Abstract
The effect of Cu, Fe, Co, Ni, Cr and Zn on Mn–Zr–Ti mixed oxides catalysts introduced by co-precipitation was investigated. The Mn–Co catalyst showed the highest NO conversion near 100% and a good N2 selectivity > 90% at 200–300 °C. Comparing with the Mn–non catalyst, the Mn–Co catalyst presented a higher reaction rate constant at 120 °C with 23.3 ml s−1 g−1. The Mn–Co catalyst possesses a high concentration of Mn4+ and surface labile oxygen, which should improve the redox property and increase catalytic activity. Additionally, the Mn–Co showed the highest ratio of Lewis acid sites. The resistance to SO2 was improved by incorporation of Co. In summary, the Mn–Zr–Ti mixed oxides catalyst have a better N2 selectivity than other Mn-based catalysts and could be improved by doping with Co.
Similar content being viewed by others
References
Zhou H, Su Y, Liao W, Deng W, Zhong F (2016) Fuel 182:352–360
Jo S-H, Kim S, Kim H-D, Jeong B, Lee H (2018) Reac Kinet Mech Cat 125:733–742
Shi R, Lin X, Zheng Z, Feng R, Liu Y, Ni L, Yuan B (2017) Reac Kinet Mech Cat 124:217–227
Zhang S, Zhang B, Liu B, Sun S (2017) RSC Adv 7:26226–26242
Li F, Xie J, Cui H, Gong P, He F (2018) Reac Kinet Mech Cat 125:647–661
Xie C, Yang S, Shi J, Li B, Gao C, Niu C (2017) Chem Eng J 327:1–8
Huang L, Hu X, Yuan S, Li H, Yan T, Shi L, Zhang D (2017) Appl Catal B 203:778–788
Gao C, Shi J-W, Fan Z, Yu Y, Chen J, Li Z, Niu C (2017) Fuel Process Technol 167:322–333
Thirupathi B, Smirniotis PG (2012) J Catal 288:74–83
Deng S, Zhuang K, Xu B, Ding Y, Yu L, Fan Y (2016) Catal Sci Technol 6:1772–1778
Zhang B, Zhang S, Liu B, Shen H, Li L (2018) RSC Adv 8:12733–12741
Zhang B, Liebau M, Liu B, Li L, Zhang S, Gläser R (2019) J Mater Sci 54:6943–6960
Wang H, Qu Z, Xie H, Maeda N, Miao L, Wang Z (2016) J Catal 338:56–67
Peng Y, Li K, Li J (2013) Appl Catal B 140–141:483–492
Chen Z, Yang Q, Li H, Li X, Wang L, Chi Tsang S (2010) J Catal 276:56–65
Zamudio MA, Russo N, Fino D (2011) Ind Eng Chem Res 50:6668–6672
Shen K, Zhang Y, Wang X, Xu H, Sun K, Zhou C (2013) J Energy Chem 22:617–623
Zhou C, Zhang Y, Wang X, Xu H, Sun K, Shen K (2013) J Colloid Interface Sci 392:319–324
Wang T, Sun K, Lu Z, Zhang Y (2010) Reac Kinet Mech Cat 101:153–161
Casapu M, Kröcher O, Elsener M (2009) Appl Catal B 88:413–419
Yang S, Qi F, Xiong S, Dang H, Liao Y, Wong PK, Li J (2016) Appl Catal B 181:570–580
Kozuch S, Martin JML (2012) ACS Catal 2:2787–2794
Lente G (2013) ACS Catal 3:381–382
Bligaard T, Bullock RM, Campbell CT, Chen JG, Gates BC, Gorte RJ, Jones CW, Jones WD, Kitchin JR, Scott SL (2016) ACS Catal 6:2590–2602
Zhang G, Han W, Zhao H, Zong L, Tang Z (2018) Appl Catal B 226:117–126
Liu F, He H, Zhang C, Feng Z, Zheng L, Xie Y, Hu T (2010) Appl Catal B 96:408–420
