Refractories and Industrial Ceramics

, Volume 57, Issue 1, pp 33–37 | Cite as

Synthesis and Conversion on Heating of Nickel-Containing Antioxidant Organic Precursor for Periclase-Carbon Refractories

  • G. D. Semchenko
  • D. A. Brazhnik
  • V. V. Povshuk
  • I. N. Rozhko
  • E. E. Starolat
  • K. P. Vernigora

Results are given for a study of physicochemical processes occurring on heating synthesized antioxidant precursor, i.e., nickel oxalate salt. It is shown that after heating at 300°C NiO is formed that is an antioxidant. Salt before and after heat treatment at 300 – 500°C may be used as an antioxidant


periclase-carbon refractories antioxidant NiO precursor nickel oxalate 


  1. 1.
    K. K. Strelov, Structure and Properties of Refractories [in Russian], Metallurgiya, Moscow (1982).Google Scholar
  2. 2.
    I. D. Kashcheev, Oxide-Carbon Refractories [in Russian], Intermet Inzhiniring, Moscow (2000).Google Scholar
  3. 3.
    S. A. Suvorov, V. A. Musevich, F. R. Iksanov, et al., “Effect of parameters of state on phase transitions of carbonized periclase refractories,” Refract. Indust. Ceram., 48(5), 362 – 367 (2007).CrossRefGoogle Scholar
  4. 4.
    A. Yamaguchi, “The development of the self-repairing refractories,” Proc.World refractory congress, 27 – 29 Jun. 2004, Singapore.Google Scholar
  5. 5.
    S. Zhang, N. J. Marriott, and W. E. Lee, “Thermochemistry and microstructures of MgO–C refractories containing various antioxidants,” J. Eur. Ceram. Soc., 21(8), 1037 – 1047 (2001).CrossRefGoogle Scholar
  6. 6.
    Yu. S. Rodgol’ts, L. M. Aksel’rod, and V. I. Éntin, Ukrainian Patent 25805, MPK6 C 04 B 35/035. Method for preparing periclase-carbon refractories, Claimant and patent holder B. M. B.-S. D Trading Corp. Ltd., No. 98105217, Claim 10.12.1998, Publ. 02.28.2000, Byul. No. 1.Google Scholar
  7. 7.
    S. K. Sadrnezhaad, Z. A. Nemati, S. Mahshid, et al., “Effect of Al antioxidant on the rate of oxidation of carbon in MgO–C refractory,” J. Amer. Ceram. Soc., 90(2), 509 – 515 (2007).CrossRefGoogle Scholar
  8. 8.
    A. V. Mozzherin, V. A. Musevich, A. P. Duka, “The design and resistance evolution of 150-ton ladles lining,” Refract. Indust. Ceram., 50(1), 1 – 9 (2009).CrossRefGoogle Scholar
  9. 9.
    E. V. Krivokorytov, A. G. Gur’ev, and B. I. Polyak, “High-Carbon Binders in Refractories and Corrosion-Resistant Ceramics Technology (A Review),” Steklo Keram., No. 5, 12 – 15 (1998).Google Scholar
  10. 10.
    K. Murata, T. Matsui, and K. Kono, “Oxidizing prevention of MgO–C bricks for converters,” Taikabutsu Overseas, 11(2), 17 – 22 (1991).Google Scholar
  11. 11.
    A. G. Ryabukhin and E. G. Novoselova, “Oxidation of nickel in air with solid film formation,” Vestn. YuUrGU, No. 10, 34 – 40 (2005).Google Scholar
  12. 12.
    L. Ya. Margolis, The Magic Wand of Chemistry [in Russian], Nauka, Moscow (1964).Google Scholar
  13. 13.
    L. N. Poling, Chemistry [in Russian], Nauka, Moscow 91985).Google Scholar
  14. 14.
    D. A. Brazhnik, G. D. Semchenko, I. I. Rizhko, et al., “Use of nickel antioxidants in the composition of periclase-carbon refractories,” Vestn. NTU KhPI, No. 53, 9 – 13 (2014).Google Scholar
  15. 15.
    A. P. Il’in, D. A. Pivovarov, and Yu. Yu. Polubchikova, RF Patent 2468892, B 22 F 9/30, Method for preparing ultrafine metal powders by thermal decomposition of oxalates in saturated hydrocarbons, Claimant and patent holder FGBOU higher professional society “National Research Tomsk Polytechnic University”, Claim 09.20.11, Publ. 12.10.12.Google Scholar
  16. 16.
    J. Benare, Oxidation of Metals, in 2 Vol., Vol. 1 [Russian translation], Metallurgiya, (1968), Vol. 2 (1969).Google Scholar
  17. 17.
    K. V. Vatsura and G. A. Mishchenko, Named Reactions in Organic Chemistry: Handbook [in Russian], Khimiya, Moscow (1976).Google Scholar

Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • G. D. Semchenko
    • 1
  • D. A. Brazhnik
    • 1
  • V. V. Povshuk
    • 1
  • I. N. Rozhko
    • 1
  • E. E. Starolat
  • K. P. Vernigora
    • 1
  1. 1.National Technical University, Khar’kov Polytechnic InstituteKhar’kovUkraine

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