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Substituted N-hydroxyphthalimides as oxidation catalysts

  • K. V. Novikova
  • M. O. Kompanets
  • O. V. Kushch
  • S. P. Kobzev
  • M. M. Khliestov
  • I. O. Opeida
Article

Abstract

A series of substituted N-hydroxyphthalimides (NHPI) with electron-withdrawing groups (4-C(O)OH, C=O) and an electron-donating group (4-C(CH3)3) were investigated as catalysts for cumene oxidation. The initial reaction rates, measured by the oxygen uptake, conversion of substrate and yield of oxidation products are discussed. The catalytic activity of oxidation rate enhancement of NHPI derivatives in acetonitrile follows the order 4-tert-BuNHPI > NHPI > 4-carb-NHPI > NDHPI > NAPI. NMPT, trityl-NPI and NHPLI are inactive.

Keywords

N-hydroxyphthalimide Homogenous catalysis Aerobic oxidation Cumene BDE 

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2011

Authors and Affiliations

  • K. V. Novikova
    • 1
  • M. O. Kompanets
    • 1
  • O. V. Kushch
    • 1
  • S. P. Kobzev
    • 1
  • M. M. Khliestov
    • 2
  • I. O. Opeida
    • 1
  1. 1.L.M. Litvinenko Institute of physico-organic and coal chemistry of NASUDonetskUkraine
  2. 2.Department of chemistryDonetsk national universityDonetskUkraine

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