Gao R, Zhang D, Maitarad P, Shi L, Rungrotmongkol T, Li H, Zhang J, Cao W (2013) J Phys Chem C 117:10502–10511
Boningari T, Pappas DK, Ettireddy PR, Kotrba A, Smirniotis PG (2015) Ind Eng Chem Res 54:2261–2273
Qi G, Yang RT, Chang R (2004) Appl Catal B 51:93–106
Gao G, Shi J-W, Fan Z, Gao C, Niu C (2017) Chem Eng J 325:91–100
Cai S, Liu J, Zha K, Li H, Shi L, Zhang D (2017) Nanoscale 9:5648–5657
Fang D, Xie J, Hu H, Yang H, He F, Fu Z (2015) Chem Eng J 271:23–30
Gao F, Tang X, Yi H, Li J, Zhao S, Wang J, Chu C, Li C (2017) Chem Eng J 317:20–31
Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, Sing KSW (2015) Pure Appl Chem 87:1051–1069
Deorsola FA, Andreoli S, Armandi M, Bonelli B, Pirone R (2016) Appl Catal A 522:120–129
Li C, Tang X, Yi H, Wang L, Cui X, Chu C, Li J, Zhang R, Yu Q (2018) Appl Surf Sci 428:924–932
Wang X, Cheng J, Wang X, Shi Y, Chen F, Jing X, Wang F, Ma Y, Wang L, Ning P (2018) Chem Eng J 333:402–413
Tang X, Li C, Yi H, Wang L, Yu Q, Gao F, Cui X, Chu C, Li J, Zhang R (2018) Chem Eng J 333:467–476
Yu L, Zhong Q, Deng Z, Zhang S (2016) J Mol Catal A Chem 423:371–378
Gao F, Tang X, Yi H, Zhao S, Wang J, Shi Y, Meng X (2018) Appl Surf Sci 443:103–113
Boningari T, Ettireddy PR, Somogyvari A, Liu Y, Vorontsov A, McDonald CA, Smirniotis PG (2015) J Catal 325:145–155
Li X, Li J, Peng Y, Chang H, Zhang T, Zhao S, Si W, Hao J (2016) Appl Catal B 184:246–257
Chen H, Xia Y, Huang H, Gan Y, Tao X, Liang C, Luo J, Fang R, Zhang J, Zhang W, Liu X (2017) Chem Eng J 330:1195–1202
France LJ, Yang Q, Li W, Chen Z, Guang J, Guo D, Wang L, Li X (2017) Appl Catal B 206:203–215
Fang D, He F, Liu X, Qi K, Xie J, Li F, Yu C (2018) Appl Surf Sci 427:45–55
Thirupathi B, Smirniotis PG (2011) Appl Catal B 110:195–206
Putluru SSR, Schill L, Jensen AD, Siret B, Tabaries F, Fehrmann R (2015) Appl Catal B 165:628–635
Zhan S, Qiu M, Yang S, Zhu D, Yu H, Li Y (2014) J Mater Chem A 2:20486–20493
Meng D, Xu Q, Jiao Y, Guo Y, Guo Y, Wang L, Lu G, Zhan W (2018) Appl Catal B 221:652–663
Li P, Zhang R, Liu N, Royer S (2017) Appl Catal B 203:174–188
Yang W, Zhang R, Chen B, Bion N, Duprez D, Royer S (2012) J Catal 295:45–58
Jin R, Liu Y, Wang Y, Cen W, Wu Z, Wang H, Weng X (2014) Appl Catal B 148–149:582–588
Acknowledgements
This work is sponsored by National Natural Science Foundation of China (Grants U1360202, 51672024, 51472030 and 51502014) and Fundamental Research Funds for the Central Universities (2302017FRF-IC-17-005 and 2302017FRF-BR-17-005A).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Zhang, B., Zhang, S. & Liu, B. Comparative study on transition element doped Mn–Zr–Ti-oxides catalysts for the low-temperature selective catalytic reduction of NO with NH3. Reac Kinet Mech Cat 127, 637–652 (2019). https://doi.org/10.1007/s11144-019-01586-w
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11144-019-01586-w