Abstract
Catalytic wet peroxide oxidation of 4-chlorophenol solution was studied over nickel and zinc ferrite nanoparticles at mild conditions. The catalysts were prepared by sol–gel auto combustion method using ethylene glycol and citric acid as gelling agents at different calcination temperatures. Complete removal of 4-chlorophenol (25 ml of 1 g/l 4-chlorophenol solution) was achieved within 60 min at ambient conditions. Studies on the effect of reaction variables revealed that only a small amount of the oxidant (1 ml) is required for the complete degradation of 4-chlorophenol. 100 % of the target pollutant was removed at catalyst concentrations of 300 mg. The catalysts were reusable and the activity as well as the single phasic nature of the ferrite catalysts remained the same after five successive runs. Leaching of iron from ferrite nanoparticles was not observed after five consecutive cycles indicating the mechanism to be heterogeneous. The samples were characterized by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The results underline the effect of preparation conditions on the morphology, crystallite size and catalytic efficiency of nanoferrites.
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References
Kulkarni US, Dixit SG (1991) Destruction of phenol from wastewater by oxidation with SO3 2−−O2. Ind Eng Chem Res 30:1916–1920
Kaith LH, Telliard WA (1979) Priority pollutants I–—a perspective view. Environ Sci Technol 13:416–423
Stoyanova M, Christoskova G, Georgieva M (2003) Low-temperature catalytic oxidation of water containing 4-chlorophenol over Ni-oxide catalyst. Appl Catal A 248:249–259
Li N, Descorme C, Besson M (2007) Catalytic wet air oxidation of aqueous solution of 2-chlorophenol over Ru/zirconia catalysts. Appl Catal B 71:262–270
Cezar C, Daniela A, Carmen T (2011) Catalytic wet hydrogen peroxide oxidation of para-chlorophenol over Al/Fe pillared clays (AlFePILCs) prepared from different host clays. Appl Catal B 101:451–460
Caudo S, Centi G, Genovese C, Perathoner S (2007) Copper- and iron-pillared clay catalysts for the WHPCO of model and real wastewater streams from olive oil milling production. Appl Catal B 70:437–446
Chamarro E, Maeco E, Esplugas S (2001) Use of Fenton reagent to improve organic chemical biodegradability. Water Res 35:1047
Psillakis E, Mantzavinos D (2004) Enhancement of biodegradability of industrial wastewaters by chemical oxidation pre-treatment. J Chem Technol Biotechnol 79:431–454
Kurian M, Joy M, Raj D (2012) Hydroxylation of phenol over rare earth exchanged iron pillared montmorillonites. J Porous Mater 19:633–640
Brain TN, Pawe IM, David RC (2007) Magnetic properties of nickel–zinc ferrite toroids prepared from nanoparticles. J Am Ceram Soc 90:3547–3553
Wang JH, Liu YC, Liu DC, Yu YW, Guo FB (2009) Effect of electromagnetic field strength on Ni0.35Zn0.65Fe2O4 as performed by combustion synthesis. J Magn Magn Mater 321:3646–3649
Silva VJ, Cornejo DR, Morelli MR, Gama L (2008) Magnetic and structural properties of NiFe2O4 ferrite nanopowder doped with Zn2+. J Magn Magn Mater 320:370–372
Ramankutty CG, Sugunan S (2001) Surface properties and catalytic activity of ferrospinels of nickel, cobalt and copper, prepared by soft chemical methods. Appl Catal A 218:39–51
Kale S, Gubbala RDK, Misra (2004) Magnetic behavior of nanocrystalline nickel ferrite synthesized by the reverse micelle technique. J Magn Magn Mater 277:350
Kurian M, Nair DS (2013) Effect of preparation conditions on Nickel–Zinc Ferrite nanoparticles: a comparison between sol–gel auto combustion and co-precipitation methods. J Saudi Chem Soc 17(3):345–426. doi:10.1016/j.jscs.2013.03.003
Cabanas A, Poliakoff M (2001) The continuous hydrothermal synthesis of nano-particulate ferrites in near critical and supercritical water. J Mater Chem 11:1408–1416
Slama J, Gruskova A, Usakova M, Usak E (2009) Contribution to analysis of Cu-substituted Ni–Zn ferrites. J Magn Magn Mater 321:3346–3351
Zhou S, Gu C, Qian Z, Xu J, Xia C (2011) The activity and selectivity of catalytic peroxide oxidation of chlorophenols over Cu–Al hydrotalcite/clay composite. J Colloid Interface Sci 357:447–452
Molina VG, Lopez Arias M, Florczyk M, Chamarro E, Esplugas S (2005) Wet peroxide oxidation of chlorophenols. Water Res 39:795–802
Hamoudi S, Sayari A, Belkacemi K, Bonneviot L, Larachi F (2000) Catalytic wet oxidation of phenol over PtxAg1−xMnO2/CeO2 catalysts. Catal Today 62:379–388
Kurian M, Babu R (2013) Iron aluminium mixed pillared montmorillonite and the rare earth exchanged analogues as efficient catalysts for phenol oxidation. J Environ Chem Eng 1:86–91
Sadana A, Katzer JR (1974) Involvement of free radicals in the aqueous-phase catalytic oxidation of phenol over copper oxide. J Catal 35:140–152
Kurian M, Sugunan S (2006) Wet peroxide oxidation of phenol over mixed pillared montmorillonites. Chem Eng J 115:139–146
Mallat T, Baiker A (1994) Oxidation of alcohols with molecular-oxygen on platinum metal-catalysts in aqueous-solutions. Catal Today 19:247–283
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The financial assistance from the Department of Science and Technology, India through Fast Track Scheme for Young Scientists is gratefully acknowledged.
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Kurian, M., Nair, D.S. & Rahnamol, A.M. Influence of the synthesis conditions on the catalytic efficiency of NiFe2O4 and ZnFe2O4 nanoparticles towards the wet peroxide oxidation of 4-chlorophenol. Reac Kinet Mech Cat 111, 591–604 (2014). https://doi.org/10.1007/s11144-013-0667-x
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DOI: https://doi.org/10.1007/s11144-013-0667-x