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Reaction Kinetics, Mechanisms and Catalysis

, Volume 104, Issue 1, pp 61–73 | Cite as

Adsorption and photooxidation of pharmaceuticals and personal care products on clay minerals

  • Yanxiang Liu
  • Xujie Lu
  • Feng Wu
  • Nansheng Deng
Article

Abstract

The adsorption and photodegradation behavior of tetracycline (TC), chloramphenicol (CAP) and sulfamethoxazole (SMX) in clay mineral dispersion was investigated in this work. Only TC showed significant adsorption to natural montmorillonite and rectorite, whereas CAP and SMX adsorbed to natural montmorillonite, kaolinite and rectorite to a much lower extent. The adsorption equilibrium constants (L/kg) of TC to natural montmorillonite were 332 and 108 at pH 3.0 and 7.0, respectively. The kinetic rate constant k app (min−1) for the removal of CAP in the presence of different clay minerals follows the sequence: montmorillonite KSF (1.6 × 10−2) > rectorite (4.6 × 10−3) > natural montmorillonite (3.8 × 10−3) > kaolinite (2.8 × 10−3). Removal of SMX follows the same sequence. Oxalate significantly promotes the removal of CAP and SMX in montmorillonite KSF dispersion, while penicillamine (PEN) and β-cyclodextrin retard the diminution. After 3 h of irradiation in 5 g/L KSF dispersion, the total organic carbon was reduced by 72 and 39% for CAP and SMX, respectively.

Keywords

PPCPs Clay minerals Adsorption Photodegradation 

Notes

Acknowledgment

This work was financed by the Natural Science Foundation of Hubei, China (No. 2009CDB159). The authors thank the anonymous reviewers for their comments.

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2011

Authors and Affiliations

  • Yanxiang Liu
    • 1
  • Xujie Lu
    • 1
  • Feng Wu
    • 2
  • Nansheng Deng
    • 2
  1. 1.School of Chemical and Environmental EngineeringJianghan UniversityWuhanPeople’s Republic of China
  2. 2.School of Resources and Environmental ScienceWuhan UniversityWuhanPeople’s Republic of China

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