Abstract
The Mo–Fe/HZSM-5 catalyst was prepared by the impregnation method using citric acid to form Fe3+ and Mo6+ chelates in the impregnation solution. The structure, acidity and the catalytic performance for the macrolactonization of methyl 15-hydroxypentadecanoate to cyclopentadecanolide over Mo–Fe/HZSM-5 catalyst in comparison with unmodified HZSM-5, Fe/HZSM-5 and Mo/HZSM-5 catalysts were studied. The results indicate that the optimum ratio of Mo/Fe is 2.5. The Fe2(MoO4)3 and Al2(MoO4)3 species are formed on the Mo–Fe/HZSM-5 catalyst, with an increase of strength and slight diminution of the amount of acid sites. The Mo–Fe/HZSM-5 catalyst exhibited high activity for the selective macrolactonization of methyl 15-hydroxypentadecanoate to cyclopentadecanolide.
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References
Gautschi M, Bajgrowicz JA, Kraft P (2001) Chimia 55:379
Kraft P, Frater G (2001) Chirality 13:388
Ishihara K, Kubota M, Kurihara H, Yamamoto H (1996) J Org Chem 61:4560
Mukaiyama T, Izumi J, Shiina I (1997) Chem Lett 26:187
Keck GE, Sanchez C, Wager CA (2000) Tetrahedron Lett 41:8673–8676
Shiina I, Kubota K, Ibuka R (2002) Tetrahedron Lett 43:7535–7539
Liu X, Li W, Li P, Zhou Y (2007) J Chem J Chin Univ 28(5):897–899 (in Chinese)
Ookoshi T, Onaka M (1998) Tetrahedron Lett 39:293–296
Kirumakki SR, Nagaraju N, Murthy KVVSBSR et al (2002) Appl Catal A 226:175–182
Peng J, Chen P, Lou H et al (2009) Bioresour Technol 100:3415–3418
Kirumakki SR, Nagaraju N, Chary KVR et al (2003) Appl Catal A 248:161–167
Zhu X, Yu K, Cheng D, Zhang Y, Xia Q, Liu C (2008) Front Chem Eng China 2(1):55–58
Wu P, Kan Q, Wang D, Xing H, Yang P, Wua T (2005) Appl Catal A: Gen 282:39–44
Liu S, Wang L, Ohnishi R, Ichikawa M (1999) J Catal 181:175
Lu J, Zhao Z, Xu C, Duan A, Wang X, Zhang P (2008) J Porous Mater 15:213–220
Masiero SS, Marcilio NR, Perez-Lopez OW (2009) Catal Lett 131:194–202
Liu H, Li Y, Shen W, Bao X, Xu Y (2004) Catal Today 93–95:65
Kentgens M, Scholl J, Veeman S (1983) J Phys Chem 87:4357
Li Y, Liu L, Huang X, Liu X, Shen W, Xu Y, Bao X (2007) Catal Commun 8:1567
Tessonnier J, Louis B, Rigolet S, Ledoux MJ, Pham-Huu C (2008) Appl Catal A 336:79
Li B, Li S, Li N, Chen H, Zhang W, Bao X, Lin B (2006) Microporous Mesoporous Mater 88:24
Tessonnier J, Louis B, Walspurger S, Sommer J, Ledoux M, Pham-Huu C (2006) J Phys Chem B 110:10390
Tan PL, Au CT, Lai SY (2007) Appl Catal A 324:36
Acknowledgments
We are grateful for the support of the Natural Science Foundation of Guangxi Zhuang Autonomous Region of China (No GKZ 0135013). Lastly, we are full of gratitude to Dr. Min Ling for checking our manuscript.
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Lai, F., Liu, X., Li, W. et al. Macrolactonization of methyl 15-hydroxypentadecanoate to cyclopentadecanolide over Mo–Fe/HZSM-5 catalyst. Reac Kinet Mech Cat 100, 407–415 (2010). https://doi.org/10.1007/s11144-010-0196-9
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DOI: https://doi.org/10.1007/s11144-010-0196-9