforcing ceramic,” Vopr. Oboronoi. Tekh., Ser. 16, No. 7/8 (85/86), 95 – 101 (2015).
S. S. Ordan’yan, D. D. Nesmelov, and A. I. Ovsienko, “Phase formation during reactive sintering of the B4C–SiC–Si(Al) composite (Review),” Refract. Ind. Ceram., 58(6), 666 – 672 (2017).
J. Pittari, G. Subhash, J Zheng, et al., “The rate-dependent fracture toughness of silicon carbide- and boron carbide-based ceramics,” J. Eur. Ceram. Soc., 35(16), 4411 – 4422 (2015).
C. Zhang, H. Ru, W. Wang, et al., “The role of infiltration temperature in the reaction bonding of boron carbide by silicon infiltration,” J. Am. Ceram. Soc., 97(10), 3286 – 3293 (2014); DOI: https://doi.org/10.1111/jace.13085.
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Translated from Novye Ogneupory, No. 10, pp. 9 – 15, October, 2018.
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Ovsienko, A.I., Rumyantsev, V.I. & Ordan’yan, S.S. Ceramics Based on Reactively Sintered Boron Carbide. Refract Ind Ceram 59, 507–513 (2019). https://doi.org/10.1007/s11148-019-00263-8
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DOI: https://doi.org/10.1007/s11148-019-00263-8