Results are given for a study of physicochemical processes occurring on heating synthesized antioxidant precursor, i.e., nickel oxalate salt. It is shown that after heating at 300°C NiO is formed that is an antioxidant. Salt before and after heat treatment at 300 – 500°C may be used as an antioxidant
Similar content being viewed by others
References
K. K. Strelov, Structure and Properties of Refractories [in Russian], Metallurgiya, Moscow (1982).
I. D. Kashcheev, Oxide-Carbon Refractories [in Russian], Intermet Inzhiniring, Moscow (2000).
S. A. Suvorov, V. A. Musevich, F. R. Iksanov, et al., “Effect of parameters of state on phase transitions of carbonized periclase refractories,” Refract. Indust. Ceram., 48(5), 362 – 367 (2007).
A. Yamaguchi, “The development of the self-repairing refractories,” Proc.World refractory congress, 27 – 29 Jun. 2004, Singapore.
S. Zhang, N. J. Marriott, and W. E. Lee, “Thermochemistry and microstructures of MgO–C refractories containing various antioxidants,” J. Eur. Ceram. Soc., 21(8), 1037 – 1047 (2001).
Yu. S. Rodgol’ts, L. M. Aksel’rod, and V. I. Éntin, Ukrainian Patent 25805, MPK6 C 04 B 35/035. Method for preparing periclase-carbon refractories, Claimant and patent holder B. M. B.-S. D Trading Corp. Ltd., No. 98105217, Claim 10.12.1998, Publ. 02.28.2000, Byul. No. 1.
S. K. Sadrnezhaad, Z. A. Nemati, S. Mahshid, et al., “Effect of Al antioxidant on the rate of oxidation of carbon in MgO–C refractory,” J. Amer. Ceram. Soc., 90(2), 509 – 515 (2007).
A. V. Mozzherin, V. A. Musevich, A. P. Duka, “The design and resistance evolution of 150-ton ladles lining,” Refract. Indust. Ceram., 50(1), 1 – 9 (2009).
E. V. Krivokorytov, A. G. Gur’ev, and B. I. Polyak, “High-Carbon Binders in Refractories and Corrosion-Resistant Ceramics Technology (A Review),” Steklo Keram., No. 5, 12 – 15 (1998).
K. Murata, T. Matsui, and K. Kono, “Oxidizing prevention of MgO–C bricks for converters,” Taikabutsu Overseas, 11(2), 17 – 22 (1991).
A. G. Ryabukhin and E. G. Novoselova, “Oxidation of nickel in air with solid film formation,” Vestn. YuUrGU, No. 10, 34 – 40 (2005).
L. Ya. Margolis, The Magic Wand of Chemistry [in Russian], Nauka, Moscow (1964).
L. N. Poling, Chemistry [in Russian], Nauka, Moscow 91985).
D. A. Brazhnik, G. D. Semchenko, I. I. Rizhko, et al., “Use of nickel antioxidants in the composition of periclase-carbon refractories,” Vestn. NTU KhPI, No. 53, 9 – 13 (2014).
A. P. Il’in, D. A. Pivovarov, and Yu. Yu. Polubchikova, RF Patent 2468892, B 22 F 9/30, Method for preparing ultrafine metal powders by thermal decomposition of oxalates in saturated hydrocarbons, Claimant and patent holder FGBOU higher professional society “National Research Tomsk Polytechnic University”, Claim 09.20.11, Publ. 12.10.12.
J. Benare, Oxidation of Metals, in 2 Vol., Vol. 1 [Russian translation], Metallurgiya, (1968), Vol. 2 (1969).
K. V. Vatsura and G. A. Mishchenko, Named Reactions in Organic Chemistry: Handbook [in Russian], Khimiya, Moscow (1976).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Novye Ogneupory, No. 1, pp. 29 – 34, January, 2016.
Rights and permissions
About this article
Cite this article
Semchenko, G.D., Brazhnik, D.A., Povshuk, V.V. et al. Synthesis and Conversion on Heating of Nickel-Containing Antioxidant Organic Precursor for Periclase-Carbon Refractories. Refract Ind Ceram 57, 33–37 (2016). https://doi.org/10.1007/s11148-016-9922-9
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11148-016-9922-9