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Mechanochemically modified hydrazine reduction method for the synthesis of nickel nanoparticles and their catalytic activities in the Suzuki–Miyaura cross-coupling reaction

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Abstract

The commonly used hydrazine reduction method for the synthesis of Ni nanoparticles was integrated with the mechanochemical treatment of the nickel hydroxide precursors to modify the structural and catalytic attributes of the as-prepared metallic nickel materials. The precursors and the nanoparticles were studied by X-ray diffractometry, infrared spectroscopy, and dynamic light scattering as well as scanning electron microscopy. The changes in catalytic activities were followed in the Suzuki–Miyaura cross-coupling reaction between iodobenzene and phenylboronic acid and correlated with structural changes resulting from mechanochemical pretreatment.

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Acknowledgement

This work was supported by the GINOP-2.3.2-15-2016-00013 Grant. The financial help is highly appreciated.

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Authors and Affiliations

  1. Department of Organic Chemistry, University of Szeged, Dóm tér 8, Szeged, 6720, Hungary

    Katalin Musza, Márton Szabados, Adél Anna Ádám & István Pálinkó

  2. Material and Solution Structure Research Group, Institute of Chemistry, University of Szeged, Aradi Vértanúk tere 1, Szeged, 6720, Hungary

    Katalin Musza, Márton Szabados, Adél Anna Ádám, Pál Sipos & István Pálinkó

  3. Department of Applied and Environmental Chemistry, University of Szeged, Rerrich B. tér 1, Szeged, 6720, Hungary

    Zoltán Kónya & Ákos Kukovecz

  4. MTA-SZTE Reaction Kinetics and Surface Chemistry Research Group, Rerrich B. tér 1, Szeged, 6720, Hungary

    Zoltán Kónya

  5. Department of Inorganic and Analytical Chemistry, University of Szeged, Dóm tér 7, Szeged, 6720, Hungary

    Pál Sipos

Authors
  1. Katalin Musza
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  2. Márton Szabados
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  4. Zoltán Kónya
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  6. Pál Sipos
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  7. István Pálinkó
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Correspondence to István Pálinkó.

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Musza, K., Szabados, M., Ádám, A.A. et al. Mechanochemically modified hydrazine reduction method for the synthesis of nickel nanoparticles and their catalytic activities in the Suzuki–Miyaura cross-coupling reaction. Reac Kinet Mech Cat 126, 857–868 (2019). https://doi.org/10.1007/s11144-018-1509-7

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  • DOI: https://doi.org/10.1007/s11144-018-1509-7

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